Acyclic boron-containing π-ligand complexes: η2- and η3-coordination modes

Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

(2011) Marc-Etienne Moret et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Potassium S2N-heteroscorpionates: structure and iridaboratrane formation

(2011) María J. López-Gómez et al.   DALTON TRANSACTIONS

Novel Pyridazine Based Scorpionate Ligands in Cobalt and Nickel Boratrane Compounds

(2011) Gernot Nuss et al.   INORGANIC CHEMISTRY

Ni→B Interactions in Nickel Phosphino-Alkynyl-Borane Complexes

(2010) Xiaoxi Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity of the Bifunctional Ambiphilic Molecule 8-(dimesitylboryl)quinoline: Hydrolysis and Coordination to CuI, AgI and PdII

(2010) Jung-Ho Son et al.   DALTON TRANSACTIONS

Fluxional rhodium scorpionate complexes of the hydrotris(methimazolyl)borate (Tm) ligand and their static boratrane derivatives

(2010) María J. López-Gómez et al.   DALTON TRANSACTIONS

Diversity of Metal−Ligand Interactions in Halide (X = I, Br, Cl, F) and Halide-Free Ambiphilic Ligand Rhodium Complexes

(2010) Bradley E. Cowie et al.   INORGANIC CHEMISTRY

Borylene-Based Functionalization of Iron-Alkynyl-σ-Complexes and Stepwise Reversible Metal-Boryl-to-Borirene Transformation: Synthesis, Characterization, and Density Functional Theory Studies

(2010) Holger Braunschweig et al.   INORGANIC CHEMISTRY

A 1,1′-ferrocenyl phosphine-borane: synthesis, structure and evaluation in Rh-catalyzed hydroformylation

(2010) Magnus W. P. Bebbington et al.   NEW JOURNAL OF CHEMISTRY

Structures and Properties of Nonchelated, d0Alkyl Alkene Complexes of the Type [Cp2ZrMe(alkene)]+: Elusive Intermediates during Ziegler-Natta Polymerizations of Alkenes

(2009) Francoise Sauriol et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A novel route to rhodaboratranes [Rh(CO)(PR3){B(taz)3}]+via the redox activation of scorpionate complexes [RhLL′Tt]

(2009) Robin J. Blagg et al.   DALTON TRANSACTIONS

Unexpected pincer-type coordination (κ3-SBS) within a zerovalent platinum metallaboratrane complex

(2009) Gareth R. Owen et al.   DALTON TRANSACTIONS

A new hybrid scorpionate ligand: a study of the metal–boron bond within metallaboratrane complexes

(2009) Gareth R. Owen et al.   DALTON TRANSACTIONS

Copper(I) Complexes derived from Mono- and Diphosphino-Boranes: Cu→B Interactions Supported by Arene Coordination

(2009) M. Sircoglou et al.   INORGANIC CHEMISTRY

Consistent van der Waals Radii for the Whole Main Group

(2009) Manjeera Mantina et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Reactions of H2Os3(CO)10 with triallylboranes: formation of novel triosmium boron-containing olefin clusters

(2009) Ol’ga A. Kizas et al.   NEW JOURNAL OF CHEMISTRY

Further Exploring the “Sting of the Scorpion”: Hydride Migration and Subsequent Rearrangement of Norbornadiene to Nortricyclyl on Rhodium(I)

(2009) Nikolaos Tsoureas et al.   ORGANOMETALLICS

Metallaboratranes: Bis- and Tris(methimazolyl)borane Complexes of Group 9 Metal Carbonyls and Thiocarbonyls

(2009) Ian R. Crossley et al.   ORGANOMETALLICS

Metallaboratranes Derived from a Triphosphanyl–Borane: IntrinsicC3 Symmetry Supported by a Z-Type Ligand

(2008) Sébastien Bontemps et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity of a Terminal Chromium Borylene Complex towards Olefins: Insertion of a Borylene into a CH Bond

(2008) Holger Braunschweig et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity of the Ni→B dative σ-bond in the nickel boratrane compounds [κ4-B(mimBut)3]NiX (X = Cl, OAc, NCS, N3): synthesis of a series of B-functionalized tris(2-mercapto-1-tert-butylimidazolyl)borato complexes, [YTmBut]NiZ

(2008) Keliang Pang et al.   CHEMICAL COMMUNICATIONS

Covalent radii revisited

(2008) Beatriz Cordero et al.   DALTON TRANSACTIONS

1,2-Diboracyclopentanes without Strong Donor Substituents: Synthesis, Reactions, and Computational Analysis

(2008) Carsten Präsang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl, and Au+) Derived from a Triphosphine−Borane

(2008) Marie Sircoglou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}](Ru→B)8and [Ru(CO)(CNR){B(mt)3}](Ru→B)8(mt = methimazolyl, R =tBu, C6H3Me2-2,6, C6H2Me3-2,4,6)

(2008) Ian R. Crossley et al.   ORGANOMETALLICS

Reactivity of B(C6F5)3with Simple Early Transition Metal Alkoxides: Alkoxide-Aryl Exchange, THF Ring-Opening, or Acetonitrile CC Coupling

(2008) Christian Lorber et al.   ORGANOMETALLICS

Retention of Pt→B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh3){B(mt)3}](Pt→B)10(mt = Methimazolyl)

(2008) Ian R. Crossley et al.   ORGANOMETALLICS

Synthesis and Reactivity of Ruthenium Arene Complexes Incorporating Novel Ph2PCH2CH2BR2Ligands. Easy Access to the Four-Membered Ruthenacycle [(p-cymene)RuCl(κC,P-CH2CH2PPh2)]

(2008) Jérôme Vergnaud et al.   ORGANOMETALLICS

Group 10 Transition-Metal Complexes of an Ambiphilic PSB-Ligand: Investigations into η3(BCC)-Triarylborane Coordination

(2008) David J. H. Emslie et al.   ORGANOMETALLICS

β-Phosphinoethylboranes as Ambiphilic Ligands in Nickel−Methyl Complexes

(2008) Andreas Fischbach et al.   ORGANOMETALLICS

Ambiphilic Diphosphine–Borane Ligands: Metal→Borane Interactions within Isoelectronic Complexes of Rhodium, Platinum and Palladium

(2007) Sébastien Bontemps et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unlocking the metallaboratrane cage: reversible B–H activation in platinaboratranes

(2007) Ian R. Crossley et al.   DALTON TRANSACTIONS