4.7 Article

Effect of lipids with different physical state on the physicochemical properties of starch/gelatin edible films prepared by extrusion blowing

Journal

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
Volume 185, Issue -, Pages 1005-1014

Publisher

ELSEVIER
DOI: 10.1016/j.ijbiomac.2021.06.203

Keywords

Starch; Gelatin; Lipids; Edible film; Extrusion blowing

Funding

  1. Great Innovation Program of Agricul-tural Application Technology in Shandong Province
  2. Key Technol-ogy Research and Development Program of Shandong province [2019GNC106035]
  3. Natural Science Foundation of Shandong Province [ZR2020QC222]
  4. Natural Science Foundation of Tianjin City [18JCQNJC84200]
  5. Funds of Shandong Double Tops Program

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Different physical state lipids (rapeseed oil, shortening, beeswax) have varied effects on the physicochemical properties of starch/gelatin blown films, with rapeseed oil promoting starch melting and fracturing while beeswax and shortening inhibit hydrogen bond formation. The addition of lipids enhances surface hydrophobicity, strength, and water resistance properties of the films.
The effects of various physical state lipids (rapeseed oil (RO), shortening (ST), beeswax (BW)), on the physicochemical properties of starch (S) (hydroxypropyl distarch phosphate (HP), oxidized hydroxypropyl starch (OS))/gelatin (G) blown films were studied. S/G-lipid blends showed decreased storage modulus and complex viscosity. The formation of hydrogen bonds was inhibited by the ST and BW, but facilitated by the RO. Compared with BW and ST, RO was more effective to promote the melted and fractured of starch. Lipids addition promoted the compatibility of starch and gelatin. The presence of the lipids significantly improved the surface hydrophobicity, mechanical, water vapor barrier and water resistance properties of S/G films. S/G-RO films exhibited the strongest surface hydrophobicity and tensile strength, while HP/G-BW film showed the strongest water resistance and water vapor barrier properties. These results revealed that the appropriate lipids could be used to produce S/G-lipid films with desirable physicochemical properties.

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