Mono- and Difluorination of Benz­ylic Carbon Atoms

Advances in Transition-Metal-Mediated Di-and Monofluoroalkylations

(2015) Chuanfa Ni et al.   ACTA CHIMICA SINICA

Direct photocatalytic fluorination of benzylic C–H bonds with N-fluorobenzenesulfonimide

(2015) Matthew B. Nodwell et al.   CHEMICAL COMMUNICATIONS

Introduction: Fluorine Chemistry

(2015) Veronique Gouverneur et al.   CHEMICAL REVIEWS

Monofluorination of Organic Compounds: 10 Years of Innovation

(2015) Pier Alexandre Champagne et al.   CHEMICAL REVIEWS

Recent Progress toward the Introduction of Functionalized Difluoromethylated Building Blocks onto C(sp2) and C(sp) Centers

(2015) Marie-Charlotte Belhomme et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Vicinal Difunctionalization of Alkynes: An Efficient Approach Towards the Synthesis of Highly Functionalized Fluorinated Alkenes

(2015) Tatiana Besset et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

PyFluor: A Low-Cost, Stable, and Selective Deoxyfluorination Reagent

(2015) Matthew K. Nielsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Chiral β-Fluoro α-Amino Acids via Pd(II)-Catalyzed Fluorination of Unactivated Methylene C(sp3)–H Bonds: Scope and Mechanistic Studies

(2015) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-metal-free C–H oxidative activation: persulfate-promoted selective benzylic mono- and difluorination

(2015) Jing-jing Ma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Fluorination of 2-substituted benzo[b]furans with Selectfluor™

(2015) Mingliang Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-catalyzed benzylic fluorination of trichloroacetimidates

(2015) Qi Zhang et al.   TETRAHEDRON

cis-Specific Hydrofluorination of Alkenylarenes under Palladium Catalysis through an Ionic Pathway

(2014) Enrico Emer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Silver-Mediated Geminal Difluorination of Styrenes Using an Air- and Moisture-Stable Fluoroiodane Reagent

(2014) Nadia O. Ilchenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed Oxidative Activation of Benzylic CH Bonds for the Synthesis of Difluoromethylated Arenes

(2014) Peng Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-catalyzed decarboxylative acylfluorination of styrenes in aqueous media

(2014) Hua Wang et al.   CHEMICAL COMMUNICATIONS

Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of CH Bond Functionalization

(2014) Tatiana Besset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triethylborane-Initiated Radical Chain Fluorination: A Synthetic Method Derived from Mechanistic Insight

(2014) Cody Ross Pitts et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct, Catalytic Monofluorination of sp3 C–H Bonds: A Radical-Based Mechanism with Ionic Selectivity

(2014) Cody Ross Pitts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes

(2014) Eric P. A. Talbot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalyzed Benzylic Fluorination: Shedding “Light” on the Involvement of Electron Transfer

(2014) Steven Bloom et al.   ORGANIC LETTERS

Diversity-Oriented Approach to CF3CHF-, CF3CFBr-, CF3CF2-, (CF3)2CH-, and CF3(SCF3)CH-Substituted Arenes from 1-(Diazo-2,2,2-trifluoroethyl)arenes

(2014) Enrico Emer et al.   ORGANIC LETTERS

An Efficient and Convenient Protocol for the Synthesis of 1,1-Difluoro-6-nitro-2,3-dihydro-1H-indene Derivatives

(2014) Haihong Huang et al.   SYNTHESIS-STUTTGART

Recent advances in C–H fluorination

(2014) Aijun Lin et al.   Organic Chemistry Frontiers

Catalytic fluorination of unactivated C(sp3)–H bonds

(2014) Jun-An Ma et al.   Organic Chemistry Frontiers

C sp 3F Bond Formation: A Free-Radical Approach

(2013) Mukund P. Sibi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Oxidative Benzylic C-H Fluorination by Fluoride Ions

(2013) Wei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An easy access to fluoroalkanes by deoxygenative hydrofluorination of carbonyl compounds via their tosylhydrazones

(2013) Arvind K. Yadav et al.   CHEMICAL COMMUNICATIONS

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Simple Route to Adducts of (Amino)(aryl)carbene with Phosphorus Pentafluoride

(2013) Olexandr I. Guzyr et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis of 4-Fluoromethylsydnones and their Participation in Alkyne Cycloaddition Reactions

(2013) Robert S. Foster et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination

(2013) Ji-Bao Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(II)-Catalyzed Benzylic Fluorination

(2013) Steven Bloom et al.   ORGANIC LETTERS

Silver-Catalyzed Vinylogous Fluorination of Vinyl Diazoacetates

(2013) Changming Qin et al.   ORGANIC LETTERS

Metal-Free Fluorination of C(sp3)–H Bonds Using a Catalytic N-Oxyl Radical

(2013) Yuuki Amaoka et al.   ORGANIC LETTERS

Catalytic Decarboxylative Fluorination for the Synthesis of Tri- and Difluoromethyl Arenes

(2013) Satoshi Mizuta et al.   ORGANIC LETTERS

Fluorine Transfer to Alkyl Radicals

(2012) Montserrat Rueda-Becerril et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Reagent for Direct Difluoromethylation

(2012) Yuta Fujiwara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridine•BrF3, the Missing Link for Clean Fluorinations of Aromatic Derivatives

(2012) Youlia Hagooly et al.   ORGANIC LETTERS

Pd-Catalyzed C–H Fluorination with Nucleophilic Fluoride

(2012) Kate B. McMurtrey et al.   ORGANIC LETTERS

Synthesis of an H3 Antagonist via Sequential One-Pot Additions of a Magnesium Ate Complex and an Amine to a 1,4-Ketoester followed by Carbonyl-Directed Fluoride Addition

(2012) Joel M. Hawkins et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Organocatalyzed Enantioselective Fluorocyclizations

(2011) Oscar Lozano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Efficient Difluorohydroxylation of Indoles Using Selectfluor as a Fluorinating Reagent

(2011) Riyuan Lin et al.   ORGANIC LETTERS

Electropolymerization of 9,9-difluorofluorene in BF3-OEt2 toward a photostable n-type material

(2010) Shinsuke Inagi et al.   ELECTROCHEMISTRY COMMUNICATIONS

Stereospecific benzylic dehydroxyfluorination reactions using Bio’s TMS-amine additive approach with challenging substrates

(2010) Stefano Bresciani et al.   TETRAHEDRON LETTERS

An Efficient Synthesis of an NMDA Receptor Antagonist via Stereoselective Fluorination

(2008) Matthew Bio et al.   SYNTHESIS-STUTTGART

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS