Generation of Diazomethyl Radicals by Hydrogen Atom Abstraction and Their Cycloaddition with Alkenes

Visible Light‐Induced [3+2] Cyclization Reactions of Hydrazones with Hypervalent Iodine Diazo Reagents for the Synthesis of 1‐Amino‐1,2,3‐Triazoles

(2021) Jun‐Ying Dong et al.   ADVANCED SYNTHESIS & CATALYSIS

Polarity Umpolung Strategy for the Radical Alkylation of Alkenes

(2020) Jige Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Oxidative Cleavage Reactions of Arylalkenes by tert-Butyl Hydroperoxide – A Mechanistic Assessment

(2020) Yong-Liang Su et al.   JOURNAL OF ORGANIC CHEMISTRY

α-Amino Radicals via Photocatalytic Single-Electron Reduction of Imine Derivatives

(2020) Jamie A. Leitch et al.   ACS Catalysis

Predicting Absolute Rate Constants for Huisgen Reactions of Unsaturated Iminium Ions with Diazoalkanes

(2020) Jingjing Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Huisgen Reaction: Milestones of the 1,3‐Dipolar Cycloaddition

(2020) Martin Breugst et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical-Mediated Strategies for the Functionalization of Alkenes with Diazo Compounds

(2020) Yong-Liang Su et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron: a worthy contender in metal carbene chemistry

(2020) Vasco Figueiredo Batista et al.   ACS Catalysis

2,2,2-Trifluorodiazoethane (CF3CHN2): A Long Journey since 1943

(2020) Pavel K. Mykhailiuk   CHEMICAL REVIEWS

Recent Advances in Iron‐Catalyzed Chemical and Enzymatic Carbene‐Transfer Reactions

(2020) Parmjeet Kaur et al.   ADVANCED SYNTHESIS & CATALYSIS

α‐Diazo Sulfonium Triflates: Synthesis, Structure and Application to the Synthesis of 1‐(Dialkylamino)‐1,2,3‐triazoles

(2020) Manuel Alcarazo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox Catalysis Enables Decarboxylative Cyclization with Hypervalent Iodine(III) Reagents: Access to 2,5-Disubstituted 1,3,4-Oxadiazoles

(2020) Jian Li et al.   ORGANIC LETTERS

Sustainable Carbene Transfer Reactions with Iron and Light

(2019) Claire Empel et al.   SYNLETT

Design, synthesis and biological evaluation of a new series of thiazolyl-pyrazolines as dual EGFR and HER2 inhibitors

(2019) Belgin Sever et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Generation of Halomethyl Radicals by Halogen Atom Abstraction and Their Addition Reactions with Alkenes

(2019) Robynne K. Neff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinuclear Manganese(II), Cobalt(II), and Nickel(II) Aryl Phosphates Incorporating 4′-Chloro-2,2′:6′,2′′-Terpyridine Coligands - Efficient Catalysts for Alcohol Oxidation

(2018) Gulzar A. Bhat et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Comprehensive Review on Recent Developments in the Field of Biological Applications of Potent Pyrazolines Derived from Chalcone Precursors

(2018) Vinutha V. Salian et al.   Letters in Drug Design & Discovery

Reactive carbon species tamed for synthesis

(2018) Rohan E. J. Beckwith   NATURE

Generating carbyne equivalents with photoredox catalysis

(2018) Zhaofeng Wang et al.   NATURE

Transition-Metal-Free [3 + 2] Cycloaddition of Nitroolefins and Diazoacetonitrile: A Facile Access to Multisubstituted Cyanopyrazoles

(2018) Zhen Chen et al.   ORGANIC LETTERS

An Efficient Synthesis of Substituted Pyrazoles from One-Pot Reaction of Ketones, Aldehydes, and Hydrazine Monohydrochloride

(2018) Vit Lellek et al.   SYNLETT

Iodine-catalyzed diazo activation to access radical reactivity

(2018) Pan Li et al.   Nature Communications

Nickel Catalyzed Ipso-hydroxylation and Subsequent Cross Dehydrogenative Coupling of Arylboronic Acids with Tertiary Amines: A Facile Access to α-phenolated Tertiary Amines

(2018) Promod Kumar et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis of Tetrahydroindolizines by Bimetallic Relay Catalyzed Cycloaddition of Pyridinium Ylides

(2018) Dong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleophilicity and Electrophilicity Parameters for Predicting Absolute Rate Constants of Highly Asynchronous 1,3-Dipolar Cycloadditions of Aryldiazomethanes

(2018) Harish Jangra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Radical Difunctionalization of Simple Alkenes

(2017) Xing-Wang Lan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Difluoro- and trifluoro diazoalkanes – complementary approaches in batch and flow and their application in cycloaddition reactions

(2017) Katharina J. Hock et al.   GREEN CHEMISTRY

Enantioselective Cyclopropanation of a Wide Variety of Olefins Catalyzed by Ru(II)–Pheox Complexes

(2016) Soda Chanthamath et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cobalt(i)-catalysed CH-alkylation of terminal olefins, and beyond

(2016) Maciej Giedyk et al.   CHEMICAL COMMUNICATIONS

Gold-catalyzed transformations of α-diazocarbonyl compounds: selectivity and diversity

(2016) Lu Liu et al.   CHEMICAL SOCIETY REVIEWS

Fluoroalkyl-Substituted Diazomethanes and Their Application in a General Synthesis of Pyrazoles and Pyrazolines

(2016) Lucas Mertens et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of CF2H-Substituted Pyrazolines by [3+2] Cycloaddition between CF2HCHN2and Electron-Deficient Alkenes

(2016) Jue Li et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Unprecedented Intramolecular [4 + 2]-Cycloaddition between a 1,3-Diene and a Diazo Ester

(2016) Huang Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Catalysis with Organic Azides and Diazo Compounds Initiated by Photoinduced Electron Transfer

(2016) Xiaoqiang Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[3 + 2] cycloaddition and subsequent oxidative dehydrogenation between alkenes and diazo compounds: a simple and direct approach to pyrazoles using TBAI/TBHP

(2016) Ying Shao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

1,3-Dipolar Cycloadditions of Diazo Compounds in the Presence of Azides

(2016) Matthew R. Aronoff et al.   ORGANIC LETTERS

Cu-based carbene involved in a radical process: a new crossover reaction to construct γ-peroxy esters and 1,4-dicarbonyl compounds

(2015) Jiewen Jiang et al.   CHEMICAL COMMUNICATIONS

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Fe-Catalyzed Olefin Hydroamination with Diazo Compounds for Hydrazone Synthesis

(2015) Jing Zheng et al.   ORGANIC LETTERS

Practical synthesis of pyrazoles via a copper-catalyzed relay oxidation strategy

(2014) Xiaodong Tang et al.   CHEMICAL COMMUNICATIONS

Generation of C2F5CHN2In Situ and Its First Reaction: [3+2] Cycloaddition with Alkenes

(2014) Pavel K. Mykhailiuk    CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Synthesis of CF3-Substituted Pyrazolines/Pyrazoles from Electron-Deficient Alkenes/Alkynes and CF3CHN2Generated in situ: Optimized Synthesis of Tris(trifluoromethyl)pyrazole

(2014) Evgeniy Y. Slobodyanyuk et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of CF3-Containing 3,3′-Cyclopropyl Spirooxindoles by Sequential [3 + 2] Cycloaddition/Ring Contraction of Ylideneoxindoles with 2,2,2-Trifluorodiazoethane

(2014) Tian-Ren Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-catalyzed transformations of diazo compounds

(2014) Shou-Fei Zhu et al.   National Science Review

Novel Multicomponent Reactions via Trapping of Protic Onium Ylides with Electrophiles

(2013) Xin Guo et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Cross-Dehydrogenative Coupling of C sp 3H Bonds: A Versatile Strategy for CC Bond Formations

(2013) Simon A. Girard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic umpolung: N-heterocyclic carbenes and beyond

(2012) Xavier Bugaut et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in the therapeutic applications of pyrazolines

(2012) Mohamed R Shaaban et al.   EXPERT OPINION ON THERAPEUTIC PATENTS

Fe-Catalyzed One-Pot Synthesis of 1,3-Di- and 1,3,5-Trisubstituted Pyrazoles from Hydrazones and Vicinal Diols

(2012) Niranjan Panda et al.   JOURNAL OF ORGANIC CHEMISTRY

Olefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 Enzymes

(2012) P. S. Coelho et al.   SCIENCE

Cyclopropanation Reactions Mediated by Group 9 Metal Porphyrin Complexes

(2011) Daniela Intrieri et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Biological Activity of Chiral Dihydropyrazole: Potential Lead for Drug Design

(2011) X.-H. Liu et al.   MINI-REVIEWS IN MEDICINAL CHEMISTRY

Buchner and Beyond: Arene Cyclopropanation as Applied to Natural Product Total Synthesis

(2011) Sarah Reisman et al.   SYNLETT

Synthetic and biological studies of pyrazolines and related heterocyclic compounds

(2011) Mohamad Yusuf et al.   Arabian Journal of Chemistry

Kinetics of the Solvolyses of Fluoro-Substituted Benzhydryl Derivatives: Reference Electrofuges for the Development of a Comprehensive Nucleofugality Scale

(2010) Christoph Nolte et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalytic enantioselective 1,3-dipolar cycloadditions of alkyl diazoacetates with α,β-disubstituted acroleins

(2009) Lizhu Gao et al.   CHEMICAL COMMUNICATIONS

Application of donor/acceptor-carbenoids to the synthesis of natural products

(2009) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Recent studies on the reactions of α-diazocarbonyl compounds

(2008) Zhenhua Zhang et al.   TETRAHEDRON