Recent Advances in Nonprecious Metal Catalysis

Chiral Alkyl Amine Synthesis via Catalytic Enantioselective Hydroalkylation of Enecarbamates

(2021) Deyun Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C–H Amination Catalyzed by Nickel Iminyl Complexes Supported by Anionic Bisoxazoline (BOX) Ligands

(2021) Yuyang Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-catalysed synthesis and chemical recycling of telechelic 1,3-enchained oligocyclobutanes

(2021) Megan Mohadjer Beromi et al.   Nature Chemistry

Regio-, Chemo-, and Enantioselective Ni-Catalyzed Hydrocyanation of 1,3-Dienes

(2021) Rongrong Yu et al.   ORGANIC LETTERS

Copper-Catalyzed Formal [3 + 3] Annulations of Arylketoximes and o-Fluorobenzaldehydes: An Entry to Quinoline Compounds

(2021) Zhenhua Xu et al.   ORGANIC LETTERS

Cu(I)-Catalyzed [2 + 2 + 1] Cycloaddition of Amines, Alkynes, and Ketenes: An Umpolung and Regioselective Approach to Full-Substituted β-Pyrrolinones

(2021) Hao Wu et al.   ORGANIC LETTERS

Cu-Enabled [3 + 2] Annulation of In Situ Formed Nitrile Ylides with Aryldiazonium Salts: Access to 5-Cyano-1,2,4-Triazoles

(2021) Lu-Nan Zhou et al.   ORGANIC LETTERS

Iron-Catalyzed Vinylsilane Dimerization and Cross-Cycloadditions with 1,3-Dienes: Probing the Origins of Chemo- and Regioselectivity

(2021) C. Rose Kennedy et al.   ACS Catalysis

Nickel‐Catalyzed Regioselective Arylboration of Conjugated Dienes

(2021) Haoyang Li et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The Asymmetric Synthesis of Amines via Nickel-Catalyzed Enantioconvergent Substitution Reactions

(2021) Ze-Peng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl Halides

(2021) Zijian Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed α,β-Dehydrogenation of Carbonyl Compounds

(2021) Xiao-Wei Zhang et al.   ORGANIC LETTERS

Synthesis of N-Alkyl Anilines from Arenes via Iron-Promoted Aromatic C–H Amination

(2021) Eric Falk et al.   ORGANIC LETTERS

Using Chlorotrifluoroethane for Trifluoroethylation of (Hetero)aryl Bromides and Chlorides via Nickel Catalysis

(2021) Xuefei Li et al.   ORGANIC LETTERS

Recent Advances in Nonprecious Metal Catalysis

(2021) Frederic Buono et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Sulfinamide Synthesis Using Organometallic Reagents, DABSO, and Amines

(2020) Pui Kin Tony Lo et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient C-H amination catalysis using nickel-dipyrrin complexes

(2020) Yuyang Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Synthesis of Tetrasubstituted 2,3-Allenols through Decarboxylative Silylation of Alkyne-Substituted Cyclic Carbonates

(2020) Kun Guo et al.   ORGANIC LETTERS

Recent Advances in Nonprecious Metal Catalysis

(2020) Robert A. Singer et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Chemical recycling to monomer for an ideal, circular polymer economy

(2020) Geoffrey W. Coates et al.   Nature Reviews Materials

Design and scalable synthesis of novel N‐alkyl‐hydroxylamine reagents for the direct, Fe‐catalyzed installation of medicinally relevant amines

(2020) Eric Falk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective Cross-Coupling of gem-Borazirconocene Alkanes with Aryl Halides

(2020) Chao Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Ni-Catalyzed Radical Relayed Reductive Coupling

(2020) Xiaofeng Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand‐Controlled Regiodivergence in Nickel‐Catalyzed Hydroarylation and Hydroalkenylation of Alkenyl Carboxylic Acids

(2020) Zi‐Qi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel‐Catalyzed Migratory Hydrocyanation of Internal Alkenes: Unexpected Diastereomeric‐Ligand‐Controlled Regiodivergence

(2020) Jihui Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroxylamine‐derived Reagent as a Dual Oxidant and Amino Group Donor for the Iron Catalyzed Preparation of Unprotected Sulfinamides from Thiols

(2020) Sayanti Chatterjee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel‐Catalyzed Asymmetric Synthesis of α‐Arylbenzamides

(2020) Sergio Cuesta-Galisteo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive Arylation of Amides via a Nickel‐Catalyzed Suzuki–Miyaura Coupling and Transfer Hydrogenation Cascade

(2020) Timothy Boit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of a Green and Sustainable Manufacturing Process for Gefapixant Citrate (MK-7264) Part 2: Development of a Robust Process for Phenol Synthesis

(2020) Feng Peng et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

A Widely Applicable Dual Catalytic System for Cross-Electrophile Coupling Enabled by Mechanistic Studies

(2020) David J. Charboneau et al.   ACS Catalysis

Efficient Amination of Activated and Non‐Activated C(sp 3 )−H Bonds with a Simple Iron–Phenanthroline Catalyst

(2020) Lucie Jarrige et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Robust Iron Catalyst System for Intramolecular C(sp 3 )−H Amidation Leading to γ‐Lactams

(2020) Jeonguk Kweon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intermolecular Heck and Reductive Heck Reactions of Aryl Triflates, Mesylates, and Tosylates Catalyzed by Nickel

(2020) Xiaolei Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Assembly of α‐(Hetero)aryl Nitriles via Cu‐Catalyzed Coupling Reactions with (Hetero)aryl Chlorides and Bromides

(2020) Dawei Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel‐Catalyzed Electrochemical C(sp 3 )−C(sp 2 ) Cross‐Coupling Reactions of Benzyl Trifluoroborate and Organic Halides**

(2020) Jian Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electro‐Reductive Nickel‐Catalyzed Thiolation: Efficient Cross‐Electrophile Coupling for C–S Formation

(2020) Nate W. J. Ang et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Validated “Pool and Split” Approach to Screening and Optimization of Copper-Catalyzed C–N Cross-Coupling Reactions

(2020) Raphael R. Steimbach et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Decarboxylative [3 + 2] Annulation of Ethynylethylene Carbonates with Azlactones: Access to γ-Butyrolactones Bearing Two Vicinal Quaternary Carbon Centers

(2020) Wen-Ya Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Synthesis of Unprotected 2-Azidoamines from Alkenes via an Iron-Catalyzed Difunctionalization Reaction

(2020) Szabolcs Makai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselective Construction of Spirocycles by Nickel-Catalyzed Cascade Borrowing Hydrogen Cyclization

(2020) Zhengtian Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Cross-Electrophile Arylation of Benzyl Alcohols by Nickel Catalysis

(2020) Peng Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis

(2020) Lei Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C(sp3)–C(sp3) cross-coupling of non-activated alkyl electrophiles via nickel hydride catalysis

(2020) Srikrishna Bera et al.   Nature Chemistry

Nickel-Catalyzed Directed Cross-Electrophile Coupling of Phenolic Esters with Alkyl Bromides

(2020) Feiyan Yang et al.   ORGANIC LETTERS

Alkyl halides as both hydride and alkyl sources in catalytic regioselective reductive olefin hydroalkylation

(2020) Xianxiao Chen et al.   Nature Communications

Nickel-Catalyzed Vinylidene Insertions into O–H Bonds

(2020) Houng Kang et al.   ACS Catalysis

100th Anniversary of Macromolecular Science Viewpoint: Redefining Sustainable Polymers

(2020) Danielle E. Fagnani et al.   ACS Macro Letters

Copper-Catalyzed Enantioselective Construction of Tertiary Propargylic Sulfones

(2019) José Enrique Gómez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemically Promoted Nickel-Catalyzed Carbon–Sulfur Bond Formation

(2019) Yang Wang et al.   ACS Catalysis

Catalytic reductive [4 + 1]-cycloadditions of vinylidenes and dienes

(2019) You-Yun Zhou et al.   SCIENCE

Modification and Biological Evaluation of a Series of 1,5-Diaryl-1,2,4-triazole Compounds as Novel Agents against Pancreatic Cancer Metastasis through Targeting Myoferlin

(2019) Yunqi Li et al.   JOURNAL OF MEDICINAL CHEMISTRY

Nickel-Catalyzed Regioselective Hydroalkylation and Hydroarylation of Alkenyl Boronic Esters

(2019) Srikrishna Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene/Copper Cooperative Catalysis for the Asymmetric Synthesis of Spirooxindoles

(2019) Zi-Jing Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Antibacterial activity study of 1,2,4-triazole derivatives

(2019) Feng Gao et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Base-Mediated Meerwein–Ponndorf–Verley Reduction of Aromatic and Heterocyclic Ketones

(2019) Timothy B. Boit et al.   ORGANIC LETTERS

Nondissociative Chain Walking As a Strategy in Catalytic Organic Synthesis

(2019) Takuya Kochi et al.   TETRAHEDRON LETTERS

Ligand-Controlled Regiodivergent Hydroalkylation of Pyrrolines

(2019) Deyun Qian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Difunctionalization of Alkenes Involving Metal Migration

(2019) Yuqiang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective formation of γ-lactams via C–H amidation enabled by tailored iridium catalysts

(2018) Seung Youn Hong et al.   SCIENCE

Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides

(2018) Yi Fang et al.   Nature Communications

Walking Metals for Remote Functionalization

(2018) Heiko Sommer et al.   ACS Central Science

Copper-Catalyzed Enantioselective Synthesis of β-Amino Alcohols Featuring Tetrasubstituted Tertiary Carbons

(2018) Lan Tian et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective [3 + 2] Cycloaddition Reaction of Ethynylethylene Carbonates with Malononitrile Enabled by Organo/Metal Cooperative Catalysis

(2018) Yu-Chen Zhang et al.   ORGANIC LETTERS

Efficient access to unprotected primary amines by iron-catalyzed aminochlorination of alkenes

(2018) Luca Legnani et al.   SCIENCE

Understanding the Insertion Pathways and Chain Walking Mechanisms of α-Diimine Nickel Catalysts for α-Olefin Polymerization: A 13C NMR Spectroscopic Investigation

(2017) Kyle S. O’Connor et al.   MACROMOLECULES

Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide

(2017) Francisco Juliá-Hernández et al.   NATURE

Electrochemical Nickel Catalysis for Sp2-Sp3 Cross-Electrophile Coupling Reactions of Unactivated Alkyl Halides

(2017) Robert J. Perkins et al.   ORGANIC LETTERS

A Ligand-Directed Catalytic Regioselective Hydrocarboxylation of Aryl Olefins with Pd and Formic Acid

(2017) Wei Liu et al.   ORGANIC LETTERS

Selectivity Control in Ruthenium(II)-Catalyzed C–H/N–O Activation with Alkynyl Bromides

(2017) Huawen Huang et al.   ORGANIC LETTERS

Enantioselective Nickel-Catalyzed Mizoroki–Heck Cyclizations To Generate Quaternary Stereocenters

(2017) Jean-Nicolas Desrosiers et al.   ORGANIC LETTERS

Catalyst: Sustainable Catalysis

(2017) Jacob R. Ludwig et al.   Chem

Nickel Hydride Complexes

(2016) Nathan A. Eberhardt et al.   CHEMICAL REVIEWS

Remote functionalization through alkene isomerization

(2016) Alexandre Vasseur et al.   Nature Chemistry

Harnessing Complex Mixtures for Catalyst Discovery

(2016) Joseph Moran et al.   SYNLETT

Direct and Practical Synthesis of Primary Anilines through Iron-Catalyzed C–H Bond Amination

(2016) Luca Legnani et al.   ACS Catalysis

Nickel-catalysed para-CH activation of pyridine with switchable regioselective hydroheteroarylation of allylarenes

(2015) Wei-Chih Lee et al.   CHEMICAL COMMUNICATIONS

Formal [4+1] Annulation Reactions in the Synthesis of Carbocyclic and Heterocyclic Systems

(2015) Jia-Rong Chen et al.   CHEMICAL REVIEWS

Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?

(2015) Dean G. Brown et al.   JOURNAL OF MEDICINAL CHEMISTRY

Nickel-catalysed Suzuki–Miyaura coupling of amides

(2015) Nicholas A. Weires et al.   Nature Chemistry

Spotlight on Non-Precious Metal Catalysis

(2015) Joshua R. Dunetz et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Secondary Alkene Insertion and Precision Chain-Walking: A New Route to Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare Catalytic Events

(2014) Tulaza Vaidya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in the synthesis of quinolines: a review

(2014) Shraddha M. Prajapati et al.   RSC Advances

Mechanism and Selectivity in Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Halides with Alkyl Halides

(2013) Soumik Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Isomerization and C–H Activation: Regioselective Hydroheteroarylation of Allylarenes

(2013) Wei-Chih Lee et al.   ORGANIC LETTERS

Cationic Ruthenium Catalysts for Alkyne Annulations with Oximes by C–H/N–O Functionalizations

(2012) Christoph Kornhaaß et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Regioselective Synthesis of Pyridines from Alkenes and α,β-Unsaturated Oxime Esters

(2012) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Highly Regioselective Cyclization of Ketoximes with Alkynes by C–H Bond Activation: A Practical Route to Synthesize Substituted Isoquinolines

(2012) Ravi Kiran Chinnagolla et al.   ORGANIC LETTERS

Activation of “Inert” Alkenyl/Aryl CO Bond and Its Application in Cross-Coupling Reactions

(2011) Bi-Jie Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium-Catalyzed Isoquinolone Synthesis through CH Activation Using an Oxidizing Directing Group

(2011) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh(III)-Catalyzed Directed C−H Olefination Using an Oxidizing Directing Group: Mild, Efficient, and Versatile

(2011) Souvik Rakshit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed C–H/N–O Bond Functionalization: Green Isoquinolone Syntheses in Water

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Synthesis ofN-Substituted 1,2,4-Triazoles. A Review

(2011) Stefanie C. Holm et al.   ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover

(2010) Nicolas Guimond et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(I)-Catalyzed Huisgen Azide−Alkyne 1,3-Dipolar Cycloaddition Reaction in Nucleoside, Nucleotide, and Oligonucleotide Chemistry

(2009) Franck Amblard et al.   CHEMICAL REVIEWS

Transition Metal-Catalyzed Living Radical Polymerization: Toward Perfection in Catalysis and Precision Polymer Synthesis

(2009) Makoto Ouchi et al.   CHEMICAL REVIEWS

Synthesis of α-Hydroxyallenes by Copper-Catalyzed SN2′ Substitution of Propargylic Dioxolanones

(2009) Xiaoping Tang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Diels−Alder Reactions

(2008) Sébastien Reymond et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed 1,3-Dipolar Cycloadditions

(2008) Levi M. Stanley et al.   CHEMICAL REVIEWS