Cycloaddition of carbonyl compounds and alkynes to (di)silenes and (di)germenes: reactivity and mechanism

Reductive Cleavage of Carbon Monoxide by a Disilenide

(2015) Moumita Majumdar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of the addition of alkynes to silenes and germenes: A density functional study

(2015) Laura C. Pavelka et al.   CANADIAN JOURNAL OF CHEMISTRY

Synthesis and Characterization of a 1,2-Digermabenzene

(2015) Takahiro Sasamori et al.   ORGANOMETALLICS

The addition of terminal alkynes to dimesitylfluorenylidenegermane

(2014) Nada Y. Tashkandi et al.   CANADIAN JOURNAL OF CHEMISTRY

Isolable 2,3-Disila-1,3-butadiene from a Double Sila-Peterson Reaction

(2014) Daiki Motomatsu et al.   CHEMISTRY-A EUROPEAN JOURNAL

σ-π Conjugated Organosilicon Hybrid Polymers from Copolymerization of a Tetrasiladiene and 1,4-Diethynylbenzene

(2014) Moumita Majumdar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tetrakis(di-tert-butylmethylsilyl)digermene: Synthesis, Structure, Electrochemical Properties, and Reactivity

(2014) Vladimir Ya Lee et al.   HETEROATOM CHEMISTRY

Thermal reactions of pivaloyl- and adamantoyl(tert-butylethynyl)bis(trimethylsilyl)silane with 2,3-dimethylbutadiene and diphenylacetylene

(2014) Akinobu Naka et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

NHC-Stabilized Silagermenylidene: A Heavier Analogue of Vinylidene

(2013) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A New Family of Multiple-Bond Compounds between Heavier Group 14 Elements

(2013) Takahiro Sasamori et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Brook silenes: inspiration for a generation

(2013) Kim M. Baines   CHEMICAL COMMUNICATIONS

The mechanism of addition of aldehydes to germene in different solvents: A DFT study

(2013) Jia Zhou et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The Osmium–Silicon Triple Bond: Synthesis, Characterization, and Reactivity of an Osmium Silylyne Complex

(2013) Paul G. Hayes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potential Protecting Group Strategy for Disila Analogues of Vinyllithiums: Synthesis and Reactivity of a 2,4,6-Trimethoxyphenyl-Substituted Disilene

(2013) Antje Meltzer et al.   ORGANOMETALLICS

Recent Developments in the Reactivity of Stable Disilynes

(2012) Matthew Asay et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Substituent Effects in Thermal Reactions of a Silene with Silyl-Substituted Alkynes: A Theoretical Study

(2012) Hiromasa Tanaka et al.   ORGANOMETALLICS

Bonding and structure of disilenes and related unsaturated group-14 element compounds

(2012) Mitsuo KIRA   PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES

Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

(2011) Philip P. Power   ACCOUNTS OF CHEMICAL RESEARCH

Addition of a cyclopropyl alkyne to tetramesityldigermene: evidence for a biradical intermediate

(2011) Krysten L. Hurni et al.   CHEMICAL COMMUNICATIONS

Silicon–carbon unsaturated compounds. 77. Thermal behavior of cis- and trans-1-silacyclobut-3-ene formed from pivaloyl[tert-butylbis(trimethylsilyl)]silane and tert-butylacetylene

(2011) Akinobu Naka et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Reactivity of a Germene toward Terminal Alkynes: Competition between Cycloaddition, Ene-Addition, and CH-Insertion

(2011) Laura C. Pavelka et al.   ORGANOMETALLICS

Addition of Aldehydes to Germenes: The Influence of Solvent

(2011) Christopher J. Allan et al.   ORGANOMETALLICS

Theoretical Study on the Formation of Silacyclopropene from Acylsilane and Acetylene via Silene-to-Silylene Rearrangement

(2011) Hiromasa Tanaka et al.   ORGANOMETALLICS

Reactivities of Adamantyl-Substituted Metallenes with a C═E (E = C, Si, Ge, Sn, and Pb) Double Bond. A Theoretical Study

(2011) Bo-Ying Li et al.   ORGANOMETALLICS

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

Reactions of germenes with various naphthoquinones controlled by substituent effects

(2010) Dumitru Ghereg et al.   DALTON TRANSACTIONS

π-Conjugated disilenes stabilized by fused-ring bulky “Rind” groups

(2010) Tsukasa Matsuo et al.   DALTON TRANSACTIONS

Silyl–substituted germenes. The reactions of germenes generated thermally from acyltris(trimethylsilyl)germane with conjugated enones

(2010) Akinobu Naka et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

The Reactivity of Phosphagermaallene Mes*P═C═Ge(t-Bu)Tip toward Aldehydes and Ketones: an Experimental and Theoretical Study

(2010) F. Ouhsaine et al.   ORGANOMETALLICS

Probing the Mechanism of Aldehyde Addition to a Disilene and Two Silenes: Solvent Effects

(2010) Julie A. Hardwick et al.   ORGANOMETALLICS

Reactions of Germenes with Somepara-Quinones: Formation of a Tricyclic Compound from 1,4-Benzoquinone Undergoing an Unexpected Rearrangement†

(2010) Dumitru Ghereg et al.   ORGANOMETALLICS

Reactivity of a Polar Silene toward Terminal Alkynes: Preference for C−H Insertion over Cycloaddition

(2010) Kaarina K. Milnes et al.   ORGANOMETALLICS

Synthesis of homo- and heterocyclic silanes via intermediates with Si=Si bonds

(2010) Kai Abersfelder et al.   PURE AND APPLIED CHEMISTRY

An isolable o-quinodimethane and its fixation of molecular oxygen to give an endoperoxide

(2009) Dumitru Ghereg et al.   CHEMICAL COMMUNICATIONS

Anionic Reagents with Silicon-Containing Double Bonds

(2009) David Scheschkewitz   CHEMISTRY-A EUROPEAN JOURNAL

Laser Flash Photolysis Studies of Some Dimethylgermylene Precursors

(2009) Farahnaz Lollmahomed et al.   ORGANOMETALLICS

Silicon−Carbon Unsaturated Compounds. 76. Photochemical and Thermal Behavior of 1-Silacyclobut-3-enes Generated from the Reaction of Pivaloyltris(trimethylsilyl)silane withtert-Butylacetylene

(2009) Akinobu Naka et al.   ORGANOMETALLICS

A mechanistic study of the addition of alkynes to Brook silenes

(2008) Kaarina K Milnes et al.   CANADIAN JOURNAL OF CHEMISTRY

An unexpected epoxidation of benzil derivatives in their reaction with a germene

(2008) Sakina Ech-Cherif El Kettani et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Silicon−Carbon Unsaturated Compounds. 74. Thermal Behavior of 1-Silacyclobut-3-enes Generated from the Reaction of Acylpolysilanes withtert-Butylacetylene

(2008) Akinobu Naka et al.   ORGANOMETALLICS

Synthesis of a 1-Hydrosilene Stable in Solution and Its Unique Properties#

(2008) Shuhei Ozaki et al.   ORGANOMETALLICS

Competing Germene and Germylene Extrusion from Photolysis of 1,1-Diarylgermacyclobutanes. Substituent Effects on Germene Reactivity

(2008) William J. Leigh et al.   ORGANOMETALLICS

Silenes: Connectors between classical alkenes and nonclassical heavy alkenes

(2007) Henrik Ottosson et al.   COORDINATION CHEMISTRY REVIEWS