Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts

Cobalt-Catalyzed Regio- and Enantioselective Allylic Alkylation of Malononitriles

(2020) Samir Ghorai et al.   ORGANIC LETTERS

Asymmetric Allylic Alkylation of β-Ketoesters via C–N Bond Cleavage of N-Allyl-N-methylaniline Derivatives Catalyzed by a Nickel–Diphosphine System

(2020) Haruki Nagae et al.   ACS Catalysis

The Allylic Alkylation of Ketone Enolates

(2020) Lukas Junk et al.   ChemistryOpen

Construction of Vicinal Quaternary Carbon Centers via Cobalt-Catalyzed Asymmetric Reverse Prenylation

(2019) Minghe Sun et al.   ORGANIC LETTERS

Cobalt-Catalyzed Allylic Alkylation Enabled by Organophotoredox Catalysis

(2019) Koji Takizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Allylation Reactions

(2019) Mahesh Thoke et al.   SYNTHESIS-STUTTGART

P-Chiral Monophosphorus Ligands for Asymmetric Copper-Catalyzed Allylic Alkylation

(2019) Wenrui Xiong et al.   ORGANOMETALLICS

Chiral N-heterocyclic carbene ligands with additional chelating group(s) applied to homogeneous metal-mediated asymmetric catalysis

(2019) Christophe Fliedel et al.   COORDINATION CHEMISTRY REVIEWS

Novel Chiral Ligands for Palladium-catalyzed Asymmetric Allylic Alkylation/ Asymmetric Tsuji-Trost Reaction: A Review

(2019) Samar Noreen et al.   CURRENT ORGANIC CHEMISTRY

Controllable, Sequential, and Stereoselective C–H Allylic Alkylation of Alkenes

(2019) Ling Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols

(2018) Aurapat Ngamnithiporn et al.   Chemical Science

Asymmetric Rhodium-Catalyzed Allylic Substitution Reactions: Discovery, Development and Applications to Target-Directed Synthesis

(2018) Ben W. H. Turnbull et al.   JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

(2018) Qiang Cheng et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters

(2018) Barry Trost et al.   SYNTHESIS-STUTTGART

Dealing at Arm's Length: Catalysis with N-Heterocyclic Carbene Ligands Bearing Anionic Tethers

(2017) Felix Pape et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Readily Accessible Unsymmetrical Unsaturated 2,6-Diisopropylphenyl N-Heterocyclic Carbene Ligands. Applications in Enantioselective Catalysis

(2017) Robert Tarrieu et al.   JOURNAL OF ORGANIC CHEMISTRY

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles

(2016) Hirohisa Ohmiya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereodivergent Reverse Prenylation of Indole and Tryptophan Derivatives: Total Synthesis of Amauromine, Novoamauromine, and epi -Amauromine

(2016) Jonas M. Müller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

All-carbon quaternary centers in natural products and medicinal chemistry: recent advances

(2016) Taotao Ling et al.   TETRAHEDRON

Enantioselective Synthesis of Di- and Tri-Arylated All-Carbon Quaternary Stereocenters via Copper-Catalyzed Allylic Arylations with Organolithium Compounds

(2016) Sureshbabu Guduguntla et al.   ACS Catalysis

Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates

(2016) J. Caleb Hethcox et al.   ACS Catalysis

Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

(2015) Yiyang Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Allylic Alkylation of β-Ketoesters with Allylic Alcohols by a Nickel/Diphosphine Catalyst

(2015) Yusuke Kita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Allylic Alkylation of (Z)-Allyl Bromides with Organolithium Reagents

(2015) Martín Fañanás-Mastral et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pentacoordinated Carboxylate π-Allyl Nickel Complexes as Key Intermediates for the Ni-Catalyzed Direct Amination of Allylic Alcohols

(2015) Yusuke Kita et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Heterocyclic Carbene–Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes

(2015) Ying Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium-Catalyzed Allylic Substitution with a Nitrile Anion: Construction of Acyclic Quaternary Carbon Stereogenic Centers

(2015) Ben W. H. Turnbull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed enantioselective allylic cross-coupling with alkylboranes

(2015) Kentaro Hojoh et al.   TETRAHEDRON

Allylic Functionalization of Unactivated Olefins with Grignard Reagents

(2014) Hongli Bao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Cross-Coupling with Alkylboranes

(2014) Kentaro Hojoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multicomponent Synthesis of Chiral Bidentate Unsymmetrical UnsaturatedN-Heterocyclic Carbenes: Copper-Catalyzed Asymmetric CC Bond Formation

(2014) Claire Jahier-Diallo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Quaternary Carbon Stereocenters by Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Arylboronates

(2014) Momotaro Takeda et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles

(2014) Ayumi Harada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective synthesis of quaternary carbon stereocentres

(2014) Kyle W. Quasdorf et al.   NATURE

Cu-Catalyzed Asymmetric Allylic Alkylation of Phosphonates and Phosphine Oxides with Grignard Reagents

(2013) Valentín Hornillos et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Tertiary and Quaternary Stereogenic Centers: Copper/Phosphoramidite-Catalyzed Allylic Alkylation with Organolithium Reagents

(2012) Martín Fañanás-Mastral et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bidentate Hydroxyalkyl NHC Ligands for the Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Grignard Reagents

(2012) Magaly Magrez et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Copper-Catalyzed Alkylation of β-Ketoesters and Subsequent Cyclization to Spirolactones/Bi-spirolactones

(2012) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Mechanisms of Nucleophilic Organocopper(I) Reactions

(2011) Naohiko Yoshikai et al.   CHEMICAL REVIEWS

Short Synthesis of Chiral 4-Substituted (S)-Imidazolinium Salts Bearing Sulfonates and Their Use in γ-Selective Reactions of Allylic Halides with Grignard Reagents

(2011) Christopher M. Latham et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents

(2011) Jennifer A. Dabrowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Enantioselective Allylic Substitutions with Readily Accessible Aryl- or Heteroaryllithium Reagents and Aluminum Chlorides

(2010) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of Quaternary Chiral Centers by N-Heterocyclic Carbene-Cu-Catalyzed Asymmetric Conjugate Addition Reactions with Grignard Reagents on Trisubstituted Cyclic Enones

(2010) Stefan Kehrli et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereogenic-at-Metal Zn- and Al-Based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

β- and γ-Disubstituted Olefins: Substrates for Copper-Catalyzed Asymmetric Allylic Substitution

(2008) Caroline A. Falciola et al.   ADVANCED SYNTHESIS & CATALYSIS

Regiodivergent 1,4 versus 1,6 Asymmetric Copper-Catalyzed Conjugate Addition

(2008) Hélène Hénon et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Directed Reactions of Organocopper Reagents

(2008) Bernhard Breit et al.   CHEMICAL REVIEWS

High Diversity on Simple Substrates: 1,4-Dihalo-2-butenes and Other Difunctionalized Allylic Halides for Copper-Catalyzed SN2′ Reactions

(2008) Caroline A. Falciola et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Asymmetric Allylic Alkylation

(2008) Caroline A. Falciola et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Development of Biisoquinoline-Based Chiral Diaminocarbene Ligands:  Enantioselective SN2‘ Allylic Alkylation Catalyzed by Copper−Carbene Complexes

(2008) Hwimin Seo et al.   JOURNAL OF ORGANIC CHEMISTRY

The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation

(2008) John A. Enquist Jr et al.   NATURE