Post‐Assembly Photomasking of Potassium Acyltrifluoroborates (KATs) for Two‐Photon 3D Patterning of PEG‐Hydrogels

Design and Applications of Photoresponsive Hydrogels

(2019) Lei Li et al.   ADVANCED MATERIALS

Contemporary approaches to site-selective protein modification

(2019) Emily A. Hoyt et al.   Nature Reviews Chemistry

Native Chemical Ligation and Extended Methods: Mechanisms, Catalysis, Scope, and Limitations

(2019) Vangelis Agouridas et al.   CHEMICAL REVIEWS

Caged Cyclopropenes with Improved Tetrazine Ligation Kinetics

(2019) Pratik Kumar et al.   ORGANIC LETTERS

One-Step Synthesis of Aliphatic Potassium Acyltrifluoroborates (KATs) from Organocuprates

(2018) Sizhou M. Liu et al.   ORGANIC LETTERS

A Reversible and Repeatable Thiol–Ene Bioconjugation for Dynamic Patterning of Signaling Proteins in Hydrogels

(2018) Joseph C. Grim et al.   ACS Central Science

PEGylation and Dimerization of Expressed Proteins under Near Equimolar Conditions with Potassium 2-Pyridyl Acyltrifluoroborates

(2018) Christopher J. White et al.   ACS Central Science

Development of a Visible Light Triggerable Traceless Staudinger Ligation Reagent

(2018) Peng Hu et al.   JOURNAL OF ORGANIC CHEMISTRY

Potassium Acyltrifluoroborate (KAT) Ligations are Orthogonal to Thiol-Michaeland SPAAC Reactions: Covalent Dual Immobilization of Proteins onto Synthetic PEG Hydrogels

(2017) Dmitry Mazunin et al.   HELVETICA CHIMICA ACTA

Multiphoton Activation of Photo-Strain-Promoted Azide Alkyne Cycloaddition “Click” Reagents Enables in Situ Labeling with Submicrometer Resolution

(2017) Christopher D. McNitt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Bifunctional Potassium Acyltrifluoroborates

(2016) Sizhou M. Liu et al.   ORGANIC LETTERS

One-Pot/Sequential Native Chemical Ligation Using Photocaged Crypto-thioester

(2016) Keisuke Aihara et al.   ORGANIC LETTERS

Critical Evaluation and Rate Constants of Chemoselective Ligation Reactions for Stoichiometric Conjugations in Water

(2015) Fumito Saito et al.   ACS Chemical Biology

A photoreversible protein-patterning approach for guiding stem cell fate in three-dimensional gels

(2015) Cole A. DeForest et al.   NATURE MATERIALS

Hydrogels as scaffolds and delivery systems to enhance axonal regeneration after injuries

(2015) Oscar A. Carballo-Molina et al.   Frontiers in Cellular Neuroscience

Cartilage Repair Using Hydrogels: A Critical Review of in Vivo Experimental Designs

(2015) C. A. Vilela et al.   ACS Biomaterials-Science & Engineering

Synthesis of Biocompatible PEG Hydrogels by pH-Sensitive Potassium Acyltrifluoroborate (KAT) Amide Ligations

(2015) Dmitry Mazunin et al.   ACS Biomaterials-Science & Engineering

Cartilage Repair Using Hydrogels: A Critical Review of in Vivo Experimental Designs

(2015) C. A. Vilela et al.   ACS Biomaterials Science & Engineering

Synthesis of Biocompatible PEG Hydrogels by pH-Sensitive Potassium Acyltrifluoroborate (KAT) Amide Ligations

(2015) Dmitry Mazunin et al.   ACS Biomaterials Science & Engineering

Finding the Right (Bioorthogonal) Chemistry

(2014) David M. Patterson et al.   ACS Chemical Biology

Developments in the Field of Bioorthogonal Bond Forming Reactions—Past and Present Trends

(2014) Mathias King et al.   BIOCONJUGATE CHEMISTRY

Cellular Incorporation of Unnatural Amino Acids and Bioorthogonal Labeling of Proteins

(2014) Kathrin Lang et al.   CHEMICAL REVIEWS

Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation

(2014) Hidetoshi Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Microscale patterning of hydrogel stiffness through light-triggered uncaging of thiols

(2014) Katarzyna A. Mosiewicz et al.   Biomaterials Science

Synthetically Tractable Click Hydrogels for Three-Dimensional Cell Culture Formed Using Tetrazine–Norbornene Chemistry

(2013) Daniel L. Alge et al.   BIOMACROMOLECULES

In situ cell manipulation through enzymatic hydrogel photopatterning

(2013) Katarzyna A. Mosiewicz et al.   NATURE MATERIALS

Light-Induced Hydrogen Sulfide Release from “Caged” gem-Dithiols

(2013) Nelmi O. Devarie-Baez et al.   ORGANIC LETTERS

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

(2012) Aaron M. Dumas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Acyltrifluoroborates

(2012) Aaron M. Dumas et al.   ORGANIC LETTERS

Advances in Bioactive Hydrogels to Probe and Direct Cell Fate

(2012) Cole A. DeForest et al.   Annual Review of Chemical and Biomolecular Engineering

Photoreversible Patterning of Biomolecules within Click-Based Hydrogels

(2011) Cole A. DeForest et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spatial and temporal control of the alkyne–azide cycloaddition by photoinitiated Cu(II) reduction

(2011) Brian J. Adzima et al.   Nature Chemistry

Cytocompatible click-based hydrogels with dynamically tunable properties through orthogonal photoconjugation and photocleavage reactions

(2011) Cole A. DeForest et al.   Nature Chemistry

Spatially controlled simultaneous patterning of multiple growth factors in three-dimensional hydrogels

(2011) Ryan G. Wylie et al.   NATURE MATERIALS

Bringing chemistry to life

(2011) Michael Boyce et al.   NATURE METHODS

Styryl Conjugated Coumarin Caged Alcohol: Efficient Photorelease by Either One-Photon Long Wavelength or Two-Photon NIR Excitation

(2011) Chunyan Bao et al.   ORGANIC LETTERS

Sensitized two-photon photochemical deprotection

(2010) Michael C. Pirrung et al.   CHEMICAL COMMUNICATIONS

Peptide-Functionalized Click Hydrogels with Independently Tunable Mechanics and Chemical Functionality for 3D Cell Culture

(2010) Cole A. DeForest et al.   CHEMISTRY OF MATERIALS

Biomimetic materials in tissue engineering

(2010) Jennifer Patterson et al.   Materials Today

Bioorthogonal Chemistry: Fishing for Selectivity in a Sea of Functionality

(2009) Ellen M. Sletten et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogels as extracellular matrix mimics for 3D cell culture

(2009) Mark W. Tibbitt et al.   BIOTECHNOLOGY AND BIOENGINEERING

A Caged Retinoic Acid for One- and Two-Photon Excitation in Zebrafish Embryos

(2008) Pierre Neveu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-dimensional Chemical Patterning of Transparent Hydrogels

(2008) Jordan H. Wosnick et al.   CHEMISTRY OF MATERIALS

Synthesis of potassium and tetra n-butylammonium 2-substituted-1,3-dithianotrifluoroborate salts and addition to chiral cyclic N-acyliminium ions

(2008) Adriano S. Vieira et al.   TETRAHEDRON