Iridium(III)-Catalyzed Branch-Selective C–H Alkenylation of Aniline Derivatives with Alkenes

Bidentate Directing Groups: An Efficient Tool in C–H Bond Functionalization Chemistry for the Expedient Construction of C–C Bonds

(2020) Supriya Rej et al.   CHEMICAL REVIEWS

Understanding chemical reactivity using the activation strain model

(2020) Pascal Vermeeren et al.   Nature Protocols

Rhodium‐Catalyzed Electrooxidative C–H Olefination of Benzamides

(2020) Yan Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Distal γ‐C(sp3)−H Olefination of Ketone Derivatives and Free Carboxylic Acids

(2020) Han Seul Park et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Direct Rh(III)-Catalyzed C–H Amidation of Aniline Derivatives Using a Pyrimidine Directing Group: The Selective Solvent Controlled Synthesis of 1,2-Diaminobenzenes and Benzimidazoles

(2020) Shrikant M. Khake et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–H Olefination of Aromatic/Vinyl Acids with Unactivated Olefins at Room Temperature

(2020) Subramanian Jambu et al.   ORGANIC LETTERS

Rapid Synthesis of Alkenylated BINOL Derivatives via Rh(III)-Catalyzed C–H Bond Activation

(2020) Hao Liu et al.   ORGANIC LETTERS

Density Functional Theory Study on the Mechanism of Iridium-Catalyzed Benzylamine ortho C–H Alkenylation with Ethyl Acrylate

(2020) Jiarong Wang et al.   ACS Omega

Rhodium-catalyzed C–H olefination of aromatic acids with unactivated olefins to achieve branched vinylated or linear allylated product: A theoretical investigation

(2020) Xiaowen Zheng et al.   Molecular Catalysis

Iridium-Catalyzed Benzylamine C–H Alkenylation Enabled by Pentafluorobenzoyl as the Directing Group

(2019) Xiao Yang et al.   ORGANIC LETTERS

Orthogonal Selectivity in C–H Olefination: Synthesis of Branched Vinylarene with Unactivated Aliphatic Substitution

(2019) Soumitra Agasti et al.   ACS Catalysis

Iridium-catalyzed carbonyl group-directed oxidative coupling of arenes with alkenes

(2018) Kumaran Elumalai et al.   TETRAHEDRON LETTERS

Dual Effects of Cyclopentadienyl Ligands on Rh(III)-Catalyzed Dehydrogenative Arylation of Electron-Rich Alkenes

(2018) Weidong Lin et al.   ACS Catalysis

Manganese-Catalyzed Redox-Neutral C−H Olefination of Ketones with Unactivated Alkenes

(2018) Yuanyuan Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed α-Selective Arylation of Styrenes by Dual C−H Functionalization

(2018) Phillippa Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Exploration of Cp*CoIII/RhIII-Catalyzed Carboamination/Olefination of N-Phenoxyacetamides with Alkenes

(2018) Yang-Yang Xing et al.   INORGANIC CHEMISTRY

Branched-Selective Intermolecular Ketone α-Alkylation with Unactivated Alkenes via an Enamide Directing Strategy

(2017) Dong Xing et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-catalyzed direct C–H amidation of anilines with sulfonyl azides: easy access to 1,2-diaminobenzenes

(2017) Lianhui Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-Catalyzed Ortho-Alkenylation of Anilines Directed by a Removable Boc-Protecting Group

(2017) Tomohiro Morita et al.   ORGANIC LETTERS

Iridium(III)-Catalyzed Synthesis of Benzimidazoles via C–H Activation and Amidation of Aniline Derivatives

(2017) Jintao Xia et al.   ORGANIC LETTERS

Incorporating Unbiased, Unactivated Aliphatic Alkenes in Pd(II)-Catalyzed Olefination of Benzyl Phosphonamide

(2017) Kapileswar Seth et al.   ACS Catalysis

Recent advances in positional-selective alkenylations: removable guidance for twofold C–H activation

(2017) Wenbo Ma et al.   Organic Chemistry Frontiers

A General Strategy for the Nickel-Catalyzed C−H Alkylation of Anilines

(2016) Zhixiong Ruan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Traceless directing group mediated branched selective alkenylation of unbiased arenes

(2016) Soumitra Agasti et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Olefination of Aryl C–H Bonds by Using Directing­ Scaffolds

(2016) Debabrata Maiti et al.   SYNTHESIS-STUTTGART

Iridium(iii)- and rhodium(iii)-catalyzed coupling of anilines with α-diazoesters via chelation-assisted C–H activation

(2016) Guo-Dong Tang et al.   Organic Chemistry Frontiers

Rhodium(III)-Catalyzed Direct CH Olefination of Arenes with Aliphatic Olefins

(2015) Xiao Xue et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative Olefination of Anilides with Unactivated Alkenes Catalyzed by an (Electron-Deficient η5-Cyclopentadienyl)Rhodium(III) Complex Under Ambient Conditions

(2015) Yuji Takahama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Complete Switch of Selectivity in the C–H Alkenylation and Hydroarylation Catalyzed by Iridium: The Role of Directing Groups

(2015) Jiyu Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Oxidative Alkenylation of 1,3-Dithiane-Protected Arenecarbaldehydes via Regioselective C–H Bond Cleavage

(2015) Yuto Unoh et al.   ORGANIC LETTERS

Reversed reactivity of anilines with alkynes in the rhodium-catalysed C–H activation/carbonylation tandem

(2015) Siba P. Midya et al.   Nature Communications

The activation strain model and molecular orbital theory

(2015) Lando P. Wolters et al.   Wiley Interdisciplinary Reviews-Computational Molecular Science

Weakly Coordinating Directing Groups for Ruthenium(II)- Catalyzed CH Activation

(2014) Suman De Sarkar et al.   ADVANCED SYNTHESIS & CATALYSIS

The activation strain model and molecular orbital theory: understanding and designing chemical reactions

(2014) Israel Fernández et al.   CHEMICAL SOCIETY REVIEWS

Rhodium(III)-Catalyzed Selectiveortho-Olefinations ofN-Acyl andN-Aroyl Sulfoximines by CH Bond Activation

(2014) Kanniyappan Parthasarathy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ir(III)-Catalyzed C7-Position-Selective Oxidative CH Alkenylation of Indolines with Alkenes in Air

(2014) Shiguang Pan et al.   Chemistry-An Asian Journal

Palladium-Catalyzed α-Selective Alkenylation of Imidazo[1,2-a]pyridines through Aerobic Cross-Dehydrogenative Coupling Reaction

(2014) Monoranjan Ghosh et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Oxidative Olefination of Furans with Unactivated Alkenes

(2014) Christo S. Sevov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Directed peri-C–H Alkenylation of Anthracene Derivatives

(2014) Jaganathan Karthikeyan et al.   ORGANIC LETTERS

Mechanistic Study of the Oxidative Coupling of Styrene with 2-Phenylpyridine Derivatives Catalyzed by Cationic Rhodium(III) via C–H Activation

(2013) Mikaël Brasse et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Direction in CH Alkenylation: Silanol as a Helping Hand

(2012) Marius Mewald et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic Rationalization of Unusual Kinetics in Pd-Catalyzed C–H Olefination

(2012) Ryan D. Baxter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Alkenylation of Aromatic Esters by Ruthenium-Catalyzed Twofold C–H Bond Cleavages

(2012) Karolina Graczyk et al.   ORGANIC LETTERS

Ruthenium-catalyzed direct oxidative alkenylation of arenes through twofold C–H bond functionalization

(2012) Sergei I. Kozhushkov et al.   Chemical Science

Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms

(2011) Mar Gómez-Gallego et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The activation strain model of chemical reactivity

(2010) Willem-Jan van Zeist et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C−H Activation

(2010) Andy S. Tsai et al.   ORGANIC LETTERS

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Regioselective Palladium-Catalyzed Oxidative Coupling of Indolizines and Vinylarenes via C−H Bond Cleavage

(2009) Yuzhu Yang et al.   ORGANIC LETTERS

C−H Activation of Phenyl Imines and 2-Phenylpyridines with [Cp*MCl2]2(M = Ir, Rh): Regioselectivity, Kinetics, and Mechanism

(2009) Ling Li et al.   ORGANOMETALLICS

Ligand-Enabled Reactivity and Selectivity in a Synthetically Versatile Aryl C-H Olefination

(2009) D.-H. Wang et al.   SCIENCE