Nucleophilic and Radical Heptafluoroisopropoxylation with Redox‐Active Reagents

Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis

(2021) Yuegang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Access to AgOCF 3 and Its New Applications as a Reservoir for OCF 2 for the Direct Synthesis of N−CF 3 , Aryl or Alkyl Carbamoyl Fluorides

(2020) Abdurrahman Turksoy et al.   CHEMISTRY-A EUROPEAN JOURNAL

δ-C–H Mono- and Dihalogenation of Alcohols

(2020) Alastair N. Herron et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Nickel-Catalyzed Cross-Coupling Arylation via Proton-Coupled Electron Transfer-Enabled C–C Bond Cleavage

(2020) Long Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct and Chemoselective Electrophilic Monofluoromethylation of Heteroatoms (O-, S-, N-, P-, Se-) with Fluoroiodomethane

(2020) Raffaele Senatore et al.   ORGANIC LETTERS

Nucleophilic trifluoromethoxylation of alkyl halides without silver

(2020) Yan Li et al.   Nature Communications

Metabolic and Pharmaceutical Aspects of Fluorinated Compounds

(2020) Benjamin M. Johnson et al.   JOURNAL OF MEDICINAL CHEMISTRY

Discovery of BMS-986251: A Clinically Viable, Potent, and Selective RORγt Inverse Agonist

(2020) Robert J. Cherney et al.   ACS Medicinal Chemistry Letters

Contribution of Organofluorine Compounds to Pharmaceuticals

(2020) Munenori Inoue et al.   ACS Omega

Redox‐Neutral TEMPO Catalysis: Direct Radical (Hetero)Aryl C−H Di‐ and Trifluoromethoxylation

(2020) Johnny W. Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoinduced Fragmentation Borylation of Cyclic Alcohols and Hemiacetals

(2020) Chao Shu et al.   ORGANIC LETTERS

Current Contributions of Organofluorine Compounds to the Agrochemical Industry

(2020) Yuta Ogawa et al.   iScience

Dual Catalytic Strategy for Forging sp2–sp3 and sp3–sp3 Architectures via β-Scission of Aliphatic Alcohol Derivatives

(2020) Fei Cong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advances in Asymmetric Di-and Trifluoromethylthiolation, and Di- and Trifluoromethoxylation Reactions

(2019) Melissa A. Hardy et al.   Asian Journal of Organic Chemistry

Structure-based Discovery of Phenyl (3-Phenylpyrrolidin-3-yl)sulfones as Selective, Orally Active RORγt Inverse Agonists

(2019) James J.-W. Duan et al.   ACS Medicinal Chemistry Letters

Recent advances in new trifluoromethoxylation reagents

(2019) Xiaofei Zhang et al.   Science China-Chemistry

Synthesis of Tri- and Difluoromethoxylated Compounds by Visible-Light Photoredox Catalysis

(2019) Johnny W. Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deoxytrifluoromethylthiolation and Selenylation of Alcohols by Using Benzothiazolium Reagents

(2019) Stefan Dix et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Hydro-, Bromo-, and Chloroheptafluoroisopropylation of Unactivated Alkenes with Heptafluoroisopropyl Silver

(2019) Chao-Lai Tong et al.   ORGANIC LETTERS

Photochemical Carbopyridylation of Alkenes Using N -Alkenoxypyridinium Salts as Bifunctional Reagents

(2019) Gangadhar Rao Mathi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Radical Revolution for Trifluoromethoxylation

(2018) Basudev Sahoo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C−H Trifluoromethoxylation of Arenes and Heteroarenes

(2018) Weijia Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Trifluoromethoxylation of Arenes Triggered by a Visible-Light-Mediated N-O Redox Fragmentation

(2018) Antonio Togni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethyl Benzoate: A Versatile Trifluoromethoxylation Reagent

(2018) Min Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal Heptafluoroisopropyl (M-hfip) Complexes for Use as hfip Transfer Agents

(2018) Nicholas O. Andrella et al.   ORGANOMETALLICS

Triple Mode of Alkylation with Ethyl Bromodifluoroacetate: N , or O -Difluoromethylation, N -Ethylation and S -(ethoxycarbonyl)difluoromethylation

(2018) Arghya Polley et al.   ADVANCED SYNTHESIS & CATALYSIS

Redox-Active Reagents for Photocatalytic Generation of the OCF3 Radical and (Hetero)Aryl C−H Trifluoromethoxylation

(2018) Weijia Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct and Regioselective C–H Oxidative Difluoromethylation of Heteroarenes

(2018) Sheng-Qing Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dual Photoredox/Copper Catalysis for the Remote C(sp3 )−H Functionalization of Alcohols and Alkyl Halides by N -Alkoxypyridinium Salts

(2018) Xu Bao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective C–O bond formation via a photocatalytic radical coupling strategy: access to perfluoroalkoxylated (ORF) arenes and heteroarenes

(2017) Johnny W. Lee et al.   Chemical Science

Direct Difluoromethylation of Alcohols with an Electrophilic Difluoromethylated Sulfonium Ylide

(2016) Jiansheng Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthetic Approaches to Trifluoromethoxy-Substituted Compounds

(2016) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Promoted Trifluoromethylthiolation of Styrenes by Dual Photoredox/Halide Catalysis

(2016) Roman Honeker et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free Direct Dehydroxytri­fluoromethylthiolation of Alcohols via the Umpolung Reactivity of Trifluoromethanesulfenamides

(2016) Quentin Glenadel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of (±)-Bisavenanthramide B-6 by an Anionic Anhydride Mannich Reaction

(2016) Michael J. Di Maso et al.   ORGANIC LETTERS

Metal-Free Direct Nucleophilic Perfluoroalkylthiolation with Perfluoroalkanesulfenamides

(2016) Quentin Glenadel et al.   Asian Journal of Organic Chemistry

New entries toward the synthesis of OCF3-containing molecules

(2016) Tatiana Besset et al.   Organic Chemistry Frontiers

Silver-Mediated Oxidative Trifluoromethylation of Phenols: Direct Synthesis of Aryl Trifluoromethyl Ethers

(2015) Jian-Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Trifluoromethylthiolation of N-Heteroarenes

(2015) Roman Honeker et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Trifluoromethylation and Trifluoromethylthiolation Reactions Using (Trifluoromethyl)trimethylsilane as a Nucleophilic CF3 Source

(2014) Lingling Chu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide

(2014) Jian-Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds

(2014) Yuwen Zeng et al.   CHEMISTRY-A EUROPEAN JOURNAL

O-Trifluoromethylation ofN,N-Disubstituted Hydroxylamines with Hypervalent Iodine Reagents

(2014) Václav Matoušek et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct C–F Bond Formation Using Photoredox Catalysis

(2014) Montserrat Rueda-Becerril et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Three-Component Oxytrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate and Hydroxamic Acid

(2013) Xin-Yi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct monofluoromethylation of O-, S-, N-, and P-nucleophiles with PhSO(NTs)CH2F: the accelerating effect of α-fluorine substitution

(2013) Xiao Shen et al.   Chemical Science

How the Generalized Anomeric Effect Influences the Conformational Preference

(2012) Changwei Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient synthesis of 5′-fluoroalkoxythiazoles via α-bromo-α-fluoroalkoxyacetophenones Hantzsch type cyclization with thioureas or thioamides

(2012) Taras M. Sokolenko et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthesis and Biochemical Characterization of a Series of 17α-Perfluoroalkylated Estradiols as Selective Ligands for Estrogen Receptor α

(2010) Barbara Eignerová et al.   JOURNAL OF MEDICINAL CHEMISTRY

Trifluoromethyl ethers – synthesis and properties of an unusual substituent

(2008) Frédéric R Leroux et al.   Beilstein Journal of Organic Chemistry

Understanding organofluorine chemistry. An introduction to the C–F bond

(2007) David O'Hagan   CHEMICAL SOCIETY REVIEWS