Dual Catalysis Relay: Coupling of Aldehydes and Alkenes Enabled by Visible-Light and NHC-Catalyzed Cross-Double C–H Functionalizations

Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling

(2021) Stavros K. Kariofillis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carbene-Catalyzed Alkylation of Carboxylic Esters via Direct Photoexcitation of Acyl Azolium Intermediates

(2021) Shi-Chao Ren et al.   ACS Catalysis

Catalytic Generation of Carbanions through Carbonyl Umpolung

(2021) Shun Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct α-Acylation of Alkenes via N-Heterocyclic Carbene, Sulfinate, and Photoredox Cooperative Triple Catalysis

(2021) Kun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzylic C−H acylation by cooperative NHC and photoredox catalysis

(2021) Qing-Yuan Meng et al.   Nature Communications

Aryl radical-mediated N-heterocyclic carbene catalysis

(2021) Yuki Matsuki et al.   Nature Communications

N‐Heterocyclic Carbene Catalyzed Photooxidation: Intramolecular Cross Dehydrogenative Coupling of Tetrahydroisoquinoline‐Tethered Aldehydes

(2020) Zhong-Hua Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

Combined Photoredox and Carbene Catalysis for the Synthesis of Ketones from Carboxylic Acids

(2020) Karl Scheidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Methods Driven by the Photoactivity of Electron-Donor Acceptor Complexes

(2020) Giacomo E. M. Crisenza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

NHC-Catalyzed Radical Trifluoromethylation Enabled by Togni Reagent

(2020) Bei Zhang et al.   ORGANIC LETTERS

Photo/N-Heterocyclic Carbene Co-catalyzed Ring Opening and γ-Alkylation of Cyclopropane Enal

(2020) Lei Dai et al.   ORGANIC LETTERS

Visible Light-Driven Radical-Mediated C–C Bond Cleavage/Functionalization in Organic Synthesis

(2020) Xiao-Ye Yu et al.   CHEMICAL REVIEWS

N ‐Heterocyclic carbene organocatalysis: activation modes and typical reactive intermediates

(2020) Xingkuan Chen et al.   CHINESE JOURNAL OF CHEMISTRY

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls

(2020) Kenji Ota et al.   ORGANIC LETTERS

Stereoinduction in Metallaphotoredox Catalysis

(2020) Alexander Lipp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative NHC and Photoredox Catalysis for the Synthesis of β‐Trifluoromethylated Alkyl Aryl Ketones

(2020) Qing-Yuan Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bio- and Medicinally Compatible α-Amino-Acid Modification via Merging Photoredox and N-Heterocyclic Carbene Catalysis

(2020) Ding Du et al.   ORGANIC LETTERS

N-Heterocyclic Carbene-Based Catalysis Enabling Cross-Coupling Reactions

(2020) Hirohisa Ohmiya   ACS Catalysis

Direct Synthesis of Dialkyl Ketones from Aliphatic Aldehydes through Radical N-Heterocyclic Carbene Catalysis

(2020) Yuki Kakeno et al.   ACS Catalysis

Catalytic, Metal-Free Amide Synthesis from Aldehydes and Imines Enabled by a Dual-Catalyzed Umpolung Strategy under Redox-Neutral Conditions

(2020) Ming-Shang Liu et al.   ACS Catalysis

Organocatalytic Three-Component 1,2-Cyanoalkylacylation of Alkenes via Radical Relay

(2020) Yu Gao et al.   ORGANIC LETTERS

Photoredox-catalyzed branch-selective pyridylation of alkenes for the expedient synthesis of Triprolidine

(2019) Shengqing Zhu et al.   Nature Communications

N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Breslow Intermediates from a Thiazolin-2-ylidene and Fluorinated Aldehydes: First XRD Characterization, and Solution Phase NMR

(2019) Albrecht Berkessel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

En Route to Intermolecular Cross-Dehydrogenative Coupling Reactions

(2019) Chia-Yu Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes

(2019) Takuya Ishii et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Driven N-Heterocyclic Carbene Catalyzed γ- and ϵ -Alkylation with Alkyl Radicals

(2019) Lei Dai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Acylfluoroalkylation of Olefins through N-Heterocyclic Carbene Organocatalysis

(2019) Jun-Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Catalyzed Photoenolization/Diels-Alder Reaction of Acid Fluorides

(2019) Andreas Mavroskoufis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC‐catalyzed Redox‐Neutral Aza‐Benzoin Reaction of Aldehydes with Tetrahydroisoquinolines

(2019) Di Jiang et al.   CHINESE JOURNAL OF CHEMISTRY

Energy transfer catalysis mediated by visible light: principles, applications, directions

(2018) Felix Strieth-Kalthoff et al.   CHEMICAL SOCIETY REVIEWS

Direct arylation of strong aliphatic C–H bonds

(2018) Ian B. Perry et al.   NATURE

A Toolbox Approach To Construct Broadly Applicable Metal-Free Catalysts for Photoredox Chemistry: Deliberate Tuning of Redox Potentials and Importance of Halogens in Donor–Acceptor Cyanoarenes

(2018) Elisabeth Speckmeier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?

(2018) Vianney Regnier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible light-driven organic photochemical synthesis in China

(2018) Yiyun Chen et al.   Science China-Chemistry

Recent advancements in dehydrogenative cross coupling reactions for CC bond formation

(2017) Begur Vasanthkumar Varun et al.   TETRAHEDRON LETTERS

Trimerization of enones under air enabled by NHC/NaOtBu via a SET radical pathway

(2017) Yuexia Zhang et al.   Organic Chemistry Frontiers

N-Heterocyclic Carbene Catalyzed γ-Dihalomethylenation of Enals by Single-Electron Transfer

(2016) Wen Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis and Activation with N-Heterocyclic Carbenes

(2016) Michael H. Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photochemical Approaches to Complex Chemotypes: Applications in Natural Product Synthesis

(2016) Markus D. Kärkäs et al.   CHEMICAL REVIEWS

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Dual Catalysis Strategies in Photochemical Synthesis

(2016) Kazimer L. Skubi et al.   CHEMICAL REVIEWS

Carbene-catalysed reductive coupling of nitrobenzyl bromides and activated ketones or imines via single-electron-transfer process

(2016) Bao-Sheng Li et al.   Nature Communications

Exploration of New Chemical Reactivities for Sustainable Molecular Transformations

(2016) Chao-Jun Li   Chem

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

(2015) Darrin M. Flanigan et al.   CHEMICAL REVIEWS

Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals

(2015) Nicholas A. White et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Catalysis Sees the Light: Combining Photoredox with Organo-, Acid, and Transition-Metal Catalysis

(2014) Matthew N. Hopkinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Oxidative coupling reactions for the functionalisation of C–H bonds using oxygen

(2014) Naeem Gulzar et al.   Catalysis Science & Technology

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

(2013) Christopher K. Prier et al.   CHEMICAL REVIEWS

Catalytic Asymmetric α-Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N-Heterocyclic Carbene and Photoredox Catalysis

(2012) Daniel A. DiRocco et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Cross-Dehydrogenative Coupling (CDC): Exploring C−C Bond Formations beyond Functional Group Transformations

(2008) Chao-Jun Li   ACCOUNTS OF CHEMICAL RESEARCH