4.7 Article

Thermal decomposition kinetics and properties of grafted barley husk reinforced PVA/starch composite films for packaging applications

Journal

CARBOHYDRATE POLYMERS
Volume 240, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2020.116225

Keywords

Composite films; Thermal degradation; Isoconversional methods; Mechanical properties; Barrier properties; Soil burial degradation

Ask authors/readers for more resources

Thermal degradation kinetics was performed on thermogravimetric (TGA) curves of crosslinked PVA/starch composite films reinforced with barley husk (BH) and grafted BH (using lauric acid) obtained by heating samples in an inert atmosphere with different heating rates (5, 10, 15 and 20 degrees C/min). The activation energy for composite films was determined using Flynn-Wall-Ozawa (FWO) Kissinger-Akahira-Sunose (KAS), Friedman (FR) and modified Coasts Redfern (CR) methods. The results showed that activation energy for thermal degradation of grafted BH composite film was higher than of BH. Incorporation of grafted BH into crosslinked PVA/starch matrix improved the mechanical performance of the films compared to BH and showed 30 % increase in tensile strength after reinforcement. Grafted BH composite films showed higher barrier properties for light, water vapor and oxygen as required for packaging applications. Biodegradability of the films improved significantly after incorporation of BH into the polymer matrix and showed 70 % degradation after 180 days.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Environmental Sciences

Modeling and optimization of Nile blue sulfate mineralization by heterogeneous fenton oxidation

Rajkamal Kushwaha, Sangeeta Garg, Shailendra Bajpai

TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY (2019)

Article Materials Science, Characterization & Testing

The influence of fatty acid chain length on the chemical, physical and morphological properties of the grafted barley husk for application in biocomposites

Aanchal Mittal, Sangeeta Garg, Shailendra Bajpai

POLYMER TESTING (2019)

Article Chemistry, Multidisciplinary

Modeling the performance of HPA membrane for sulfate ion removal from Ternary ion system

Shailendra Bajpai, Robin Marlar Rajendran, Sanjeevani Hooda

KOREAN JOURNAL OF CHEMICAL ENGINEERING (2019)

Article Environmental Sciences

Application of ANN and RSM on fluoride removal using chemically activated D. sissoo sawdust

Saurabh Joshi, Shailendra Bajpai, Somen Jana

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2020)

Article Materials Science, Characterization & Testing

Synthesis of polyvinyl alcohol/modified starch-based biodegradable nanocomposite films reinforced with starch nanocrystals for packaging applications

Aanchal Mittal, Sangeeta Garg, Anshuman Premi, Ardhendu Sekhar Giri

Summary: The grafting of oleic acid onto corn starch and the synthesis of SNCs improved the tensile strength and water uptake of PVA matrix, showing potential as alternative biodegradable packaging films.

POLYMERS & POLYMER COMPOSITES (2021)

Article Environmental Sciences

Modelling of arsenic (III) removal from aqueous solution using film theory combined Spiegler-Kedem model: pilot-scale study

Robin Marlar Rajendran, Sangeeta Garg, Shailendra Bajpai

Summary: This study successfully removed arsenic (III) from water using HFN300 polyethersulfone nanofiltration membrane, achieving over 96.4% rejection for 50 mg L-1 feed at optimized conditions. The FTCSK model was effective in predicting arsenic (III) removal using NF membrane, with simulated results in excellent agreement with experimental results within 10% error.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2021)

Review Energy & Fuels

Biorefining of leather solid waste to harness energy and materials-A review

V. N. S. Gunasri Appala, Nitin Naresh Pandhare, S. Bajpai

Summary: The tannery business is crucial in the global economy, but it also contributes significantly to environmental pollution. Recent technologies that utilize waste as a feedstock for energy or value-added products can potentially reduce reliance on nonrenewable resources. This review explores various methods for converting tannery waste into marketable products and energy, highlighting the potential for sustainable biorefinery development.

BIOMASS CONVERSION AND BIOREFINERY (2022)

Review Chemistry, Multidisciplinary

Economic feasibility of arsenic removal using nanofiltration membrane: A mini review

Robin Marlar Rajendran, Sangeeta Garg, Shailendra Bajpai

Summary: Arsenic contamination in drinking water is a global issue, with 230 million people exposed to it, primarily in South Asian developing countries. The World Health Organization recommends a maximum contaminant limit of 0.01 mg/L for arsenic in drinking water. High-pressure membrane separation processes like reverse osmosis and nanofiltration are promising methods for achieving recommended drinking water quality.

CHEMICAL PAPERS (2021)

Proceedings Paper Materials Science, Multidisciplinary

Fabrication and characteristics of poly (vinyl alcohol)-starch-cellulosic material based biodegradable composite film for packaging application

Aanchal Mittal, Sangeeta Garg, Shailendra Bajpai

MATERIALS TODAY-PROCEEDINGS (2020)

Article Engineering, Chemical

Study of adherence kinetics of Escherichia coli on cotton knitted fabrics

S. Bajpai, Vidushi Bajpai, Apurba Dey, Subrata Ghosh, M. K. Jha

INDIAN CHEMICAL ENGINEER (2019)

Review Chemistry, Applied

Molecular dynamics simulation techniques and their application to aroma compounds/cyclodextrin inclusion complexes: A review

Xingran Kou, Dongdong Su, Fei Pan, Xiwei Xu, Qingran Meng, Qinfei Ke

Summary: This review provides a systematic discussion of the application of molecular dynamics (MD) simulations in aroma compounds (ACs)/cyclodextrins (CDs) inclusion complexes (ICs). It covers the establishment of the simulation process, parameter selection, model evaluation, and various application cases, summarizing the major achievements and challenges of this method.

CARBOHYDRATE POLYMERS (2024)

Review Chemistry, Applied

Opportunities and challenges of fucoidan for tumors therapy

Haoyu Yu, Quanbin Zhang, Ammad Ahmad Farooqi, Jing Wang, Yang Yue, Lihua Geng, Ning Wu

Summary: Brown algae are rich in fucoidan, which has been found to have anti-cancer and anti-metastasis effects. Fucoidan inhibits tumor cell growth, proliferation, and metastasis, and also promotes immune responses in the tumor microenvironment.

CARBOHYDRATE POLYMERS (2024)

Review Chemistry, Applied

A review of chitosan in gene therapy: Developments and challenges

Liang Dong, Yanan Li, Hailin Cong, Bing Yu, Youqing Shen

Summary: Gene therapy is a revolutionary treatment that requires suitable vectors for protecting and releasing exogenous nucleic acids in target cells. Chitosan, as a non-viral vector, has gained attention due to its good biocompatibility and ability to load large amounts of nucleic acids. This paper summarizes the potential of chitosan and its derivatives as gene delivery vector materials, discusses factors influencing transfection efficiency, performance evaluation, ways to optimize infectious efficiency, and current research development directions. It also provides an outlook on the future prospects of chitosan.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Vancomycin-loaded methylcellulose aerogel scaffolds for advanced bone tissue engineering

Ana Iglesias-Mejuto, Beatriz Magarinos, Tania Ferreira-Goncalves, Ricardo Starbird-Perez, Carmen Alvarez-Lorenzo, Catarina Pinto Reis, Ines Ardao, Carlos A. Garcia-Gonzalez

Summary: This study developed a novel processing strategy to manufacture drug-loaded and personalized aerogels with nanostructures. The aerogels demonstrated bioactivity and antimicrobial effects, promoting bone regeneration and preventing infections in bone tissue engineering.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Micro assembly strategies for enhancing solid-state emission of cellulose nanocrystals and application in photoluminescent inks

Zhenxu Shi, Dimei Yang, Yan Zhou, Xinyu Chen, Lin Gan, Jin Huang

Summary: This study proposes a micro-assembly method to improve the photoluminescent properties of crystalline cellulose nanocrystals (CNCs) by organizing them within a sub-micrometer-sized metal-organic framework and coating with TiO2. The TiO2 coating prevents CNC assembly breakdown and allows information to be revealed using screenprinted labels for anti-counterfeiting purposes.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

High-throughput intact Glycopeptide quantification strategy with targeted-MS (HTiGQs-target) reveals site-specific IgG N-glycopeptides as biomarkers for hepatic disorder diagnosis and staging

Xuejiao Liu, Bin Fu, Jierong Chen, Zhenyu Sun, Dongdong Zheng, Zhonghua Li, Bing Gu, Ying Zhang, Haojie Lu

Summary: Liver disease is a major cause of global mortality, and identifying biomarkers for diagnosing its progression is crucial for improving outcomes. Targeted mass spectrometry is a powerful tool for verifying biomarker candidates and clinical applications, particularly for glycoproteins translation. However, the limitation of analyzing only one sample per run has become apparent. In this study, a high-throughput intact N-glycopeptides quantification strategy was developed, allowing the validation of 20 samples per run with an average analysis time of 3 minutes per sample. The strategy was applied in a cohort of 461 serum samples and identified a panel of 10 IgG N-glycopeptides that have strong clinical utility in evaluating the severity of liver disease.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

β-Glucan-conjugated anti-PD-L1 antibody enhances antitumor efficacy in preclinical mouse models

Qian Wang, Hao Jiang, Hongli Zhang, Weiqiao Lu, Xiao Wang, Wenfeng Xu, Jia Li, Youjing Lv, Guoyun Li, Chao Cai, Guangli Yu

Summary: This study proposes a novel strategy of antibody-beta-glucan conjugates (AGC) to enhance the antitumor immune response to immune checkpoint blockade (ICB) therapy. AGC demonstrated powerful tumor suppression and promoted interaction between tumor cells and dendritic cells (DCs), thereby enhancing immunotherapeutic benefits.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Enhanced porous membrane fabrication using cellulose acetate and citric acid: Improved structural integrity, thermal stability, and gas permeability

Chaeyeon Lee, Sojeong Lee, Sang Wook Kang

Summary: The study aims to enhance the properties of porous membranes by addressing the limitations associated with phase separation. By using cellulose acetate and citric acid, the researchers were able to fabricate membranes with improved mechanical strength and thermal stability. The cross-linking effect of citric acid resulted in a more uniform pore structure and higher porosity.

CARBOHYDRATE POLYMERS (2024)

Review Chemistry, Applied

Stimuli-responsive polysaccharide-based smart hydrogels for diabetic wound healing: Design aspects, preparation methods and regulatory perspectives

Tejaswini Kolipaka, Giriraj Pandey, Noella Abraham, Dadi A. Srinivasarao, Rajeev Singh Raghuvanshi, P. S. Rajinikanth, Vidya Tickoo, Saurabh Srivastava

Summary: This review focuses on the design and application of polysaccharide-based hydrogel wound dressings, highlighting aspects such as biocompatibility, biodegradability, drug entrapment, moisturizing ability, swelling, and mechanical properties. Additionally, various crosslinking methods and recent developments in stimuli-responsive hydrogels are discussed.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

A highly stretchable, adhesive, and antibacterial hydrogel with chitosan and tobramycin as dynamic cross-linkers for treating the infected diabetic wound

Anqi Xu, Nan Zhang, Shixing Su, Hongyu Shi, Daoqiang Lu, Xifeng Li, Xin Zhang, Xin Feng, Zhuohua Wen, Gengwu Ma, Mengshi Huang, Chi Huang, Yuqi Hu, Hao Yuan, Qinwen Liu, Daogang Guan, Jun Wang, Chuanzhi Duan

Summary: The study presents a one-pot radical polymerization method to fabricate a hydrogel with adhesive properties, which can effectively treat bacterial-infected diabetic wounds and accelerate wound healing.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Valorization of shrimp processing waste-derived chitosan into anti-inflammatory chitosan-oligosaccharides (CHOS)

Montarop Yamabhai, Munthipha Khamphio, Thae Thae Min, Chai Noy Soem, Nguyen Cao Cuong, Waheni Rizki Aprilia, Krisanai Luesukprasert, Karsidete Teeranitayatarn, Atthaphon Maneedaeng, Tina R. Tuveng, Silje B. Lorentzen, Simen Antonsen, Paiboon Jitprasertwong, Vincent G. H. Eijsink

Summary: The study investigates the bioconversion of chitosan into soluble anti-inflammatory chitosan oligosaccharides (CHOS) using an enzyme. The results show that the generated CHOS have anti-inflammatory activity, but the magnitude of the activity depends on the substrate and production process. Different methods of dissolving chitosan also affect the properties of CHOS. The study highlights the importance of quality assurance in CHOS preparations.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Structural elucidation of an active polysaccharide from Radix Puerariae lobatae and its protection against acute alcoholic liver disease

Wen Cao, Jiangping Wu, Xinya Zhao, Zixu Li, Jie Yu, Taili Shao, Xuefeng Hou, Lutan Zhou, Chunfei Wang, Guodong Wang, Jun Han

Summary: In this study, a water-soluble polysaccharide (PLP1) was successfully isolated and purified from Pueraria lobata. It was found that PLP1 was composed of specific glycosidic units and exhibited a better free radical-scavenging ability. Moreover, PLP1 effectively protected the liver against acute alcoholic liver disease (ALD) in mice.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Caffeic acid-grafted chitosan/sodium alginate/nanoclay-based multifunctional 3D-printed hybrid scaffolds for local drug release therapy after breast cancer surgery

Ya Su, Yaqian Liu, Xueyan Hu, Yueqi Lu, Jinyuan Zhang, Wenbo Jin, Wang Liu, Yan Shu, Yuen Yee Cheng, Wenfang Li, Yi Nie, Bo Pan, Kedong Song

Summary: A 3D printed scaffold based on carbon dots-curcumin nano-drug release has been developed for drug delivery after breast cancer surgery. The scaffold showed effective inhibition of tumor growth, antibacterial activity, and promotion of wound healing, making it a promising approach for preventing tumor recurrence.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Enzymatically-derived oligo-carrageenans interact with α-Gal antibodies and Galectin-3

Ekaterina Sokolova, Diane Jouanneau, Antonin Chevenier, Murielle Jam, Nathalie Desban, Pierre Colas, Elizabeth Ficko-Blean, Gurvan Michel

Summary: Carrageenans, a compound synthesized in red algae, have various biological properties and are valuable in the pharmaceutical and cosmetic industries. Their fine structure affects wound healing, oxidative processes, hemostasis, and inflammation. Enzymatic modification of carrageenans produces oligosaccharides that bind to natural human serum antibodies and specific antibodies, showing potential for therapeutic applications.

CARBOHYDRATE POLYMERS (2024)

Article Chemistry, Applied

Immuno-modulation of tumor and tumor draining lymph nodes through enhanced immunogenic chemotherapy by nano-complexed hyaluronic acid/polyvinyl alcohol microneedle

Yan Shi, Miao Yu, Kaijin Qiu, Tiantian Kong, Chunjing Guo, Wenxue Zhang, Daquan Chen, Ming Kong

Summary: In this study, functionalized transfersomes were developed to co-deliver doxorubicin and 1MT towards primary tumors and tumor draining lymph nodes via transdermal administration using microneedles. The results showed that the nano-complexed microneedles exhibited a stronger suppression in tumor growth compared to the intravenous group.

CARBOHYDRATE POLYMERS (2024)