Three-Component 1,2-Carboamidation of Bridged Bicyclic Alkenes via RhIII-Catalyzed Addition of C–H Bonds and Amidating Reagents

Diverse Approaches for Enantioselective C–H Functionalization Reactions Using Group 9 CpxMIII Catalysts

(2020) Tatsuhiko Yoshino et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd-Catalyzed C–H Annulation of Five-Membered Heteroaryl Halides with Norbornene Derivatives

(2020) Birakishore Padhi et al.   ACS Catalysis

Chiral cyclopentadienyl ligands: design, syntheses and applications in asymmetric catalysis

(2020) Nicolai Cramer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt(III)‐Catalyzed Enantioselective Intermolecular Carboaminations via C‒H Functionalizations

(2020) Nicolai Cramer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Strategies for the π-Extension of Heteroaryl Halides Using Norbornadiene as an Acetylene Synthon

(2020) Siyeon Jeong et al.   ORGANIC LETTERS

An Enantioselective CpxRh(III)-Catalyzed C-H Functionalization / Ring-Opening Route to Chiral Cyclopentenylamines

(2019) Nicolai Cramer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Reaction of Benzamides with Bicylic Alkenes: Cleavage of C–H and C–N Bonds

(2019) Aymen Skhiri et al.   ORGANIC LETTERS

Synthesis, Isolation, and Characterization of Mono- and Bis-norbornene-Annulated Biarylamines through Pseudo-Catellani Intermediates

(2019) Pratheepkumar Annamalai et al.   ORGANIC LETTERS

Cobalt(III)-Catalyzed Intermolecular Carboamination of Propiolates and Bicyclic Alkenes via Non-Annulative Redox-Neutral Coupling

(2019) Yuelu Zhu et al.   ORGANIC LETTERS

α-Branched amines by catalytic 1,1-addition of C–H bonds and aminating agents to terminal alkenes

(2019) Soham Maity et al.   Nature Catalysis

Rhodium-Catalyzed Enantioselective Oxidative [3+2] Annulation of Arenes and Azabicyclic Olefins through Twofold C−H Activation

(2019) Ruijie Mi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular 1,4-Carboamination of Conjugated Dienes Enabled by Cp*RhIII -Catalyzed C−H Activation

(2019) Tobias Pinkert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Chemo-divergent Couplings of Sulfoxonium Ylides with Oxa/azabicyclic Olefins

(2019) Peiyuan Wang et al.   ORGANIC LETTERS

A Planar-Chiral Rhodium(III) Catalyst with a Sterically Demanding Cyclopentadienyl Ligand and Its Application in the Enantioselective Synthesis of Dihydroisoquinolones

(2018) Evgeniya A. Trifonova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterobicyclic Core Retained Hydroarylations through C–H Activation: Synthesis of Epibatidine Analogues

(2018) Deng-Yuan Li et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Enantioselective Coupling of Indoles and 7-Azabenzonorbornadienes by C−H Activation/Desymmetrization

(2018) Xifa Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An unusual endo-selective C-H hydroarylationof norbornene by the Rh(I)-catalyzed reactionof benzamides

(2017) Kaname Shibata et al.   Nature Communications

Combination of Cp*RhIII -Catalyzed C−H Activation and a Wagner-Meerwein-Type Rearrangement

(2016) Xiaoming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting Distal Reactivity of Coumarins: A Rhodium-Catalyzed Vinylogous Asymmetric Ring-Opening Reaction

(2016) Charles C. J. Loh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective [3+2] Annulation of Aromatic/Vinylic Amides with Bicyclic Alkenes through Cobalt-Catalyzed C−H Activation and Intramolecular Nucleophilic Addition

(2016) Parthasarathy Gandeepan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

(2016) Christopher G. Newton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cascade Reaction of Alkynols and 7-Oxabenzonorbornadienes Involving Transient Hemiketal Group Directed C–H Activation and Synergistic RhIII/ScIII Catalysis

(2016) Deng Yuan Li et al.   ORGANIC LETTERS

Cobalt(III)-Catalyzed C–C Coupling of Arenes with 7-Oxabenzonorbornadiene and 2-Vinyloxirane via C–H Activation

(2016) Lingheng Kong et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Aryl and Alkenyl C–H Bond Addition to Diverse Nitroalkenes

(2016) Tyler J. Potter et al.   ACS Catalysis

Pharmaceuticals that contain polycyclic hydrocarbon scaffolds

(2015) Tegan P. Stockdale et al.   CHEMICAL SOCIETY REVIEWS

Iridium/copper-cocatalyzed asymmetric ring opening reaction of azabenzonorbornadienes with amines

(2015) Chaoyuan Zeng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-Catalyzed Direct Coupling of Arylphosphine Derivatives with Heterobicyclic Alkenes: A Concise Route to Biarylphosphines and Dibenzophosphole Derivatives

(2015) Yuto Unoh et al.   ACS Catalysis

Ruthenium-Catalyzed Hydroarylations of Oxa- and Azabicyclic Alkenes

(2015) Hanchao Cheng et al.   ACS Catalysis

The Use of Silyl Ketene Acetals and Enol Ethers in the Catalytic Enantioselective Alkylative Ring Opening of Oxa/Aza Bicyclic Alkenes

(2014) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroarylations of Heterobicyclic Alkenes through Rhodium-Catalyzed Directed CH Functionalizations of S-Aryl Sulfoximines

(2014) Wanrong Dong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Efficient Synthesis of Rigid Ladder Polymers via Palladium Catalyzed Annulation

(2014) Sheng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators

(2014) Jamie M. Neely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(iii)-catalyzed coupling of N-sulfonyl 2-aminobenzaldehydes with oxygenated allylic olefins through C–H activation

(2014) Tingting Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-Catalyzed Coupling of Arenes with 7-Oxa/Azabenzonorbornadienes by CH Activation

(2013) Zisong Qi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Tunable Class of Chiral Cp Ligands for Enantioselective Rhodium(III)-Catalyzed C–H Allylations of Benzamides

(2013) Baihua Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(iii)-catalyzed C–H activation–desymmetrization of diazabicycles with arenes: facile synthesis of functionalized cyclopentenes

(2013) Yan Zhang et al.   Chemical Science

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

(2012) T. K. Hyster et al.   SCIENCE

Chiral Cyclopentadienyl Ligands as Stereocontrolling Element in Asymmetric C-H Functionalization

(2012) B. Ye et al.   SCIENCE