Chiral Phosphoric Acids in Metal-Organic Frameworks with Enhanced Acidity and Tunable Catalytic Selectivity

Highly enantioselective Friedel–Crafts alkylation of N,N-dialkylanilines with trans-β-nitrostyrene catalyzed by a homochiral metal–organic framework

(2018) Koichi Tanaka et al.   CHEMICAL COMMUNICATIONS

In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth

(2018) Mary J. Van Vleet et al.   CHEMICAL REVIEWS

Achieving Superprotonic Conduction in Metal–Organic Frameworks through Iterative Design Advances

(2018) SiRim Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

2,3-Dihydroquinazolin-4(1H)-one as a privileged scaffold in drug design

(2018) Mariateresa Badolato et al.   RSC Advances

Chiral Metal–Organic Framework Decorated with TEMPO Radicals for Sequential Oxidation/Asymmetric Cyanation Catalysis

(2018) Zijian Li et al.   INORGANIC CHEMISTRY

Controlled Exchange of Achiral Linkers with Chiral Linkers in Zr-Based UiO-68 Metal–Organic Framework

(2018) Chunxia Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boosting Chemical Stability, Catalytic Activity, and Enantioselectivity of Metal–Organic Frameworks for Batch and Flow Reactions

(2017) Xu Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Modulating the Performance of an Asymmetric Organocatalyst by Tuning Its Spatial Environment in a Metal–Organic Framework

(2017) Lujia Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multivariate Metal–Organic Frameworks as Multifunctional Heterogeneous Asymmetric Catalysts for Sequential Reactions

(2017) Qingchun Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic asymmetric arylation of indoles enabled by azo groups

(2017) Liang-Wen Qi et al.   Nature Chemistry

Enantioselective synthesis of dihydroquinazolinone derivatives catalyzed by a chiral organocatalyst

(2017) Siva Ayyanar et al.   NEW JOURNAL OF CHEMISTRY

Sixteen isostructural phosphonate metal-organic frameworks with controlled Lewis acidity and chemical stability for asymmetric catalysis

(2017) Xu Chen et al.   Nature Communications

Tunable chiral metal organic frameworks toward visible light–driven asymmetric catalysis

(2017) Yin Zhang et al.   Science Advances

Benzothiazoline: Versatile Hydrogen Donor for Organocatalytic Transfer Hydrogenation

(2015) Chen Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Enantioselective Synthesis of 2,3-Dihydroquinazolinones Catalyzed by Polymer Supported BINOL-Derived Phosphoric Acid

(2015) Baohua Zhang et al.   CATALYSIS LETTERS

Catalytic Asymmetric Synthesis of Chiral Acetals

(2015) Peng Du et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Highly Enantioselective SPINOL-Derived Phosphoric Acid Catalyzed Transfer Hydrogenation of Diverse C=N-Containing Heterocycles

(2015) Yiliang Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Robust, Chiral, and Porous BINAP-Based Metal–Organic Frameworks for Highly Enantioselective Cyclization Reactions

(2015) Takahiro Sawano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The first chiral diene-based metal–organic frameworks for highly enantioselective carbon–carbon bond formation reactions

(2015) Takahiro Sawano et al.   Chemical Science

The first route to highly stable crystalline microporous zirconium phosphonate metal–organic frameworks

(2014) Marco Taddei et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Advancements in solid acid catalysts for biodiesel production

(2014) Fang Su et al.   GREEN CHEMISTRY

Privileged Phosphine-Based Metal–Organic Frameworks for Broad-Scope Asymmetric Catalysis

(2014) Joseph M. Falkowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Homochiral Metal–Organic Framework as an Effective Asymmetric Catalyst for Cyanohydrin Synthesis

(2014) Ke Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Transfer Hydrogenation of Ketimines by Indoline as Recyclable Hydrogen Donor

(2014) Kodai Saito et al.   ORGANIC LETTERS

Atom-Economic Synthesis of Optically Active Warfarin Anticoagulant over a Chiral MOF Organocatalyst

(2013) Tao Shi et al.   ADVANCED SYNTHESIS & CATALYSIS

Two homochiral organocatalytic metal organic materials with nanoscopic channels

(2013) Zhuxiu Zhang et al.   CHEMICAL COMMUNICATIONS

DFT Study of the Mechanism and Origin of Enantioselectivity in Chiral BINOL-Phosphoric Acid Catalyzed Transfer Hydrogenation of Ketimine and α-Imino Ester Using Benzothiazoline

(2013) Yukihiro Shibata et al.   JOURNAL OF ORGANIC CHEMISTRY

Engineering Chiral Polyoxometalate Hybrid Metal–Organic Frameworks for Asymmetric Dihydroxylation of Olefins

(2013) Qiuxia Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[Ir(P−OP)]-Catalyzed Asymmetric Hydrogenation of Diversely Substituted C═N-Containing Heterocycles

(2013) José Luis Núñez-Rico et al.   ORGANIC LETTERS

Enantioselective synthesis of biologically important spiro[indoline-3,2′-quinazolines] via catalytic asymmetric isatin-involved tandem reactions

(2013) Yan Jiang et al.   TETRAHEDRON-ASYMMETRY

Highly Enantioselective Synthesis of Dihydroquinazolinones Catalyzed by SPINOL-Phosphoric Acids

(2013) Dan Huang et al.   ACS Catalysis

Catalytic Asymmetric Synthesis of Dihydroquinazolinones from Imines and 2-Aminobenzamides

(2012) Dao-Juan Cheng et al.   ADVANCED SYNTHESIS & CATALYSIS

A Microporous Binol-Derived Phosphoric Acid

(2012) Dipti S. Kundu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoactive Chiral Metal–Organic Frameworks for Light-Driven Asymmetric α-Alkylation of Aldehydes

(2012) Pengyan Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cavity-induced enantioselectivity reversal in a chiral metal–organic framework Brønsted acid catalyst

(2012) Min Zheng et al.   Chemical Science

A Chiral Microporous Polymer Network as Asymmetric Heterogeneous Organocatalyst

(2011) Christian Bleschke et al.   ADVANCED SYNTHESIS & CATALYSIS

Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis

(2011) Minyoung Yoon et al.   CHEMICAL REVIEWS

Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites

(2011) Norbert Stock et al.   CHEMICAL REVIEWS

A General Thermolabile Protecting Group Strategy for Organocatalytic Metal−Organic Frameworks

(2011) David J. Lun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acid Catalyzed Enantioselective Synthesis of β-Amino-α,α-difluoro Carbonyl Compounds

(2011) Wataru Kashikura et al.   ORGANIC LETTERS

Engineering Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation

(2010) Yan Liu et al.   ADVANCED MATERIALS

Synthesis and Application of Polymer-Supported Chiral Brønsted Acid Organocatalysts

(2010) Magnus Rueping et al.   ADVANCED SYNTHESIS & CATALYSIS

The First General, Efficient and Highly Enantioselective Reduction of Quinoxalines and Quinoxalinones

(2010) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Homochiral Metal−Organic Frameworks for Heterogeneous Asymmetric Catalysis

(2010) Dongbin Dang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis

(2010) Liqing Ma et al.   Nature Chemistry

Phosphonate and sulfonate metal organic frameworks

(2009) George K. H. Shimizu et al.   CHEMICAL SOCIETY REVIEWS

Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal−Organic Porous Materials

(2009) Mainak Banerjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Benzothiazoline: Highly Efficient Reducing Agent for the Enantioselective Organocatalytic Transfer Hydrogenation of Ketimines

(2009) Chen Zhu et al.   ORGANIC LETTERS

Asymmetric Brønsted Acid Catalysis: Catalytic Enantioselective Synthesis of Highly Biologically Active Dihydroquinazolinones

(2008) Magnus Rueping et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Generation of a solid Brønsted acid site in a chiral framework

(2008) Michael J. Ingleson et al.   CHEMICAL COMMUNICATIONS

Asymmetric Synthesis of 2,3-Dihydro-2-arylquinazolin-4-ones: Methodology and Application to a Potent Fluorescent Tubulin Inhibitor with Anticancer Activity

(2008) Gary M. Chinigo et al.   JOURNAL OF MEDICINAL CHEMISTRY

Polymer-Supported Organocatalysts: Asymmetric Reduction of Imines with Trichlorosilane Catalyzed by an Amino Acid-Derived Formamide Anchored to a Polymer†

(2008) Andrei V. Malkov et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Catalytic Asymmetric Synthesis of Cyclic Aminals from Aldehydes

(2008) Xu Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theoretical Study of the Mechanism of Hantzsch Ester Hydrogenation of Imines Catalyzed by Chiral BINOL-Phosphoric Acids

(2008) Luis Simón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY