Structurally-Responsive Ligands for High-Performance Catalysts

Ru(II)-Catalyzed Amination of Aryl Fluorides via η6-Coordination

(2020) Qi-Kai Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Well-defined High-valent Palladium Complexes by Oxidation of Their Palladium(II) Precursors

(2020) Bo Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Alkyne Cyclotrimerization Assisted by a Hemilabile Acceptor Ligand: A Computational Study

(2020) Alessio F. Orsino et al.   ORGANOMETALLICS

Coordination chemistry of carboxamide ‘Nx’ ligands to metal ions for bio-inspired catalysis

(2020) Chakadola Panda et al.   COORDINATION CHEMISTRY REVIEWS

Improved Oxidative C–C Bond Formation Reactivity of High-Valent Pd Complexes Supported by a Pseudo-Tridentate Ligand

(2020) Jason W. Schultz et al.   INORGANIC CHEMISTRY

Aryl Fluoride Activation through Palladium–Magnesium Bimetallic Cooperation: A Mechanistic and Computational Study

(2020) Chen Wu et al.   ACS Catalysis

Tailored strength neighboring group interactions switch polymerization to dimerization catalysis

(2019) Eva Schiebel et al.   ACS Catalysis

Enhanced Catalytic Activity of Nickel Complexes of an Adaptive Diphosphine–Benzophenone Ligand in Alkyne Cyclotrimerization

(2019) Alessio F. Orsino et al.   ACS Catalysis

C(sp3)–C(sp3) Coupling with a Pd(II) Complex Bearing a Structurally Responsive Ligand

(2019) Kyle M. K. Jackman et al.   ORGANOMETALLICS

Biaryl monophosphine ligands in palladium-catalyzed C–N coupling: An updated User's guide

(2019) Bryan T. Ingoglia et al.   TETRAHEDRON

Terminal Phosphido Complexes of the Ru(η5-Cp*) Fragment

(2019) Jin Yang et al.   ORGANOMETALLICS

Ligands with Two Monoanionic N,N‐Binding Sites: Synthesis and Coordination Chemistry

(2019) Robert Kretschmer   CHEMISTRY-A EUROPEAN JOURNAL

The Impact of Oxygen on Leading and Emerging Ru-Carbene Catalysts for Olefin Metathesis: An Unanticipated Correlation Between Robustness and Metathesis Activity

(2019) Stephanie J. Ton et al.   ACS Catalysis

Pentafluorophenyl Groups as Remote Substituents in Ni(II) Polymerization Catalysis

(2019) Manuel Schnitte et al.   ORGANOMETALLICS

Histidine–Lysine Axial Ligand Switching in a Hemoglobin: A Role for Heme Propionates

(2018) Dillon B. Nye et al.   BIOCHEMISTRY

POP-type ligands: Variable coordination and hemilabile behaviour

(2018) Gemma M. Adams et al.   COORDINATION CHEMISTRY REVIEWS

Control of Chain Walking by Weak Neighboring Group Interactions in Unsymmetrical Catalysts

(2018) Laura Falivene et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlled Polymerization in Polar Solvents to Ultrahigh Molecular Weight Polyethylene

(2018) Philip Kenyon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unraveling the Role of a Flexible Tetradentate Ligand in the Aerobic Oxidative Carbon–Carbon Bond Formation with Palladium Complexes: A Computational Mechanistic Study

(2018) Qian Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimolecular Coupling as a Vector for Decomposition of Fast-Initiating Olefin Metathesis Catalysts

(2018) Gwendolyn A. Bailey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ring-Closing Metathesis in Pharmaceutical Development: Fundamentals, Applications and Future Directions

(2018) Miao Yu et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Recent topics on catalytic transformations of aromatic molecules via η 6 -arene transition metal complexes

(2018) Shin Takemoto et al.   TETRAHEDRON LETTERS

Hydrogen Transfer Catalysis beyond the Primary Coordination Sphere

(2018) Lillian V. A. Hale et al.   ACS Catalysis

Peroxidase activity of cytochrome c in its compact state depends on dynamics of the heme region

(2018) Nataša Tomášková et al.   BIOCHIMICA ET BIOPHYSICA ACTA-PROTEINS AND PROTEOMICS

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Cross-Coupling and Related Reactions: Connecting Past Success to the Development of New Reactions for the Future

(2018) Louis-Charles Campeau et al.   ORGANOMETALLICS

Oxidative addition of iodine to (tBu)4 (POCOP)Ir(CO) complexes

(2017) Jonathan M. Goldberg et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Cytochrome c as a Peroxidase: Activation of the Precatalytic Native State by H2O2-Induced Covalent Modifications

(2017) Victor Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen Fixation via a Terminal Fe(IV) Nitride

(2017) Niklas B. Thompson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Locked and loaded for apoptosis

(2017) Kara L. Bren et al.   SCIENCE

Metalloprotein entatic control of ligand-metal bonds quantified by ultrafast x-ray spectroscopy

(2017) Michael W. Mara et al.   SCIENCE

Olefin Metathesis at the Dawn of Implementation in Pharmaceutical and Specialty-Chemicals Manufacturing

(2016) Carolyn S. Higman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands

(2016) Christophe Fliedel et al.   CHEMICAL REVIEWS

Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

(2016) Paula Ruiz-Castillo et al.   CHEMICAL REVIEWS

Complexes of ambiphilic ligands: reactivity and catalytic applications

(2016) Ghenwa Bouhadir et al.   CHEMICAL SOCIETY REVIEWS

Metal–ligand cooperation at tethered π-ligands

(2016) Dide G. A. Verhoeven et al.   DALTON TRANSACTIONS

Biaryl Phosphine Based Pd(II) Amido Complexes: The Effect of Ligand Structure on Reductive Elimination

(2016) Pedro Luis Arrechea et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Long-Lived Five-Coordinate Platinum(IV) Intermediates: Regiospecific C–C Coupling

(2016) Paul A. Shaw et al.   ORGANOMETALLICS

Mechanistic Study of the Direct Intramolecular Allylic Amination Reaction Catalyzed by Palladium(II)

(2016) Filipe J. S. Duarte et al.   ACS Catalysis

Why Does Industry Not Use Immobilized Transition Metal Complexes as Catalysts?

(2015) Sandra Hübner et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-Ligand Cooperation

(2015) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic SNAr of unactivated aryl chlorides

(2015) James W. Walton et al.   CHEMICAL COMMUNICATIONS

Neutral Nickel Catalysts for Olefin Homo- and Copolymerization: Relationships between Catalyst Structures and Catalytic Properties

(2015) Hongliang Mu et al.   CHEMICAL REVIEWS

The emergence of sulfoxides as efficient ligands in transition metal catalysis

(2015) Gellért Sipos et al.   CHEMICAL SOCIETY REVIEWS

Artificial switchable catalysts

(2015) Victor Blanco et al.   CHEMICAL SOCIETY REVIEWS

Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?

(2015) Dean G. Brown et al.   JOURNAL OF MEDICINAL CHEMISTRY

Spin Isomers and Ligand Isomerization in a Three-Coordinate Cobalt(I) Carbonyl Complex

(2015) Malik H. Al-Afyouni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of the 21st Century: Two Decades of Innovative Catalyst Design for Palladium-Catalyzed Cross-Couplings

(2015) Peter G. Gildner et al.   ORGANOMETALLICS

Palladium(II)-Catalysed Oxidation of Alkenes

(2015) Tom Sheppard et al.   SYNTHESIS-STUTTGART

Amine-Mediated Degradation in Olefin Metathesis Reactions that Employ the Second-Generation Grubbs Catalyst

(2014) Justin A. M. Lummiss et al.   ChemCatChem

Dioxygen activation by an organometallic Pd(ii) precursor: formation of a Pd(iv)–OH complex and its C–O bond formation reactivity

(2014) Fengrui Qu et al.   CHEMICAL COMMUNICATIONS

Deactivation in Homogeneous Transition Metal Catalysis: Causes, Avoidance, and Cure

(2014) Robert H. Crabtree   CHEMICAL REVIEWS

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

Cation-Modulated Reactivity of Iridium Hydride Pincer-Crown Ether Complexes

(2014) Matthew R. Kita et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Functional Polyolefin Synthesis: Effecting Control through Chelating Ancillary Ligand Design and Mechanistic Insights

(2014) Brad P. Carrow et al.   MACROMOLECULES

Operation of the Boomerang Mechanism in Olefin Metathesis Reactions Promoted by the Second-Generation Hoveyda Catalyst

(2014) Jennifer M. Bates et al.   ACS Catalysis

Ni(II) Phenoxyiminato Olefin Polymerization Catalysis: Striking Coordinative Modulation of Hyperbranched Polymer Microstructure and Stability by a Proximate Sulfonyl Group

(2014) Casey J. Stephenson et al.   ACS Catalysis

Oxidative Additions of Aryl Halides to Palladium Proceed through the Monoligated Complex

(2013) Krista Vikse et al.   ChemCatChem

DFT Study on the Recovery of Hoveyda-Grubbs-Type Catalyst Precursors in Enyne and Diene Ring-Closing Metathesis

(2013) Francisco Núñez-Zarur et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Aryl β-diiminate complexes of the platinum metals

(2013) Di Zhu et al.   DALTON TRANSACTIONS

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Efficient and regioselective nickel-catalyzed [2 + 2 + 2] cyclotrimerization of ynoates and related alkynes

(2013) Sanjeewa K. Rodrigo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Practical Synthesis of an Aminopyridine as a Component of a BTK Inhibitor

(2013) Lady Mae Alabanza et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

Olefin Metathesis by Grubbs–Hoveyda Complexes: Computational and Experimental Studies of the Mechanism and Substrate-Dependent Kinetics

(2013) Ian W. Ashworth et al.   ACS Catalysis

Multidentate actor ligands as versatile platforms for small molecule activation and catalysis

(2013) Vincent T. Annibale et al.   RSC Advances

Lanthanide amidinates and guanidinates in catalysis and materials science: a continuing success story

(2012) Frank T. Edelmann   CHEMICAL SOCIETY REVIEWS

Synthesis of the HCV Protease Inhibitor Vaniprevir (MK-7009) Using Ring-Closing Metathesis Strategy

(2012) Jongrock Kong et al.   JOURNAL OF ORGANIC CHEMISTRY

The mechanism of oxidative addition of iodine to a dimethylplatinum(II) complex

(2012) S. Masoud Nabavizadeh et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

An Easy Conversion from Platinum(II) Reagents to Platinum(IV) Products: κ3 to κ2 Coordination Mode Interconversion, Phenyl Migration, and Ortho C–H Activation Cascade in a Hemilabile “Click”-Triazole Scorpionate Platinum System

(2012) Bryan E. Frauhiger et al.   ORGANOMETALLICS

Detection of Pd(III) and Pd(IV) Intermediates during the Aerobic Oxidative C–C Bond Formation from a Pd(II) Dimethyl Complex

(2012) Fengzhi Tang et al.   ORGANOMETALLICS

Low-Coordinate Cobalt Fluoride Complexes: Synthesis, Reactions, and Production from C–F Activation Reactions

(2012) Thomas R. Dugan et al.   ORGANOMETALLICS

Metal Impurities Cause False Positives in High-Throughput Screening Campaigns

(2012) Johannes C. Hermann et al.   ACS Medicinal Chemistry Letters

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

(2011) Marc-Etienne Moret et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

The Doping Effect of Fluorinated Aromatic Solvents on the Rate of Ruthenium-Catalysed Olefin Metathesis

(2011) Cezary Samojłowicz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Acyclic boron-containing π-ligand complexes: η2- and η3-coordination modes

(2011) David J. H. Emslie et al.   DALTON TRANSACTIONS

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Characterization of (smif)2Mn(n= 0, M = V, Cr, Mn, Fe, Co, Ni, Ru;n= +1, M = Cr, Mn, Co, Rh, Ir; smif =1,3-di-(2-pyridyl)-2-azaallyl)

(2011) Brenda A. Frazier et al.   INORGANIC CHEMISTRY

Catalyst Control in Sequential Asymmetric Allylic Substitution: Stereodivergent Access toN,N-Diprotected Unnatural Amino Acids

(2011) Paolo Tosatti et al.   JOURNAL OF ORGANIC CHEMISTRY

A Masked Two-Coordinate Cobalt(I) Complex That Activates C–F Bonds

(2011) Thomas R. Dugan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism of the Initiation Reaction in Grubbs–Hoveyda Complexes

(2011) Vasco Thiel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N2Functionalization at Iron Metallaboratranes

(2011) Marc-Etienne Moret et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Aerobic Oxidation of a Pd(II) Dimethyl Complex Leads to Selective Ethane Elimination from a Pd(III) Intermediate

(2011) Julia R. Khusnutdinova et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H and C–C Bond Formation Promoted by Facile κ3/κ2 Interconversions in a Hemilabile “Click”-Triazole Scorpionate Platinum System

(2011) Bryan E. Frauhiger et al.   ORGANOMETALLICS

Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes

(2010) Dan A. Smith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium-Phosphorus Double Bond

(2010) Eric J. Derrah et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How Important Is the Release-Return Mechanism in Olefin Metathesis?

(2010) Tim Vorfalt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sulfur-functionalized N-heterocyclic carbenes and their transition metal complexes

(2010) Matthias Bierenstiel et al.   COORDINATION CHEMISTRY REVIEWS

Heme−Copper−Dioxygen Complexes: Toward Understanding Ligand-Environmental Effects on the Coordination Geometry, Electronic Structure, and Reactivity

(2010) Zakaria Halime et al.   INORGANIC CHEMISTRY

Multifunctional ligands in transition metal catalysis

(2010) Robert H. Crabtree   NEW JOURNAL OF CHEMISTRY

Selection and Development of the Manufacturing Route for EP1Antagonist GSK269984B

(2010) Matthew Whiting et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Allosteric Supramolecular Triple-Layer Catalysts

(2010) H. J. Yoon et al.   SCIENCE

Dialkylbiaryl phosphines in Pd-catalyzed amination: a user's guide

(2010) David S. Surry et al.   Chemical Science

Nacnac …︁ Are You Still There? The Evolution of β-Diketiminate Complexes of Nickel

(2009) Daniel J. Mindiola   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−F Bond Activation in Organic Synthesis

(2009) Hideki Amii et al.   CHEMICAL REVIEWS

Mechanisms of C–H bond activation: rich synergy between computation and experiment

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Oxidatively Induced Reductive Elimination from (tBu2bpy)Pd(Me)2: Palladium(IV) Intermediates in a One-Electron Oxidation Reaction

(2009) Michael P. Lanci et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Efficient Process for Pd-Catalyzed C−N Cross-Coupling Reactions of Aryl Iodides: Insight Into Controlling Factors

(2009) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Insertion of Molecular Oxygen into a Palladium(II) Methyl Bond: A Radical Chain Mechanism Involving Palladium(III) Intermediates

(2009) Luc Boisvert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design and engineering of an O2 transport protein

(2009) Ronald L. Koder et al.   NATURE

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

When Are Tricoordinated PdIISpecies Accessible? Stability Trends and Mechanistic Consequences

(2008) Salvador Moncho et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Highly Active Catalyst for Pd-Catalyzed Amination Reactions: Cross-Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides

(2008) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates

(2008) Serge I. Gorelsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Developments on Hemilabile P,O-Type Ligands in Cross-Coupling Reactions

(2008) Fuk Kwong et al.   SYNLETT

In an Attempt to Provide a User's Guide to the Galaxy of Benzylidene, Alkoxybenzylidene, and Indenylidene Ruthenium Olefin Metathesis Catalysts

(2007) Michał Bieniek et al.   CHEMISTRY-A EUROPEAN JOURNAL