Advances in Chiral Metal–Organic and Covalent Organic Frameworks for Asymmetric Catalysis

Covalent Organic Frameworks: Design, Synthesis, and Functions

(2020) Keyu Geng et al.   CHEMICAL REVIEWS

Homochiral Covalent Organic Frameworks for Asymmetric Catalysis

(2020) Yu-Bin Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Progress in Metal‐Free Covalent Organic Frameworks as Heterogeneous Catalysts

(2020) Yongfeng Zhi et al.   Small

Homochiral Covalent Organic Framework for Catalytic Asymmetric Synthesis of a Drug Intermediate

(2020) Hui-Chao Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Covalent Organic Frameworks from Prochiral Monomers for Heterogeneous Asymmetric Catalysis

(2020) Jian-Cheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral DHIP- and Pyrrolidine-Based Covalent Organic Frameworks for Asymmetric Catalysis

(2019) Jie Zhang et al.   ACS Sustainable Chemistry & Engineering

Asymmetric Catalysis within the Chiral Confined Space of Metal-Organic Architectures

(2019) Xuezhao Li et al.   Small

Prevalence of Diarylprolinol Silyl Ethers as Catalysts in Total Synthesis and Patents

(2019) Gabriel J. Reyes-Rodríguez et al.   CHEMICAL REVIEWS

Divergent Synthesis of Chiral Covalent Organic Frameworks

(2019) Li-Ke Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Stable Zr(IV)-Based Metal–Organic Frameworks with Chiral Phosphoric Acids for Catalytic Asymmetric Tandem Reactions

(2019) Wei Gong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photothermal conversion triggered thermal asymmetric catalysis within metal nanoparticles loaded homochiral covalent organic framework

(2019) Hui-Chao Ma et al.   Nature Communications

Chiral Phosphoric Acids in Metal-Organic Frameworks with Enhanced Acidity and Tunable Catalytic Selectivity

(2019) Xu Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boosting Enantioselectivity of Chiral Organocatalysts with Ultrathin Two-Dimensional Metal–Organic Framework Nanosheets

(2019) Chunxia Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Isostructural Porphyrin–Salen Chiral Metal–Organic Frameworks through Postsynthetic Metalation Based on Single-Crystal to Single-Crystal Transformation

(2018) Jiawei Li et al.   INORGANIC CHEMISTRY

Chiral Functionalization of a Zirconium Metal–Organic Framework (DUT-67) as a Heterogeneous Catalyst in Asymmetric Michael Addition Reaction

(2018) Khoa D. Nguyen et al.   INORGANIC CHEMISTRY

Chiral induction in covalent organic frameworks

(2018) Xing Han et al.   Nature Communications

Highly Stable Chiral Zirconium-Metallosalen Frameworks for CO2 Conversion and Asymmetric C-H Azidation

(2018) Jiawei Li et al.   ACS Applied Materials & Interfaces

Chiral Metal–Organic Framework Decorated with TEMPO Radicals for Sequential Oxidation/Asymmetric Cyanation Catalysis

(2018) Zijian Li et al.   INORGANIC CHEMISTRY

Controlled Exchange of Achiral Linkers with Chiral Linkers in Zr-Based UiO-68 Metal–Organic Framework

(2018) Chunxia Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multivariate Chiral Covalent Organic Frameworks with Controlled Crystallinity and Stability for Asymmetric Catalysis

(2017) Jie Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Covalent Organic Frameworks with High Chemical Stability for Heterogeneous Asymmetric Catalysis

(2017) Xing Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boosting Chemical Stability, Catalytic Activity, and Enantioselectivity of Metal–Organic Frameworks for Batch and Flow Reactions

(2017) Xu Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modulating the Performance of an Asymmetric Organocatalyst by Tuning Its Spatial Environment in a Metal–Organic Framework

(2017) Lujia Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multivariate Metal–Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions

(2017) Qingchun Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral covalent organic frameworks for asymmetric catalysis and chiral separation

(2017) Guofeng Liu et al.   Science China-Chemistry

Sixteen isostructural phosphonate metal-organic frameworks with controlled Lewis acidity and chemical stability for asymmetric catalysis

(2017) Xu Chen et al.   Nature Communications

Modifying electron transfer between photoredox and organocatalytic units via framework interpenetration for β-carbonyl functionalization

(2017) Zhengqiang Xia et al.   Nature Communications

Coordinative Alignment of Chiral Molecules to Control over the Chirality Transfer in Spontaneous Resolution and Asymmetric Catalysis

(2017) Zhengqiang Xia et al.   Scientific Reports

Tunable chiral metal organic frameworks toward visible light–driven asymmetric catalysis

(2017) Yin Zhang et al.   Science Advances

Emerging Multifunctional Metal-Organic Framework Materials

(2016) Bin Li et al.   ADVANCED MATERIALS

A Cr(salen)-based metal–organic framework as a versatile catalyst for efficient asymmetric transformations

(2016) Qingchun Xia et al.   CHEMICAL COMMUNICATIONS

Proline Functionalized UiO-67 and UiO-68 Type Metal–Organic Frameworks Showing Reversed Diastereoselectivity in Aldol Addition Reactions

(2016) Christel Kutzscher et al.   CHEMISTRY OF MATERIALS

Chiral Cu(salen)-Based Metal–Organic Framework for Heterogeneously Catalyzed Aziridination and Amination of Olefins

(2016) Yan Liu et al.   INORGANIC CHEMISTRY

Constructing Crystalline Covalent Organic Frameworks from Chiral Building Blocks

(2016) Hai-Sen Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homochiral 2D Porous Covalent Organic Frameworks for Heterogeneous Asymmetric Catalysis

(2016) Xiuren Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Metal–Organic Framework as a Platform for Cooperative Catalysis in Asymmetric Cyanosilylation of Aldehydes

(2016) Chengfeng Zhu et al.   ACS Catalysis

Direct and Post-Synthesis Incorporation of Chiral Metallosalen Catalysts into Metal-Organic Frameworks for Asymmetric Organic Transformations

(2015) Weiqin Xi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantiopure Peptide-Functionalized Metal–Organic Frameworks

(2015) Jonathan Bonnefoy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Robust, Chiral, and Porous BINAP-Based Metal–Organic Frameworks for Highly Enantioselective Cyclization Reactions

(2015) Takahiro Sawano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts

(2015) Hong Xu et al.   Nature Chemistry

Polyoxometalate-based homochiral metal-organic frameworks for tandem asymmetric transformation of cyclic carbonates from olefins

(2015) Qiuxia Han et al.   Nature Communications

Chiral Metal-Organic Frameworks Bearing Free Carboxylic Acids for Organocatalyst Encapsulation

(2014) Yan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Engineering chiral Fe(salen)-based metal–organic frameworks for asymmetric sulfide oxidation

(2014) Zhiwei Yang et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Proline Functionalization of the Mesoporous Metal−Organic Framework DUT-32

(2014) Christel Kutzscher et al.   INORGANIC CHEMISTRY

Privileged Phosphine-Based Metal–Organic Frameworks for Broad-Scope Asymmetric Catalysis

(2014) Joseph M. Falkowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Homochiral Metal–Organic Framework as an Effective Asymmetric Catalyst for Cyanohydrin Synthesis

(2014) Ke Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a ‘bottle around the ship’ approach

(2013) Thomas Bogaerts et al.   CHEMICAL COMMUNICATIONS

A homochiral porous metal–organic framework for enantioselective adsorption of mandelates and photocyclizaton of tropolone ethers

(2013) Yongwu Peng et al.   CHEMICAL COMMUNICATIONS

Chiral microporous Ti(salan)-based metal–organic frameworks for asymmetric sulfoxidation

(2013) Chengfeng Zhu et al.   CHEMICAL COMMUNICATIONS

Catalytic covalent organic frameworks via pore surface engineering

(2013) Hong Xu et al.   CHEMICAL COMMUNICATIONS

“Click” post-synthetic modification of metal−organic frameworks for asymmetric aldol catalysis

(2013) Wenting Zhu et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Engineering Chiral Polyoxometalate Hybrid Metal–Organic Frameworks for Asymmetric Dihydroxylation of Olefins

(2013) Qiuxia Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A chiral porous metallosalan-organic framework containing titanium-oxo clusters for enantioselective catalytic sulfoxidation

(2013) Weimin Xuan et al.   Chemical Science

Homochiral Crystallization of Metal-Organic Silver Frameworks: Asymmetric [3+2] Cycloaddition of an Azomethine Ylide

(2012) Xu Jing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral metal–organic frameworks with tunable open channels as single-site asymmetric cyclopropanation catalysts

(2012) Joseph M. Falkowski et al.   CHEMICAL COMMUNICATIONS

“Click” post-synthetic modification of metal–organic frameworks with chiral functional adduct for heterogeneous asymmetric catalysis

(2012) Wenting Zhu et al.   DALTON TRANSACTIONS

Photoactive Chiral Metal–Organic Frameworks for Light-Driven Asymmetric α-Alkylation of Aldehydes

(2012) Pengyan Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Nanoporous Metal–Metallosalen Frameworks for Hydrolytic Kinetic Resolution of Epoxides

(2012) Chengfeng Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cavity-induced enantioselectivity reversal in a chiral metal–organic framework Brønsted acid catalyst

(2012) Min Zheng et al.   Chemical Science

Actuation of Asymmetric Cyclopropanation Catalysts: Reversible Single-Crystal to Single-Crystal Reduction of Metal-Organic Frameworks

(2011) Joseph M. Falkowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amino acid functionalized metal–organic frameworks by a soft coupling–deprotection sequence

(2011) Jerome Canivet et al.   CHEMICAL COMMUNICATIONS

A chiral metal–organic framework for sequential asymmetric catalysis

(2011) Feijie Song et al.   CHEMICAL COMMUNICATIONS

Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis

(2011) Minyoung Yoon et al.   CHEMICAL REVIEWS

Postsynthetic Methods for the Functionalization of Metal–Organic Frameworks

(2011) Seth M. Cohen   CHEMICAL REVIEWS

Mesoporous metal–organic framework materials

(2011) Weimin Xuan et al.   CHEMICAL SOCIETY REVIEWS

Chiral Metal-Organic Frameworks and Their Application in Asymmetric Catalysis and Stereoselective Separation

(2011) Georg Nickerl et al.   CHEMIE INGENIEUR TECHNIK

A Family of Chiral Metal-Organic Frameworks

(2011) Kristina Gedrich et al.   CHEMISTRY-A EUROPEAN JOURNAL

Delineating similarities and dissimilarities in the use of metal organic frameworks and zeolites as heterogeneous catalysts for organic reactions

(2011) Amarajothi Dhakshinamoorthy et al.   DALTON TRANSACTIONS

Asymmetric Catalysis with Chiral Porous Metal–Organic Frameworks: Critical Issues

(2011) Cheng Wang et al.   Journal of Physical Chemistry Letters

A General Thermolabile Protecting Group Strategy for Organocatalytic Metal−Organic Frameworks

(2011) David J. Lun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric catalytic reactions by NbO-type chiral metal–organic frameworks

(2011) Kyung Seok Jeong et al.   Chemical Science

Engineering Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

(2010) Yan Liu et al.   ADVANCED MATERIALS

Single-Crystal to Single-Crystal Cross-Linking of an Interpenetrating Chiral Metal-Organic Framework and Implications in Asymmetric Catalysis

(2010) Liqing Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homochiral Metal−Organic Frameworks for Heterogeneous Asymmetric Catalysis

(2010) Dongbin Dang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isoreticular Chiral Metal−Organic Frameworks for Asymmetric Alkene Epoxidation: Tuning Catalytic Activity by Controlling Framework Catenation and Varying Open Channel Sizes

(2010) Feijie Song et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis

(2010) Liqing Ma et al.   Nature Chemistry

Asymmetric Catalysis with Chiral Porous Metal–Organic Frameworks

(2010) Wenbin Lin   TOPICS IN CATALYSIS

From one to three: a serine derivate manipulated homochiral metal-organic framework

(2009) Miao Wang et al.   CHEMICAL COMMUNICATIONS

Recyclable Stereoselective Catalysts

(2009) Alexandre F. Trindade et al.   CHEMICAL REVIEWS

Enantioselective catalysis with homochiral metal–organic frameworks

(2009) Liqing Ma et al.   CHEMICAL SOCIETY REVIEWS

Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal−Organic Porous Materials

(2009) Mainak Banerjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of a solid Brønsted acid site in a chiral framework

(2008) Michael J. Ingleson et al.   CHEMICAL COMMUNICATIONS

The advent and development of organocatalysis

(2008) David W. C. MacMillan   NATURE