Confinement-Controlled, Either syn- or anti-Selective Catalytic Asymmetric Mukaiyama Aldolizations of Propionaldehyde Enolsilanes

Catalytic Asymmetric Synthesis of Unprotected β2-Amino Acids

(2021) Chendan Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Silicon–Hydrogen Exchange Reaction: A Catalytic σ-Bond Metathesis Approach to the Enantioselective Synthesis of Enol Silanes

(2020) Hui Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantiocontrol over a non-classical carbocation

(2020) Roberta Properzi et al.   Nature Chemistry

Confinement as a Unifying Element in Selective Catalysis

(2020) Benjamin Mitschke et al.   Chem

Acetaldehyde Silyl Enol Ethers in Enantioselective Mukaiyama Aldol Reactions: Enzyme-Like Organocatalysis in Action

(2019) Luca Dell'Amico et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

IDPi Catalysis

(2019) Benjamin List et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Asymmetric Mukaiyama-Michael Reaction of Silyl Ketene Acetals with α,β-Unsaturated Methyl Esters

(2018) Tim Gatzenmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Approaching sub-ppm-level asymmetric organocatalysis of a highly challenging and scalable carbon–carbon bond forming reaction

(2018) Han Yong Bae et al.   Nature Chemistry

Discovery of Presaccharothriolide X, a Retro-Michael Reaction Product of Saccharothriolide B, from the Rare Actinomycete Saccharothrix sp. A1506

(2018) Shan Lu et al.   ORGANIC LETTERS

Scalable and Highly Diastereo- and Enantioselective Catalytic Diels–Alder Reaction of α,β-Unsaturated Methyl Esters

(2018) Tim Gatzenmeier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Confined acids catalyze asymmetric single aldolizations of acetaldehyde enolates

(2018) Lucas Schreyer et al.   SCIENCE

Difluoromethyl Bioisostere: Examining the “Lipophilic Hydrogen Bond Donor” Concept

(2017) Yossi Zafrani et al.   JOURNAL OF MEDICINAL CHEMISTRY

CF2H, a Hydrogen Bond Donor

(2017) Chanan D. Sessler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergence in Asymmetric Catalysis

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Nannocystin Ax

(2017) Caroline Poock et al.   ORGANIC LETTERS

Second Generation of Aldol Reaction

(2016) Wafa Gati et al.   ACCOUNTS OF CHEMICAL RESEARCH

Antarlides: A New Type of Androgen Receptor (AR) Antagonist that Overcomes Resistance to AR-Targeted Therapy

(2016) Shun Saito et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Extremely Active Organocatalysts Enable a Highly Enantioselective Addition of Allyltrimethylsilane to Aldehydes

(2016) Philip S. J. Kaib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development and Applications of Disulfonimides in Enantioselective Organocatalysis

(2015) Thomas James et al.   CHEMICAL REVIEWS

Catalytic Asymmetric Iterative/Domino Aldehyde Cross-Aldol Reactions for the Rapid and Flexible Synthesis of 1,3-Polyols

(2015) Luqing Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diisopinocampheylborane-Mediated Reductive Aldol Reactions: Highly Enantio- and Diastereoselective Synthesis ofsynAldols fromN-Acryloylmorpholine

(2013) Philippe Nuhant et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Mukaiyama Aldol Reaction: 40 Years of Continuous Development

(2013) Jun-ichi Matsuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Impact of the Mukaiyama Aldol Reaction in Total Synthesis

(2013) S. B. Jennifer Kan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid and Stereochemically Flexible Synthesis of Polypropionates: Super-Silyl-Governed Aldol Cascades

(2012) Patrick B. Brady et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

A More Comprehensive and Highly Practical Solution to Enantioselective Aldehyde Crotylation

(2011) Hyunwoo Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Relevance of Weak Hydrogen Bonds in the Conformation of Organic Compounds and Bioconjugates: Evidence from Recent Experimental Data and High-Levelab InitioMO Calculations

(2010) Osamu Takahashi et al.   CHEMICAL REVIEWS

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

(2009) Pilar García-García et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox Economy in Organic Synthesis

(2009) Noah Z. Burns et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

anti-Diastereo- and Enantioselective Carbonyl Crotylation from the Alcohol or Aldehyde Oxidation Level Employing a Cyclometallated Iridium Catalyst: α-Methyl Allyl Acetate as a Surrogate to Preformed Crotylmetal Reagents

(2009) In Su Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis at the molecular frontier

(2009) Paul A. Wender et al.   NATURE

Design and synthesis of ansamycin antibiotics

(2008) Iwona E. Wrona et al.   COMPTES RENDUS CHIMIE

Cebulactams A1 and A2, new macrolactams isolated from Saccharopolyspora cebuensis, the first obligate marine strain of the genus Saccharopolyspora

(2008) Sheila Marie Pimentel-Elardo et al.   TETRAHEDRON LETTERS