Bonding Relationship between Silicon and Germanium with Group 13 and Heavier Elements of Groups 14–16

Isolation of a 1-Magnesium-2,3-disilacyclopropene and a Related Bis(disilenide)

(2020) Miao Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Equilibrium Formation of Stable All‐Silicon Versionsof 1,3‐Cyclobutandiyl

(2020) Cem B. Yildiz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-Stabilized Digermavinylidene

(2019) Kilian M. Krebs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Tetrasilicon Analogue of Bicyclo[1.1.0]but-1(3)-ene Containing a Si=Si Double Bond with an Inverted Geometry

(2019) Takeaki Iwamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Isolable Silicon Analogue of a Ketone that Contains an Unperturbed Si=O Double Bond

(2019) Ryo Kobayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Treatment of Silylene‐Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon Bonded Chalcogens

(2019) Herbert W. Roesky   CHEMISTRY-A EUROPEAN JOURNAL

Isolation of an N‐Heterocyclic Carbene Complex of a Borasilene

(2019) Daniel Franz et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Disilene-Silylene Interconversion: A Synthetically Accessible Acyclic Bis(silyl)silylene

(2019) Dominik Reiter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Thermal Reactions of a Spiro-type Cyclotrisilene Obtained from the Reaction between a Disilenide and a Base Adduct of a Bromosilylene

(2019) Tomoyuki Kosai et al.   CHEMISTRY LETTERS

N-Heterocyclic Carbene-Stabilized Germanium and Tin Analogues of Heavier Nitriles: Synthesis, Reactivity, and Catalytic Application

(2019) Vitaly Nesterov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation and Computational Studies of a Series of Terphenyl Substituted Diplumbynes with Ligand Dependent Lead–Lead Multiple-Bonding Character

(2019) Joshua D. Queen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ge=B π-Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes

(2019) Dominik Raiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Crystalline Boragermenes

(2019) Bin Rao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low‐Valent Group 14 Phosphinidenide Complexes [({SIDipp}P) 2 M] Exhibit P–M pπ–pπ Interaction (M=Ge, Sn, Pb)

(2019) Markus Balmer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reaction of a boryl anion with silicon halides and alkoxysilanes: Synthesis of borylsilanes

(2019) Zhaocai Liu et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Low-valent group 14 element hydride chemistry: towards catalysis

(2018) Terrance J. Hadlington et al.   CHEMICAL SOCIETY REVIEWS

Functional Disilenes in Synthesis

(2018) Andreas Rammo et al.   CHEMISTRY-A EUROPEAN JOURNAL

1,2-Dihalodigermenes bearing bulky Eind groups: synthesis, characterization, and conversion to halogermylenoids

(2018) Naoki Hayakawa et al.   DALTON TRANSACTIONS

π-Electron systems containing Si=Si double bonds

(2018) Tsukasa Matsuo et al.   SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS

A Neutral η5 -Aminoborole Complex of Germanium(II)

(2018) Patrik Tholen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Road Travelled: After Main-Group Elements as Transition Metals

(2018) Catherine Weetman et al.   ChemCatChem

Arsagermene, a compound with an –AsGe double bond

(2018) Vladimir Ya. Lee et al.   CHEMICAL COMMUNICATIONS

Second-Order Jahn–Teller (SOJT) Structural Distortions in Multiply Bonded Higher Main Group Compounds

(2018) Henry B. Wedler et al.   ORGANOMETALLICS

A Three-Membered Cyclic Phosphasilene

(2018) Yannic Heider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Small Molecules by Compounds that Contain Triple Bonds Between Heavier Group-14 Elements

(2018) Jing-Dong Guo et al.   Chemistry-An Asian Journal

Geometrically Compelled Disilene with λ4-Coordinate SiII Atoms

(2018) Arseni Kostenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Germanium Compounds Containing Ge═E Double Bonds (E = S, Se, Te) as Single-Source Precursors for Germanium Chalcogenide Materials

(2017) Hyo-Suk Kim et al.   INORGANIC CHEMISTRY

Stable Push–Pull Disilene: Substantial Donor–Acceptor Interactions through the Si═Si Double Bond

(2017) Tomoyuki Kosai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

London dispersion forces in sterically crowded inorganic and organometallic molecules

(2017) David J. Liptrot et al.   Nature Reviews Chemistry

Diverse Reactivity of an Electrophilic Phosphasilene towards Anionic Nucleophiles: Substitution or Metal-Amino Exchange

(2016) Philipp Willmes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Heterocyclic Amino(phosphanylidene-σ4 -phosphorane) Germylene

(2016) Natalia Del Rio et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isolation and Versatile Derivatization of an Unsaturated Anionic Silicon Cluster (Siliconoid)

(2016) Philipp Willmes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene

(2016) Shenglai Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Two-Coordinate Cyclic (Alkyl)(amino)silylene: Balancing Thermal Stability and Reactivity

(2016) Tomoyuki Kosai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation and Reactivity of Electron-Precise B−B Single and Multiple Bonds

(2016) Merle Arrowsmith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cover Picture: A Metallaanthracene and Derived Metallaanthraquinone (Angew. Chem. Int. Ed. 1/2017)

(2016) Benjamin J. Frogley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cycloaddition of carbonyl compounds and alkynes to (di)silenes and (di)germenes: reactivity and mechanism

(2016) Kaarina K. Milnes et al.   CHEMICAL SOCIETY REVIEWS

Applications of N-heterocyclic imines in main group chemistry

(2016) Tatsumi Ochiai et al.   CHEMICAL SOCIETY REVIEWS

Reactivity in the periphery of functionalised multiple bonds of heavier group 14 elements

(2016) Carsten Präsang et al.   CHEMICAL SOCIETY REVIEWS

Intramolecular Tetrylene Lewis Adducts: Synthesis and Reactivity

(2016) Julia Schneider et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal-Free Dehydrogenation of Amine-Boranes by Tunable N-Heterocyclic Iminoboranes

(2016) Melanie W. Lui et al.   CHEMISTRY-A EUROPEAN JOURNAL

Concise access to iminophosphonamide stabilized heteroleptic germylenes: chemical reactivity and structural investigation

(2016) Billa Prashanth et al.   DALTON TRANSACTIONS

Pentasila-1,4-diene: Homoconjugation between Si═Si Double Bonds via a SiMe2 Unit

(2016) Tomoyuki Kosai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(Z)-1,2-Di(1-pyrenyl)disilene: Synthesis, Structure, and Intramolecular Charge-Transfer Emission

(2016) Megumi Kobayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A stable heavier group 14 analogue of vinylidene

(2016) Arnab Rit et al.   Nature Chemistry

Isolation of a Heavier Cyclobutadiene Analogue: 2,4-Digerma-1,3-diphosphacyclobutadiene

(2016) Yile Wu et al.   ORGANOMETALLICS

Heavier congeners of CO and CO2 as ligands: from zero-valent germanium (‘germylone’) to isolable monomeric GeX and GeX2 complexes (X = S, Se, Te)

(2016) Yun Xiong et al.   Chemical Science

Mixed guanidinato-amido Ge(iv) and Sn(iv) complexes with GeE (E = S, Se) double bond and SnS4, Sn2Se2 rings

(2016) Milan Kr. Barman et al.   RSC Advances

SiSi Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene

(2015) Priyabrata Ghana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

London Dispersion Decisively Contributes to the Thermodynamic Stability of Bulky NHC-Coordinated Main Group Compounds

(2015) J. Philipp Wagner et al.   Journal of Chemical Theory and Computation

1,1-Dilithiosilanes, 1,1-dilithiogermanes, 1,1-dilithiostannanes and related compounds: Organometallic reagents of the new generation

(2015) Vladimir Ya. Lee et al.   MENDELEEV COMMUNICATIONS

The multiple bonding in heavier group 14 element alkene analogues is stabilized mainly by dispersion force effects

(2015) Jing-Dong Guo et al.   Chemical Science

An N-Heterocyclic Silylene-Stabilized Digermanium(0) Complex

(2014) Yu-Liang Shan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stabilization of a Diphosphagermylene through pπ-pπ Interactions with a Trigonal-Planar Phosphorus Center

(2014) Keith Izod et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cover Picture: Excellent Stability of a Lithium-Ion-Conducting Solid Electrolyte upon Reversible Li+/H+Exchange in Aqueous Solutions (Angew. Chem. Int. Ed. 1/2015)

(2014) Cheng Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, structure and a nucleophilic coordination reaction of Germanetellurones

(2014) Bin Li et al.   DALTON TRANSACTIONS

Tetrakis(di-tert-butylmethylsilyl)digermene: Synthesis, Structure, Electrochemical Properties, and Reactivity

(2014) Vladimir Ya Lee et al.   HETEROATOM CHEMISTRY

Are Ligand-Stabilized Carboxylic Acid Derivatives with Ge═Te Bonds Isolable?

(2014) Rahul Kumar Siwatch et al.   INORGANIC CHEMISTRY

Use of Thio and Seleno Germanones as Ligands: Silver(I) Halide Complexes with Ge═E→Ag–I (E = S, Se) Moieties and Chalcogen-Dependent Argentophilic Interaction

(2014) Dhirendra Yadav et al.   INORGANIC CHEMISTRY

Stibasilene Sb═Si and Its Lighter Homologues: A Comparative Study

(2014) Vladimir Ya. Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tetrasilane-Bridged Bicyclo[4.1.0]heptasil-1(6)-ene

(2014) Akihiro Tsurusaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boron–Boron Multiple Bonding: From Charged to Neutral and Back Again

(2014) Holger Braunschweig et al.   ORGANOMETALLICS

Chemical Tricks To Stabilize Silanones and Their Heavier Homologues with EO Bonds (E=Si-Pb): From Elusive Species to Isolable Building Blocks

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

(2013) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coulomb repulsion versus cycloaddition: formation of anionic four-membered rings from sodium phosphaethynolate, Na(OCP)

(2013) Dominikus Heift et al.   DALTON TRANSACTIONS

Digermylene Oxide Complexes: Facile Synthesis and Reactivity

(2013) Rahul Kumar Siwatch et al.   INORGANIC CHEMISTRY

A Cyclic Germadicarbene (“Germylone”) from Germyliumylidene

(2013) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Reactivity of N-Aminotroponiminatogermylenepyrrole and Its Derivatives

(2013) Surendar Karwasara et al.   ORGANOMETALLICS

Heavier Main Group Dimetallene Reactivity: Effects of Frontier Orbital Symmetry

(2013) Christine A. Caputo et al.   ORGANOMETALLICS

Reversible Base Coordination to a Disilene

(2012) Kinga Leszczyńska et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aminotroponiminatogermaacid Halides with a Ge(E)X Moiety (E = S, Se; X = F, Cl)

(2012) Soumen Sinhababu et al.   INORGANIC CHEMISTRY

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Disilene with π-Accepting Groups from the Reaction of Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]) with Isocyanides

(2012) Katsuhiko Takeuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A stable germanone as the first isolated heavy ketone with a terminal oxygen atom

(2012) Liangchun Li et al.   Nature Chemistry

Germaester Complexes with a Ge(E)Ot-Bu Moiety (E = S or Se)

(2012) Rahul Kumar Siwatch et al.   ORGANOMETALLICS

A Stable Derivative of the Global Minimum on the Si6H6 Potential Energy Surface

(2011) Kai Abersfelder et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphination of Carbon Monoxide: A Simple Synthesis of Sodium Phosphaethynolate (NaOCP)

(2011) Florian Frank Puschmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A blue digermene (t-Bu2MeSi)2GeGe(SiMet-Bu2)2

(2011) Vladimir Ya. Lee et al.   CHEMICAL COMMUNICATIONS

Synthesis, Structure, and Reactivity of a Pyridine-Stabilized Germanone

(2011) Shenglai Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

C–H Activation of Cycloalkenes by Dimetallynes (M = Ge, Sn) under Ambient Conditions

(2011) Owen T. Summerscales et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bulky Aminotroponiminate-Stabilized Germylene Monochloride and Its Alkyne Derivatives

(2011) Rahul Kumar Siwatch et al.   ORGANOMETALLICS

A Planar Rhombic Charge-Separated Tetrasilacyclobutadiene

(2011) K. Suzuki et al.   SCIENCE

Silicon Analogues of Carboxylic Acids: Synthesis of Isolable Silanoic Acids by Donor-Acceptor Stabilization

(2010) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Activation of EH3 (E=P, As) by an Ylide-like Silylene and Formation of a Donor-Stabilized Arsasilene with a HSiAsH Subunit

(2010) Carsten Präsang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

Heteronuclear Double Bonds E=E′ (E = Heavy Group 14 Element, E′ = Group 13–16 Element)

(2010) Vladimir Ya. Lee et al.   CHEMISTRY LETTERS

Synthesis and Reaction of Monomeric Germanium(II) and Lead(II) Dimethylamide and the Synthesis of Germanium(II) Hydrazide by Clevage of one N−H bond of Hydrazine

(2010) Anukul Jana et al.   INORGANIC CHEMISTRY

Silicon version of enamines: Amino-substituted disilenes by the reactions of the disilyne RSiSiR (R = SiiPr[CH(SiMe3)2]2) with amines

(2010) Katsuhiko Takeuchi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Unsymmetrically Substituted Disilyne Dsi2iPrSi—Si≡Si—SiNpDsi2(Np = CH2tBu): Synthesis and Characterization

(2010) Yoshitaka Murata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Air-Stable, Room-Temperature Emissive Disilenes with π-Extended Aromatic Groups

(2010) Megumi Kobayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AnN-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl2

(2010) Torahiko Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

A Tricyclic Aromatic Isomer of Hexasilabenzene

(2010) K. Abersfelder et al.   SCIENCE

A Bis(silaselenone) with Two Donor-Stabilized SiSe Bonds from an Unexpected Stereoconvergent Hydrolysis of a Diselenadisiletane

(2009) Amitabha Mitra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From NHC→germylenes to stable NHC→germanone complexes

(2009) Shenglai Yao et al.   CHEMICAL COMMUNICATIONS

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

A stable silagermene (tBu3Si)2Si=Ge(mes)2(mes = 2,4,6-trimethylphenyl): Synthesis, X-ray crystal structure, and thermal isomerization

(2009) Masayasu Igarashi et al.   HETEROATOM CHEMISTRY

Anthryl-Substituted Trialkyldisilene Showing Distinct Intramolecular Charge-Transfer Transition

(2009) Takeaki Iwamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

π-Conjugated Phosphasilenes Stabilized by Fused-Ring Bulky Groups

(2009) Baolin Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Unusual Bonding in Trisilaallene and Related Heavy Allenes

(2009) Mitsuo Kira et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Addition of Amines and Hydroborane to the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) Giving Amino- and Boryl-Substituted Disilenes

(2009) Katsuhiko Takeuchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A “Push−Pull” Phosphasilene and Phosphagermene and Their Anion-Radicals

(2009) Vladimir Ya. Lee et al.   ORGANOMETALLICS

1,3-Digerma-2-gallata- and -indataallenic Anions: The First Compounds with Ge=Ga or Ge=In Double Bonds

(2008) Norio Nakata et al.   CHEMISTRY LETTERS

Molecular Single-Bond Covalent Radii for Elements 1-118

(2008) Pekka Pyykkö et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Reactions of a Stable 1,2-Diaryl-1,2-dibromodisilene: A Precursor for Substituted Disilenes and a 1,2-Diaryldisilyne

(2008) Takahiro Sasamori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

(2008) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

1,2-Bis(ferrocenyl)disilene: A Multistep Redox System with an SiSi Double Bond

(2008) Takahiro Sasamori et al.   ORGANOMETALLICS

The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)

(2008) Selvarajan Nagendran et al.   ORGANOMETALLICS

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE