Insights into small molecule activation by multinuclear first-row transition metal cyclophanates

A [3Fe–3S]3+ cluster with exclusively μ-sulfide donors

(2016) Yousoon Lee et al.   CHEMICAL COMMUNICATIONS

Reversible Photoinduced Reductive Elimination of H2 from the Nitrogenase Dihydride State, the E4(4H) Janus Intermediate

(2016) Dmitriy Lukoyanov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Fe-N2 Complex That Generates Hydrazine and Ammonia via Fe═NNH2: Demonstrating a Hybrid Distal-to-Alternating Pathway for N2 Reduction

(2016) Jonathan Rittle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stepwise N–H bond formation from N2-derived iron nitride, imide and amide intermediates to ammonia

(2016) K. Cory MacLeod et al.   Chemical Science

An Air- and Water-Tolerant Zinc Hydride Cluster That Reacts Selectively With CO2

(2015) David M. Ermert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Genetics of Nitrogen Use Efficiency in Crop Plants

(2015) Mei Han et al.   Annual Review of Genetics

Use of plant colonizing bacteria as chassis for transfer of N 2 -fixation to cereals

(2015) Barney A Geddes et al.   CURRENT OPINION IN BIOTECHNOLOGY

Tuning steric and electronic effects in transition-metal β-diketiminate complexes

(2015) Chi Chen et al.   DALTON TRANSACTIONS

A Family of Tri- and Dimetallic Pyridine Dicarboxamide Cryptates: Unusual O,N,O-Coordination and Facile Access to Secondary Coordination Sphere Hydrogen Bonding Interactions

(2015) Gary L. Guillet et al.   INORGANIC CHEMISTRY

Nitride-Bridged Triiron Complex and Its Relevance to Dinitrogen Activation

(2015) David M. Ermert et al.   INORGANIC CHEMISTRY

Heterobimetallic Ti/Co Complexes That Promote Catalytic N–N Bond Cleavage

(2015) Bing Wu et al.   INORGANIC CHEMISTRY

Bimetallic Cobalt–Dinitrogen Complexes: Impact of the Supporting Metal on N2 Activation

(2015) Laura J. Clouston et al.   INORGANIC CHEMISTRY

Reactivity of Hydride Bridges in High-Spin [3M–3(μ-H)] Clusters (M = FeII, CoII)

(2015) Yousoon Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diiron Bridged-Thiolate Complexes That Bind N2 at the FeIIFeII, FeIIFeI, and FeIFeI Redox States

(2015) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Silylation of Dinitrogen with a Dicobalt Complex

(2015) Randall B. Siedschlag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Characterization of an Fe≡N–NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3

(2015) John S. Anderson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Activation Upon Reduction of a Triiron(II) Complex

(2014) Yousoon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage

(2014) Brian M. Hoffman et al.   CHEMICAL REVIEWS

Oxidative Stretching of Metal–Metal Bonds to Their Limits

(2014) David W. Brogden et al.   INORGANIC CHEMISTRY

Modeling Biological Copper Clusters: Synthesis of a Tricopper Complex, and Its Chloride- and Sulfide-Bridged Congeners

(2014) Gianna N. Di Francesco et al.   INORGANIC CHEMISTRY

Isolation of a (Dinitrogen)Tricopper(I) Complex

(2014) Leslie J. Murray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Why Does Activation of the Weaker C═S Bond in CS2 by P/N-Based Frustrated Lewis Pairs Require More Energy Than That of the C═O Bond in CO2? A DFT Study

(2014) Ke An et al.   ORGANOMETALLICS

Nitrogenase: A Draft Mechanism

(2013) Brian M. Hoffman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Preorganized assembly of three iron(ii) or manganese(ii) β-diketiminate complexes using a cyclophane ligand

(2013) Gary L. Guillet et al.   CHEMICAL COMMUNICATIONS

Mechanistic aspects of dinitrogen cleavage and hydrogenation to produce ammonia in catalysis and organometallic chemistry: relevance of metal hydride bonds and dihydrogen

(2013) Hong-Peng Jia et al.   CHEMICAL SOCIETY REVIEWS

Biotechnological solutions to the nitrogen problem

(2013) Giles ED Oldroyd et al.   CURRENT OPINION IN BIOTECHNOLOGY

Dinitrogen Activation at Iron and Cobalt Metallalumatranes

(2013) P. Alex Rudd et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Molecular Origin of Rapid versus Slow Intramolecular Electron Transfer in the Catalytic Cycle of the Multicopper Oxidases

(2013) David E. Heppner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Testing the Polynuclear Hypothesis: Multielectron Reduction of Small Molecules by Triiron Reaction Sites

(2013) Tamara M. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Determination of the Active Form of the Tetranuclear Copper Sulfur Cluster in Nitrous Oxide Reductase

(2013) Esther M. Johnston et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Reduction of N2 to NH3 by an Fe–N2 Complex Featuring a C-Atom Anchor

(2013) Sidney E. Creutz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic conversion of nitrogen to ammonia by an iron model complex

(2013) John S. Anderson et al.   NATURE

Dinitrogen Cleavage and Hydrogenation by a Trinuclear Titanium Polyhydride Complex

(2013) T. Shima et al.   SCIENCE

Unexpected Role of Zinc Hydride in Catalytic Hydrosilylation of Ketones and Nitriles

(2013) Courtney Boone et al.   ACS Catalysis

Rise of the Zinc Age in Homogeneous Catalysis?

(2013) Stephan Enthaler   ACS Catalysis

Multidentate actor ligands as versatile platforms for small molecule activation and catalysis

(2013) Vincent T. Annibale et al.   RSC Advances

Non-Redox-Metal-Catalyzed Redox Reactions: Zinc Catalysts

(2012) Xiao-Feng Wu   Chemistry-An Asian Journal

Inorganic and organometallic hemicage podates and cage cryptates incorporating a benzene platform

(2012) Eli Zysman-Colman et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis and characterization of a tris(2-hydroxyphenyl)methane-based cryptand and its triiron(iii) complex

(2012) Gary L. Guillet et al.   DALTON TRANSACTIONS

Reactivity of (β-Diketiminato)zinc Hydride toward Lewis Bases, Heterocumulenes and Cyclohexene Oxide

(2012) Georg Bendt et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation

(2012) Travis M. Figg et al.   INORGANIC CHEMISTRY

A Trinuclear Copper(II) Cryptate and Its μ3-CO3 Cascade Complex: Thermodynamics, Structural and Magnetic Properties

(2011) Pedro Mateus et al.   CHEMISTRY-A EUROPEAN JOURNAL

The chemistry of univalent metal β-diketiminates

(2011) Yi-Chou Tsai   COORDINATION CHEMISTRY REVIEWS

Multi-Site Reactivity: Reduction of Six Equivalents of Nitrite To Give an Fe6(NO)6Cluster with a Dramatically Expanded Octahedral Core

(2011) T. David Harris et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemically Reversible Four-Electron Oxidation and Reduction Utilizing Two Inorganic Functional Groups

(2011) Michael Nippe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dinitrogen Complexes of Sulfur-Ligated Iron

(2011) Ayumi Takaoka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ3-Nitride, [Fe3(μ3-N)]−

(2011) Tamara M. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N2O binding at a [4Cu:2S] copper–sulphur cluster in nitrous oxide reductase

(2011) Anja Pomowski et al.   NATURE

One Atom Makes All the Difference

(2011) S. Ramaswamy   SCIENCE

N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex

(2011) M. M. Rodriguez et al.   SCIENCE

Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

(2011) T. Spatzal et al.   SCIENCE

X-ray Emission Spectroscopy Evidences a Central Carbon in the Nitrogenase Iron-Molybdenum Cofactor

(2011) K. M. Lancaster et al.   SCIENCE

The hydride route to the preparation of dinitrogen complexes

(2010) Joachim Ballmann et al.   CHEMICAL COMMUNICATIONS

Reactions of a β-diketiminate zinc hydride complex with heterocumulenes

(2010) Stephan Schulz et al.   CHEMICAL COMMUNICATIONS

A molybdenum complex bearing PNP-type pincer ligands leads to the catalytic reduction of dinitrogen into ammonia

(2010) Kazuya Arashiba et al.   Nature Chemistry

Mechanism of Mo-Dependent Nitrogenase

(2009) Lance C. Seefeldt et al.   Annual Review of Biochemistry

Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co

(2009) Bennett P. Greenwood et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

O2 Reduction to H2O by the multicopper oxidases

(2008) Edward I. Solomon et al.   DALTON TRANSACTIONS

The Reactivity Patterns of Low-Coordinate Iron−Hydride Complexes

(2008) Ying Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY