Stepwise N–H bond formation from N2-derived iron nitride, imide and amide intermediates to ammonia

Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands

(2016) Ilija Čorić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57Fe Mössbauer Data, and a Hydride Resting State

(2016) Trevor J. Del Castillo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes

(2015) Sean F. McWilliams et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Challenge of Electrochemical Ammonia Synthesis: A New Perspective on the Role of Nitrogen Scaling Relations

(2015) Joseph H. Montoya et al.   ChemSusChem

Homolytic N–H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species

(2015) Markus G. Scheibel et al.   INORGANIC CHEMISTRY

Identification of a Key Catalytic Intermediate Demonstrates That Nitrogenase Is Activated by the Reversible Exchange of N2 for H2

(2015) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of an Fe≡N–NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3

(2015) John S. Anderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Ligand Modification Chemistry of a Molybdenum Dinitrogen Complex: Redox and Chemical Activity of a Bis(imino)pyridine Ligand

(2014) Grant W. Margulieux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dinitrogen Activation Upon Reduction of a Triiron(II) Complex

(2014) Yousoon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Challenges in reduction of dinitrogen by proton and electron transfer

(2014) Cornelis J. M. van der Ham et al.   CHEMICAL SOCIETY REVIEWS

Alkali Metal Control over N–N Cleavage in Iron Complexes

(2014) Katarzyna Grubel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Multi-iron System Capable of Rapid N2 Formation and N2 Cleavage

(2014) K. Cory MacLeod et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ammonia synthesis by N2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2O3

(2014) S. Licht et al.   SCIENCE

Nitrogenase: A Draft Mechanism

(2013) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Haber-Bosch Process Revisited: On the Real Structure and Stability of “Ammonia Iron” under Working Conditions

(2013) Timur Kandemir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Zwitterionic Cobaltocenium Borate and Borata-alkene Derivatives from a Borole-Radical Anion

(2013) Jürgen Bauer et al.   CHEMISTRY-A EUROPEAN JOURNAL

H–H and Si–H Bond Addition to Fe≡NNR2 Intermediates Derived from N2

(2013) Daniel L. M. Suess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Protons on the Redox Chemistry of Colloidal Zinc Oxide Nanocrystals

(2013) Carolyn N. Valdez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Iron(IV)hydroxide pKa and the Role of Thiolate Ligation in C-H Bond Activation by Cytochrome P450

(2013) T. H. Yosca et al.   SCIENCE

Proton-Coupled Electron Transfer

(2012) David R. Weinberg et al.   CHEMICAL REVIEWS

Reevaluation of colorimetric iron determination methods commonly used in geomicrobiology

(2012) Juliane Braunschweig et al.   JOURNAL OF MICROBIOLOGICAL METHODS

Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions

(2012) Masahiro Yuki et al.   Nature Communications

An electrochemical investigation of intermediates and processes involved in the catalyticreduction of dinitrogen by [HIPTN3N]Mo (HIPTN3N = (3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2)3N)

(2011) Thiruvengadam Munisamy et al.   DALTON TRANSACTIONS

Ammonia formation by metal–ligand cooperative hydrogenolysis of a nitrido ligand

(2011) Bjorn Askevold et al.   Nature Chemistry

Synthesis, Structure, and Reactivity of an Iron(V) Nitride

(2011) J. J. Scepaniak et al.   SCIENCE

N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex

(2011) M. M. Rodriguez et al.   SCIENCE

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory

(2010) James M. Mayer   ACCOUNTS OF CHEMICAL RESEARCH

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine

(2010) Nilay Hazari   CHEMICAL SOCIETY REVIEWS

Iron–dinitrogen coordination chemistry: Dinitrogen activation and reactivity

(2010) Justin L. Crossland et al.   COORDINATION CHEMISTRY REVIEWS

Isolation and Hydrogenation of a Complex with a Terminal Iridium-Nitrido Bond

(2009) Julia Schöffel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of Ammonia from an Iron Nitrido Complex

(2009) Jeremiah J. Scepaniak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitrogen Cycle Electrocatalysis

(2009) Victor Rosca et al.   CHEMICAL REVIEWS

C−H Bond Activation of Decamethylcobaltocene Mediated by a Nitrogenase Fe8S7P-Cluster Model

(2009) Yasuhiro Ohki et al.   INORGANIC CHEMISTRY

First-Principles Calculation of pKaValues for Organic Acids in Nonaqueous Solution

(2009) Feizhi Ding et al.   JOURNAL OF ORGANIC CHEMISTRY

Slow Hydrogen Atom Transfer Reactions of Oxo- and Hydroxo-Vanadium Compounds: The Importance of Intrinsic Barriers

(2009) Christopher R. Waidmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acidity of Several Anilinium Derivatives in Pure Tetrahydrofuran

(2008) Gemma Garrido et al.   JOURNAL OF SOLUTION CHEMISTRY