Recent Advances in Radical Difunctionalization of Simple Alkenes

Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines

(2017) Jin-Shun Lin et al.   Nature Communications

Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds

(2016) Takashi Koike et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center

(2016) Guoyin Yin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Selective Phosphinylphosphination of Alkenes with Tetraphenyldiphosphine Monoxide

(2016) Yuki Sato et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Formal [2+2+1] Heteroannulation of Alkenes, Alkylnitriles, and Water: Method Development and Application to a Total Synthesis of (±)-Sacidumlignan D

(2016) Tu M. Ha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts

(2016) Stephanie Kindt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Radical-Cascade Alkylation/Cyclization of α,β-Unsaturated Amides: an Efficient Approach to Quaternary Oxindoles

(2016) Promita Biswas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Mediated Intermolecular 1,2-Alkylarylation of Styrenes with α-Carbonyl Alkyl Bromides and Indoles

(2016) Xuan-Hui Ouyang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free tandem oxidative C(sp3)–H bond functionalization of alkanes and dearomatization of N-phenyl-cinnamamides: access to alkylated 1-azaspiro[4.5]decanes

(2016) Honglin Zhang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed alkylarylation of activated alkenes using isocyanides as the alkyl source: an efficient radical access to 3,3-dialkylated oxindoles

(2016) Yaping Zhao et al.   CHEMICAL COMMUNICATIONS

Copper(i)-catalyzed radical decarboxylative imidation of carboxylic acids with N-fluoroarylsulfonimides

(2016) Zhongxue Fang et al.   CHEMICAL COMMUNICATIONS

Aerobic oxidative cyclization of benzamides via meta-selective C–H tert-alkylation: rapid entry to 7-alkylated isoquinolinediones

(2016) Shi Tang et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed oxidative [2+2+1] annulation of 1,n-enynes with α-carbonyl alkyl bromides through C–Br/C–H functionalization

(2016) Ming Hu et al.   CHEMICAL COMMUNICATIONS

Oxysulfonylation of Alkenes with Sulfonyl Hydrazides under Transition-Metal-Free Conditions

(2016) Congrong Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Visible-light initiated direct oxysulfonylation of alkenes with sulfinic acids leading to β-ketosulfones

(2016) Daoshan Yang et al.   GREEN CHEMISTRY

Metal-free cascade oxidative decarbonylative alkylarylation of acrylamides with aliphatic aldehydes: a convenient approach to oxindoles via dual C(sp2)–H bond functionalization

(2016) Luo Yang et al.   GREEN CHEMISTRY

Silver-Catalyzed Cascade Radical Cyclization: A Direct Approach to 3,4-Disubstituted Dihydroquinolin-2(1H)-ones through Activation of the P–H Bond and Functionalization of the C(sp2)–H Bond

(2016) Honglin Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

A Dual-Catalytic Strategy To Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes

(2016) Jin-Shun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Amino Lactonization and Amino Oxygenation of Alkenes Using O-Benzoylhydroxylamines

(2016) Brett N. Hemric et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical Process

(2016) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Azidation in the Difunctionalization of Olefins

(2016) Kai Wu et al.   MOLECULES

Copper/Silver Cocatalyzed Oxidative Coupling of Vinylarenes with ICH2CF3 or ICH2CHF2 Leading to β-CF3/CHF2-Substituted Ketones

(2016) Niannian Yi et al.   ORGANIC LETTERS

Silver(I)-Mediated Phosphorylation/Cyclization Cascade of N-Cyanamide Alkenes for Divergent Access to Quinazolinones and Dihydroisoquinolinones

(2016) Jing Zheng et al.   ORGANIC LETTERS

Iron-Catalyzed Radical [2 + 2 + 2] Annulation of Benzene-Linked 1,7-Enynes with Aldehydes: Fused Pyran Compounds

(2016) Leiyang Lv et al.   ORGANIC LETTERS

Unactivated C(sp3)–H Bond Functionalization of Alkyl Nitriles with Vinylarenes and Mechanistic Studies

(2016) Xing-Wang Lan et al.   ORGANIC LETTERS

Copper-mediated radical alkylarylation of unactivated alkenes with acetonitrile leading to fluorenes and pyrroloindoles

(2016) Xue-Qiang Chu et al.   Organic Chemistry Frontiers

Metal-Free Radical [2+2+1] Carbocyclization of Benzene-Linked 1,n-Enynes: Dual C(sp3)H Functionalization Adjacent to a Heteroatom

(2015) Ming Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Carboetherification of Unactivated Alkenes by Alkyl Nitriles and Alcohols

(2015) Claire Chatalova-Sazepin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solvent-Enabled Radical Selectivities: Controlled Syntheses of Sulfoxides and Sulfides

(2015) Huamin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Direct Diazidation for a Broad Range of Olefins

(2015) Yong-An Yuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines

(2015) Hong-Yu Zhang et al.   CHEMICAL COMMUNICATIONS

Visible light-induced difunctionalization of electron-enriched styrenes: synthesis of tetrahydrofurans and tetrahydropyrans

(2015) Run Lin et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed intermolecular and regioselective aminofluorination of styrenes: facile access to β-fluoro-N-protected phenethylamines

(2015) Jorge Saavedra-Olavarría et al.   CHEMICAL COMMUNICATIONS

Mn(OAc)3-mediated phosphonation–lactonization of alkenoic acids: synthesis of phosphono-γ-butyrolactones

(2015) Yuzhen Gao et al.   CHEMICAL COMMUNICATIONS

Radical aminooxygenation of alkenes with N-fluoro-benzenesulfonimide (NFSI) and TEMPONa

(2015) Yi Li et al.   CHEMICAL COMMUNICATIONS

Cu-based carbene involved in a radical process: a new crossover reaction to construct γ-peroxy esters and 1,4-dicarbonyl compounds

(2015) Jiewen Jiang et al.   CHEMICAL COMMUNICATIONS

A transition-metal-free, one-pot procedure for the synthesis of α,β-epoxy ketones by oxidative coupling of alkenes and aldehydes via base catalysis

(2015) Qingping Ke et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed Cleavage of C–N Single Bonds

(2015) Kunbing Ouyang et al.   CHEMICAL REVIEWS

Olefinic C–H functionalization through radical alkenylation

(2015) Shan Tang et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalysed Alkylarylation of Activated Alkenes Using AIBN and Beyond: An Access to Cyano-Containing Oxindoles

(2015) Dong Zhou et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Manganese-Catalyzed Aerobic Oxytrifluoromethylation of Styrene Derivatives Using CF3SO2Na as the Trifluoromethyl Source

(2015) Yi Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Ascorbic Acid Promoted Oxidative Arylation of Vinyl Arenes to 2-Aryl Acetophenones without Irradiation at Room Temperature under Aerobic Conditions

(2015) Biju Majhi et al.   JOURNAL OF ORGANIC CHEMISTRY

Air Oxidative Radical Hydroxysulfurization of Styrenes Leading to β-Hydroxysulfides

(2015) Shao-Fang Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Dual 1,1-H-Abstraction/Insertion for Domino Spirocyclizations

(2015) Jiang-Kai Qiu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes

(2015) Rong Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes

(2015) Zheliang Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mn-Catalyzed Highly Efficient Aerobic Oxidative Hydroxyazidation of Olefins: A Direct Approach to β-Azido Alcohols

(2015) Xiang Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vanadyl species-catalyzed complementary β-oxidative carbonylation of styrene derivatives with aldehydes

(2015) Wen-Chieh Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Fe-promoted radical cyanomethylation/arylation of arylacrylamides to access oxindoles via cleavage of the sp3 C–H of acetonitrile and the sp2 C–H of the phenyl group

(2015) Changduo Pan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Vicinal Oxyazidation and Diazidation of Styrenes under Mild Conditions: Access to Alkyl Azides

(2015) Ming-Zhu Lu et al.   ORGANIC LETTERS

Copper-Catalyzed Radical [2 + 2 + 1] Annulation of Benzene-Linked 1,n-Enynes with Azide: Fused Pyrroline Compounds

(2015) Xuan-Hui Ouyang et al.   ORGANIC LETTERS

A Catalyst-Free Synthesis of Phosphinic Amides Using O-Benzoylhydroxylamines

(2015) Rui Zhu et al.   ORGANIC LETTERS

Transition-Metal-Free Tandem Radical Thiocyanooxygenation of Olefinic Amides: A New Route to SCN-Containing Heterocycles

(2015) Hua Yang et al.   ORGANIC LETTERS

NH4I-Mediated Three-Component Coupling Reaction: Metal-Free Synthesis of β-Alkoxy Methyl Sulfides from DMSO, Alcohols, and Styrenes

(2015) Xiaofang Gao et al.   ORGANIC LETTERS

C–H Bonds Phosphorylation of Ketene Dithioacetals

(2015) Liping Zhu et al.   ORGANIC LETTERS

Photoredox-Catalyzed Intramolecular Aminodifluoromethylation of Unactivated Alkenes

(2015) Zuxiao Zhang et al.   ORGANIC LETTERS

Visible-Light-Promoted Photoredox Syntheses of α,β-Epoxy Ketones from Styrenes and Benzaldehydes under Alkaline Conditions

(2015) Jing Li et al.   ORGANIC LETTERS

Copper/Manganese Cocatalyzed Oxidative Coupling of Vinylarenes with Ketones

(2015) Xing-Wang Lan et al.   ORGANIC LETTERS

Copper-/Cobalt-Catalyzed Highly Selective Radical Dioxygenation of Alkenes

(2015) Qingquan Lu et al.   ORGANIC LETTERS

β-Ketophosphonate Formation via Aerobic Oxyphosphorylation of Alkynes or Alkynyl Carboxylic Acids with H-Phosphonates

(2015) Mingxin Zhou et al.   ORGANIC LETTERS

A Free Radical Cascade Silylarylation of Activated Alkenes: Highly Selective Activation of the Si–H/C–H Bonds

(2015) Lizhi Zhang et al.   ORGANIC LETTERS

Acid-catalyzed cascade radical addition/cyclization of arylacrylamides with ketones

(2015) Xiao-Feng Xia et al.   TETRAHEDRON

Iodine-mediated regioselective C–N and C–I bond formation of alkenes

(2015) Kai Sun et al.   RSC Advances

Manganese-Mediated Coupling Reaction of Vinylarenes and Aliphatic Alcohols

(2015) Wei Zhang et al.   Scientific Reports

Transition-Metal-Catalyzed Carbonylation Reactions of Olefins and Alkynes: A Personal Account

(2014) Xiao-Feng Wu et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Versatile Metal-Free Intermolecular Aminochlorination of Alkenes

(2014) Claudio Martínez et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative Coupling of Alkenes with Aldehydes and Hydroperoxides: One-Pot Synthesis of 2,3-Epoxy Ketones

(2014) Wen-Ting Wei et al.   ADVANCED SYNTHESIS & CATALYSIS

Visible Light-Induced γ-Alkoxynitrile SynthesisviaThree- Component Alkoxycyanomethylation of Alkenes

(2014) Hong Yi et al.   ADVANCED SYNTHESIS & CATALYSIS

A Convenient Photocatalytic Fluorination of Unactivated CH Bonds

(2014) Shira D. Halperin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3-Containing Alkyl Azides

(2014) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interception of Cobalt-Based Carbene Radicals with α-Aminoalkyl Radicals: A Tandem Reaction for the Construction of β-Ester-γ-amino Ketones

(2014) Jie Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining Photoredox-Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of α-Trifluoromethylated Ketones from Aromatic Alkenes

(2014) Ren Tomita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Acid-Catalyzed Oxidative Radical Addition of Ketones to Olefins

(2014) Bertrand Schweitzer-Chaput et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Radical Aminofluorination of Styrenes

(2014) Hongwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed intermolecular azidocyanation of aryl alkenes

(2014) Li Xu et al.   CHEMICAL COMMUNICATIONS

Radical cascade cyanomethylation of activated alkenes to construct cyano substituted oxindoles

(2014) Juan Li et al.   CHEMICAL COMMUNICATIONS

Visible light photoredox-catalysed intermolecular radical addition of α-halo amides to olefins

(2014) Masaki Nakajima et al.   CHEMICAL COMMUNICATIONS

Oxidative coupling of alkenes with amides using peroxides: selective amide C(sp3)–H versus C(sp2)–H functionalization

(2014) Xu-Heng Yang et al.   CHEMICAL COMMUNICATIONS

The carbomethylation of arylacrylamides leading to 3-ethyl-3-substituted indolin-2-one by cascade radical addition/cyclization

(2014) Qiang Dai et al.   CHEMICAL COMMUNICATIONS

One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis

(2014) Aude Carboni et al.   CHEMICAL COMMUNICATIONS

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development

(2014) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of CH Bond Functionalization

(2014) Tatiana Besset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Mediated/Catalyzed Oxyalkylation of Alkenes with Alkylnitriles

(2014) Ala Bunescu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Radical Carbooxygenation: Alkylation and Alkoxylation of Styrenes

(2014) Zhixiong Liao et al.   Chemistry-An Asian Journal

Copper-Catalyzed Three-Component Azidotrifluoromethylation/Difunctionalization of Alkenes

(2014) Mingbo Yang et al.   CHINESE JOURNAL OF CHEMISTRY

K2S2O8-Mediated Aerobic Oxysulfonylation of Olefins into β-Keto Sulfones in Aqueous Media

(2014) Ruchi Chawla et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Functionalization of Amides via Copper-Catalyzed Oxyalkylation of Vinylarenes and Decarboxylative Alkenylation of sp3 C–H

(2014) Hong Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Combinatorialization of Fungal Polyketide Synthase–Peptide Synthetase Hybrid Proteins

(2014) Thomas B. Kakule et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper- and Cobalt-Catalyzed Direct Coupling of sp3 α-Carbon of Alcohols with Alkenes and Hydroperoxides

(2014) Jun-Kee Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent

(2014) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in heterobimetallic palladium(ii)/copper(ii) catalyzed domino difunctionalization of carbon–carbon multiple bonds

(2014) Egle M. Beccalli et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Recent advances in trifluoromethylation of organic compounds using Umemoto's reagents

(2014) Cai Zhang   ORGANIC & BIOMOLECULAR CHEMISTRY

Aerobic oxysulfonylation of alkenes using thiophenols: an efficient one-pot route to β-ketosulfones

(2014) Atul K. Singh et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Co-Catalyzed Synthesis of 1,4-Dicarbonyl Compounds Using TBHP Oxidant

(2014) Feng Zhang et al.   ORGANIC LETTERS

Radical–Polar Crossover Reactions: Oxidative Coupling of 1,3-Dioxolanes with Electron-Deficient Alkenes and Vinylarenes Based on a Radical Addition and Kornblum–DeLaMare Rearrangement

(2014) Peng Du et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Aminoazidation of Alkenes

(2014) Bo Zhang et al.   ORGANIC LETTERS

Photoredox-Induced Three-Component Azido- and Aminotrifluoromethylation of Alkenes

(2014) Guillaume Dagousset et al.   ORGANIC LETTERS

Copper-Catalyzed Intramolecular Oxytrifluoromethylthiolation of Unactivated Alkenes

(2014) Liping Zhu et al.   ORGANIC LETTERS

A Practical Method for Metal-Free Radical Trifluoromethylation of Styrenes with NaSO2CF3

(2014) Hai-Qing Luo et al.   SYNLETT

A direct approach to β-keto sulfones via AgNO3/K2S2O8 catalyzed aerobic oxysulfonylation of alkenes in aqueous medium

(2014) Atul K. Singh et al.   TETRAHEDRON LETTERS

Catalytic and direct methyl sulfonylation of alkenes and alkynes using a methyl sulfonyl radical generated from a DMSO, dioxygen and copper system

(2014) Yaojia Jiang et al.   Chemical Science

Copper-catalyzed cyanoalkylarylation of activated alkenes with AIBN: a convenient and efficient approach to cyano-containing oxindoles

(2014) Wei Wei et al.   RSC Advances

1,2-Alkylarylation of activated alkenes with dual C–H bonds of arenes and alkyl halides toward polyhalo-substituted oxindoles

(2014) Yu Liu et al.   Organic Chemistry Frontiers

Oxidative Trifluoromethylation of Unactivated Olefins: An Efficient and Practical Synthesis of α-Trifluoromethyl-Substituted Ketones

(2013) Arghya Deb et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Aminocyanation and Diamination of Alkenes

(2013) Hongwei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Controlled Highly Selective Coupling and Oxygenation of Olefins: A Direct Approach to Alcohols, Ketones, and Diketones

(2013) Yijin Su et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkene Trifluoromethylation Coupled with CC Bond Formation: Construction of Trifluoromethylated Carbocycles and Heterocycles

(2013) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes

(2013) Rong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Annulations toward Phosphorylated Oxindoles: Silver-Catalyzed Carbon-Phosphorus Functionalization of Alkenes

(2013) Ya-Min Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β-Hydroxysulfones

(2013) Qingquan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A room temperature decarboxylation/C–H functionalization cascade by visible-light photoredox catalysis

(2013) Jin Xie et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed direct oxysulfonylation of alkenes with dioxygen and sulfonylhydrazides leading to β-ketosulfones

(2013) Wei Wei et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed trifluoromethylation of N-arylacrylamides “on water” at room temperature

(2013) Fang Yang et al.   CHEMICAL COMMUNICATIONS

Catalytic X–H insertion reactions based on carbenoids

(2013) Dennis Gillingham et al.   CHEMICAL SOCIETY REVIEWS

Radical-Mediated Diamination of Alkenes with Phenylhydrazine and Azodicarboxylates: Highly Diastereoselective Synthesis oftrans-Diamines from Cycloalkenes

(2013) Ming-Kui Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Trifluoromethylation and Cyclization of Aromatic-Sulfonyl-Group-Tethered Alkenes for the Construction of 1,2-Benzothiazinane Dioxide Type Compounds

(2013) Xiang Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Direct Alkylation of Heterocycles with α-Bromo Carbonyl Compounds: C3-Selective Functionalization of 2-Pyridones

(2013) Akihiro Nakatani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Oxidative Benzylarylation of Acrylamides by Benzylic CH Bond Functionalization for the Synthesis of Oxindoles

(2013) Shi-Liu Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Copper-Catalyzed Direct Intramolecular Aminotrifluoromethylation of Unactivated Alkenes with Diverse Nitrogen-Based Nucleophiles

(2013) Jin-Shun Lin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Concise synthesis of oxindole derivatives bearing a 3-trifluoroethyl group: Copper-catalyzed trifluoromethylation of acryloanilides

(2013) Hiromichi Egami et al.   JOURNAL OF FLUORINE CHEMISTRY

Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and Tetrahydropyridazines

(2013) Xiao-Yong Duan et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Mediated Cyanotrifluoromethylation of Styrenes Using the Togni Reagent

(2013) Nadia O. Ilchenko et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron(II)-Catalyzed Intramolecular Aminohydroxylation of Olefins with Functionalized Hydroxylamines

(2013) Guan-Sai Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Radical Azidooxygenation of Alkenes

(2013) Bo Zhang et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes

(2013) Yu-Tao He et al.   ORGANIC LETTERS

Silver-Catalyzed Radical Tandem Cyclization for the Synthesis of 3,4-Disubstituted Dihydroquinolin-2(1H)-ones

(2013) Wen-Peng Mai et al.   ORGANIC LETTERS

Free-Radical Cascade Alkylarylation of Alkenes with Simple Alkanes: Highly Efficient Access to Oxindoles via Selective (sp3)C–H and (sp2)C–H Bond Functionalization

(2013) Zejiang Li et al.   ORGANIC LETTERS

Metal-Free Direct Intramolecular Carbotrifluoromethylation of Alkenes to Functionalized Trifluoromethyl Azaheterocycles

(2013) Lei Li et al.   ORGANIC LETTERS

Radical carbooxygenations of alkenes using hydroxamic acids

(2013) Ryan K. Quinn et al.   Chemical Science

Metal-Free, n-Bu4NI-Catalyzed Regioselective Difunctionalization of Unactivated Alkenes

(2013) Qicai Xue et al.   ACS Catalysis

Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

(2012) Qing Xiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts

(2012) Yusuke Yasu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

(2012) Yi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems

(2012) Uta Wille   CHEMICAL REVIEWS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Total Synthesis of (−)-Sacidumlignans B and D

(2012) Jeetendra Kumar Rout et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective Oxyalkylation of Vinylarenes Catalyzed by Diatomite-Supported Manganese Oxide Nanoparticles

(2012) Huayin Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

A Simple Method for Asymmetric Trifluoromethylation of N-Acyl Oxazolidinones via Ru-Catalyzed Radical Addition to Zirconium Enolates

(2012) Aaron T. Herrmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free Oxyarylation of Alkenes with Aryl Diazonium Salts and TEMPONa

(2012) Marcel Hartmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes

(2012) Rong Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters

(2012) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd/Cu-catalyzed oxidation of alkynes into 1,2-diketones using DMSO as the oxidant

(2012) Ang Gao et al.   TETRAHEDRON

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

(2011) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic and Direct Oxyphosphorylation of Alkenes with Dioxygen and H-Phosphonates Leading to β-Ketophosphonates

(2011) Wei Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of the CF3 radical from trifluoromethylsulfonium triflate and its trifluoromethylation of styrenes

(2011) Cheng-Pan Zhang et al.   CHEMICAL COMMUNICATIONS

Ir-catalysed formation of C−F bonds. From allylic alcohols to α-fluoroketones

(2011) Nanna Ahlsten et al.   CHEMICAL COMMUNICATIONS

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Organocatalytic Synthesis of Fluorinated Molecules

(2011) Guillem Valero et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Synthesis of (±)-Sacidumlignan D

(2011) Sunil Kumar Pandey et al.   JOURNAL OF ORGANIC CHEMISTRY

Integrated Electrochemical–Chemical Oxidation Mediated by Alkoxysulfonium Ions

(2011) Yosuke Ashikari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed C(sp3)–C(sp3) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation

(2011) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Oxyaminations of Alkenes Using Hydroxamic Acids

(2011) Valerie A. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Atom Transfer Radical Addition to Olefins Mediated by Oxidative Quenching of Photoredox Catalysts

(2011) John D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free, Aerobic Dioxygenation of Alkenes Using Simple Hydroxamic Acid Derivatives

(2011) Benjamin C. Giglio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Carbonylation-Peroxidation of Alkenes with Aldehydes and Hydroperoxides

(2011) Weiping Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Metal-Free, Aerobic Dioxygenation of Alkenes Using Hydroxamic Acids

(2010) Valerie A. Schmidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Oxidative Addition of Alkoxycarbonyl Radicals to Alkenes with Carbazates and Air

(2010) Tsuyoshi Taniguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Remote amide-directed palladium-catalyzed benzylic C–H amination with N-fluorobenzenesulfonimide

(2010) Tao Xiong et al.   CHEMICAL COMMUNICATIONS

Trifluoromethylation of various aromatic compounds by CF3I in the presence of Fe(II) compound, H2O2 and dimethylsulfoxide

(2009) Tatsuhito Kino et al.   JOURNAL OF FLUORINE CHEMISTRY

Palladium-Catalyzed Enantioselective Addition of Two Distinct Nucleophiles across Alkenes Capable of Quinone Methide Formation

(2009) Katrina H. Jensen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The enantioselective intramolecular aminative functionalization of unactivated alkenes, dienes, allenes and alkynes for the synthesis of chiral nitrogen heterocycles

(2009) Sherry R. Chemler   ORGANIC & BIOMOLECULAR CHEMISTRY

CuBr-Mediated Oxyalkylation of Vinylarenes under Aerobic Conditions via Cleavage of sp3C−H Bonds α to Oxygen

(2009) Kai Cheng et al.   ORGANIC LETTERS

Recent progress in the generation and use of nitrogen-centred radicals

(2008) Samir Z. Zard   CHEMICAL SOCIETY REVIEWS

Enantioselective Total Synthesis of Lycopodine

(2008) Hua Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS