Emergence of Coupled Rotor Dynamics in Metal–Organic Frameworks via Tuned Steric Interactions

Molecular Rotor‐Driven Advanced Porous Materials

(2021) Jinqiao Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Future of Molecular Machines

(2020) Ivan Aprahamian   ACS Central Science

Enhanced Rotation by Ground State Destabilization in Amphidynamic Crystals of a Dipolar 2,3-Difluorophenylene Rotator as Established by Solid State 2H NMR and Dielectric Spectroscopy

(2020) Ieva Liepuoniute et al.   Journal of Physical Chemistry C

Fast motion of molecular rotors in metal–organic framework struts at very low temperatures

(2020) Jacopo Perego et al.   Nature Chemistry

Rotational Dynamics of Linkers in Metal–Organic Frameworks

(2019) Adrian Gonzalez-Nelson et al.   Nanomaterials

Unidirectional rotary motion in a metal–organic framework

(2019) Wojciech Danowski et al.   Nature Nanotechnology

Screening Diffusion of Small Molecules in Flexible Zeolitic Imidazolate Frameworks Using a DFT-Parameterized Force Field

(2019) Ross J. Verploegh et al.   Journal of Physical Chemistry C

The Roles of Intrinsic Barriers and Crystal Fluidity in Determining the Dynamics of Crystalline Molecular Rotors and Molecular Machines

(2019) Morgan E. Howe et al.   JOURNAL OF ORGANIC CHEMISTRY

Morphing of liquid crystal surfaces by emergent collectivity

(2019) Hanne M. van der Kooij et al.   Nature Communications

The Influence of Chemical Modification on Linker Rotational Dynamics in Metal-Organic Frameworks

(2018) Joshua T. Damron et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting rotational motion in molecular crystals

(2018) Luca Catalano et al.   CRYSTENGCOMM

Low-Frequency Dipolar Dynamics and Atmospheric Effects in ZIF-90 Metal–Organic Framework

(2018) Sergejus Balčiu̅nas et al.   Journal of Physical Chemistry C

Liquid-Phase Multicomponent Adsorption and Separation of Xylene Mixtures by Flexible MIL-53 Adsorbents

(2017) Mayank Agrawal et al.   Journal of Physical Chemistry C

Porous Metal–Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage

(2017) Yong Yan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Influence of Intrinsic Framework Flexibility on Adsorption in Nanoporous Materials

(2017) Matthew Witman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Liquid metal–organic frameworks

(2017) Romain Gaillac et al.   NATURE MATERIALS

Detecting Molecular Rotational Dynamics Complementing the Low-Frequency Terahertz Vibrations in a Zirconium-Based Metal-Organic Framework

(2017) Matthew R. Ryder et al.   PHYSICAL REVIEW LETTERS

Ultrafast rotation in an amphidynamic crystalline metal organic framework

(2017) Cortnie S. Vogelsberg et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Tailoring porosity and rotational dynamics in a series of octacarboxylate metal-organic frameworks

(2017) Florian Moreau et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Defibrillation of soft porous metal-organic frameworks with electric fields

(2017) A. Knebel et al.   SCIENCE

Protein crowding and lipid complexity influence the nanoscale dynamic organization of ion channels in cell membranes

(2017) Anna L. Duncan et al.   Scientific Reports

Molecular Rotors Built in Porous Materials

(2016) Angiolina Comotti et al.   ACCOUNTS OF CHEMICAL RESEARCH

The flexibility of modified-linker MIL-53 materials

(2016) Alexis S. Munn et al.   DALTON TRANSACTIONS

Ultraslow Dynamics of a Framework Linker in MIL-53 (Al) as a Sensor for Different Isomers of Xylene

(2016) Alexander E. Khudozhitkov et al.   Journal of Physical Chemistry C

Understanding the Kinetic and Thermodynamic Origins of Xylene Separation in UiO-66(Zr) via Molecular Simulation

(2016) Matthew J. Lennox et al.   Journal of Physical Chemistry C

Crystal Fluidity Reflected by Fast Rotational Motion at the Core, Branches, and Peripheral Aromatic Groups of a Dendrimeric Molecular Rotor

(2016) Xing Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Framework Flexibility on C8 Aromatic Adsorption at High Loadings in Metal–Organic Frameworks

(2015) Jason A. Gee et al.   Journal of Physical Chemistry C

Metal-Cation-Independent Dynamics of Phenylene Ring in Microporous MOFs: A 2H Solid-State NMR Study

(2015) Alexander E. Khudozhitkov et al.   Journal of Physical Chemistry C

Hydrothermal Breakdown of Flexible Metal–Organic Frameworks: A Study by First-Principles Molecular Dynamics

(2015) Volker Haigis et al.   Journal of Physical Chemistry Letters

Guest Controlled Rotational Dynamics of Terephthalate Phenylenes in Metal–Organic Framework MIL-53(Al): Effect of Different Xylene Loadings

(2014) Daniil I. Kolokolov et al.   Journal of Physical Chemistry C

Solid-State NMR in Macromolecular Systems: Insights on How Molecular Entities Move

(2013) Michael Ryan Hansen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Crystalline Arrays of Pairs of Molecular Rotors: Correlated Motion, Rotational Barriers, and Space-Inversion Symmetry Breaking Due to Conformational Mutations

(2013) Cyprien Lemouchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure and Dynamics of the Functionalized MOF Type UiO-66(Zr): NMR and Dielectric Relaxation Spectroscopies Coupled with DFT Calculations

(2012) Sabine Devautour-Vinot et al.   CHEMISTRY OF MATERIALS

Probing the Dynamics of the Porous Zr Terephthalate UiO-66 Framework Using 2H NMR and Neutron Scattering

(2012) D. I. Kolokolov et al.   Journal of Physical Chemistry C

NH2-MIL-53(Al): A High-Contrast Reversible Solid-State Nonlinear Optical Switch

(2012) Pablo Serra-Crespo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phenyl Ring Dynamics in a Tetraphenylethylene-Bridged Metal–Organic Framework: Implications for the Mechanism of Aggregation-Induced Emission

(2012) Natalia B. Shustova et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystalline molecular machines: function, phase order, dimensionality, and composition

(2011) Cortnie S. Vogelsberg et al.   CHEMICAL SOCIETY REVIEWS

New Functionalized Flexible Al-MIL-53-X (X = -Cl, -Br, -CH3, -NO2, -(OH)2) Solids: Syntheses, Characterization, Sorption, and Breathing Behavior

(2011) Shyam Biswas et al.   INORGANIC CHEMISTRY

High-Resolution Solid-State2H NMR Spectroscopy of Polymorphs of Glycine

(2011) Abil E. Aliev et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Complexity behind CO2Capture on NH2-MIL-53(Al)

(2011) Eli Stavitski et al.   LANGMUIR

Dynamics of Benzene Rings in MIL-53(Cr) and MIL-47(V) Frameworks Studied by 2H NMR Spectroscopy

(2010) Daniil I. Kolokolov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Relaxation Processes in a MOF-5 Structure Revealed by Broadband Dielectric Spectroscopy: Signature of Phenylene Ring Fluctuations

(2010) Stefan Frunza et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Robust dynamics

(2010) Hexiang Deng et al.   Nature Chemistry

Reversible Structural Transition in MIL-53 with Large Temperature Hysteresis

(2008) Yun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amphidynamic Character of Crystalline MOF-5:  Rotational Dynamics of Terephthalate Phenylenes in a Free-Volume, Sterically Unhindered Environment

(2008) Stephanie L. Gould et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Membrane lipids: where they are and how they behave

(2008) Gerrit van Meer et al.   NATURE REVIEWS MOLECULAR CELL BIOLOGY

Dipolar molecular rotors in the metal–organic framework crystal IRMOF-2

(2008) Erick B. Winston et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Conformational polymorphism in a heteromolecular single crystal leads to concerted movement akin to collective rack-and-pinion gears at the molecular level

(2008) A. N. Sokolov et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA