Selenide-Catalyzed Stereoselective Construction of Tetrasubstituted Trifluoromethylthiolated Alkenes with Alkynes

Enantioselective Trifluoromethylthiolating Lactonization Catalyzed by an Indane-Based Chiral Sulfide

(2016) Xiang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkenylation of Arenes and Heteroarenes with Alkynes

(2016) Vadim P. Boyarskiy et al.   CHEMICAL REVIEWS

Copper-Catalyzed Perfluoroalkylthiolation of Alkynes with Perfluoroalkanesulfenamides

(2016) Anis Tlili et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids

(2016) Lisa Candish et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of (Z)-α-Trifluoromethyl Alkenyl Triflate: A Scaffold for Diverse Trifluoromethylated Species

(2016) Yilong Zhao et al.   JOURNAL OF ORGANIC CHEMISTRY

N-Trifluoromethylthio-dibenzenesulfonimide: A Shelf-Stable, Broadly Applicable Electrophilic Trifluoromethylthiolating Reagent

(2016) Panpan Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

A Practical Solution to Stereodefined Tetrasubstituted Olefins

(2016) Jianxin Dai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Stereoselective Cyanotriflation of Alkynes Using Aryl(cyano)iodonium Triflates

(2016) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Novel Use of CF3SO2Cl for the Metal-Free Electrophilic Trifluoromethylthiolation

(2016) Hélène Chachignon et al.   ORGANIC LETTERS

AgSCF3-Mediated Oxidative Trifluoromethythiolation of Alkynes with Dearomatization to Synthesize SCF3-Substituted Spiro[4,5]trienones

(2016) Dong-Po Jin et al.   ORGANIC LETTERS

Organoselenium-Catalyzed Synthesis of Oxygen- and Nitrogen-Containing Heterocycles

(2016) Ruizhi Guo et al.   ORGANIC LETTERS

Recent advances in trifluoromethylthiolation using nucleophilic trifluoromethylthiolating reagents

(2016) Huidong Zheng et al.   TETRAHEDRON LETTERS

A Broadly Applicable Method for Pd-Catalyzed Carboperfluoro-alkylation of Terminal and Internal Alkynes: A Convenient Route to Tri- and Tetrasubstituted Olefins

(2016) Sylwester Domański et al.   ACS Catalysis

Direct Trifluoromethylthiolation of Unactivated C(sp3)H Using Silver(I) Trifluoromethanethiolate and Potassium Persulfate

(2015) Hao Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Mediated Oxidative Aliphatic CH Trifluoromethylthiolation

(2015) Shuo Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes

(2015) Ren Tomita et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective access to CF3S-substituted dihydrofurans from homopropargylic alcohols with trifluoromethanesulfenamide

(2015) Dao-Qian Chen et al.   CHEMICAL COMMUNICATIONS

Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes

(2015) Tao Yang et al.   CHEMICAL COMMUNICATIONS

Triphenylphosphine-Mediated Deoxygenative Reduction of CF3 SO2 Na and Its Application for Trifluoromethylthiolation of Aryl Iodides

(2015) Yi Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sandmeyer-Type Trifluoromethylthiolation and Trifluoromethylselenolation of (Hetero)Aromatic Amines Catalyzed by Copper

(2015) Christian Matheis et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Vinyl Trifluoromethyl Thioethers via Copper-Mediated Trifluoromethylthiolation of Vinyl Bromides

(2015) Yangjie Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Three-Component Domino Reactions of Aryl Grignard Reagents, Alkynes, and Aryl Halides Producing Tetrasubstituted Alkenes

(2015) Fei Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed

(2015) Guoyin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diaryl Selenide Catalyzed Vicinal Trifluoromethylthioamination of Alkenes

(2015) Jie Luo et al.   ORGANIC LETTERS

Organoselenium-Catalyzed, Hydroxy-Controlled Regio- and Stereoselective Amination of Terminal Alkenes: Efficient Synthesis of 3-Amino Allylic Alcohols

(2015) Zhimin Deng et al.   ORGANIC LETTERS

Lewis Acid Mediated Trifluoromethylthio Lactonization/Lactamization

(2015) Chunfa Xu et al.   ORGANIC LETTERS

Organoselenium-catalyzed synthesis of indoles through intramolecular C–H amination

(2015) Xuelin Zhang et al.   Organic Chemistry Frontiers

N-Trifluoromethylthiosaccharin: An Easily Accessible, Shelf-Stable, Broadly Applicable Trifluoromethylthiolating Reagent

(2014) Chunfa Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Catalytic Trifluoromethylthiolation of Boronic Acids and Alkynes Employing Electrophilic Shelf-StableN-(trifluoromethylthio)phthalimide

(2014) Roman Pluta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide

(2014) Jian-Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A facile and general route to 3-((trifluoromethyl)thio)benzofurans and 3-((trifluoromethyl)thio)benzothiophenes

(2014) Jie Sheng et al.   CHEMICAL COMMUNICATIONS

Hydrotrifluoromethylthiolation of α-diazo esters – synthesis of α-SCF3 substituted esters

(2014) Quentin Lefebvre et al.   CHEMICAL COMMUNICATIONS

Catalytic enantioselective trifluoromethylthiolation of oxindoles using shelf-stable N-(trifluoromethylthio)phthalimide and a cinchona alkaloid catalyst

(2014) Magnus Rueping et al.   CHEMICAL COMMUNICATIONS

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Photochromism of Diarylethene Molecules and Crystals: Memories, Switches, and Actuators

(2014) Masahiro Irie et al.   CHEMICAL REVIEWS

Recent Progress in Direct Introduction of Fluorinated Groups on Alkenes and Alkynes by means of CH Bond Functionalization

(2014) Tatiana Besset et al.   CHEMISTRY-A EUROPEAN JOURNAL

Selective and Scalable Synthesis of Trifluoromethanesulfenamides and Fluorinated Unsymmetrical Disulfides using a Shelf-Stable Electrophilic SCF3Reagent

(2014) Roman Pluta et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Trifluoromethylthiolation of Alcohols under Mild Reaction Conditions: Conversion of ROH into RSCF3

(2014) Pavlo Nikolaienko et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trifluoromethyl Ethers and –Thioethers as Tools for Medicinal Chemistry and Drug Discovery

(2014) Gregory Landelle et al.   CURRENT TOPICS IN MEDICINAL CHEMISTRY

Direct Trifluoromethylthiolation Reactions: The “Renaissance” of an Old Concept

(2014) Fabien Toulgoat et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanistic, crystallographic and computational studies on the catalytic, enantioselective sulfenofunctionalization of alkenes

(2014) Scott E. Denmark et al.   Nature Chemistry

A Facile and General Approach to 3-((Trifluoromethyl)thio)-4H-chromen-4-one

(2014) Haoyue Xiang et al.   ORGANIC LETTERS

Zinc(II) Catalyzed Conversion of Alkynes to Vinyl Triflates in the Presence of Silyl Triflates

(2014) Mohammed H. Al-huniti et al.   ORGANIC LETTERS

Copper-Catalyzed Direct Trifluoromethylthiolation of Benzylic C–H Bonds via Nondirected Oxidative C(sp3)–H Activation

(2014) Chao Chen et al.   ORGANIC LETTERS

Copper-Catalyzed Trifluoromethylthiolation of Aryl Halides with Diverse Directing Groups

(2014) Jiabin Xu et al.   ORGANIC LETTERS

Copper-Catalyzed Synthesis of α-Trifluoromethylthio-Substituted Ketones

(2014) Yangjie Huang et al.   ORGANIC LETTERS

Copper-Catalyzed Intramolecular Oxytrifluoromethylthiolation of Unactivated Alkenes

(2014) Liping Zhu et al.   ORGANIC LETTERS

A mild and fast photocatalytic trifluoromethylation of thiols in batch and continuous-flow

(2014) Natan J. W. Straathof et al.   Chemical Science

Formation of CSCF3Bonds through Direct Trifluoromethylthiolation

(2013) Anis Tlili et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Catalyzed Electrophilic Trifluoromethylthiolation of Terminal Alkynes

(2013) Sébastien Alazet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Electrophilic Hypervalent Iodine Reagent for Trifluoromethylthiolation

(2013) Xinxin Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Trifluoromethylthiophthalimide: A Stable Electrophilic SCF3-Reagent and its Application in the Catalytic Asymmetric Trifluoromethylsulfenylation

(2013) Teerawut Bootwicha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemicals from Alkynes with Palladium Catalysts

(2013) Rafael Chinchilla et al.   CHEMICAL REVIEWS

Copper-Catalyzed Trifluoromethyl Thiolation-Mild and Efficient Synthesis of Trifluoromethyl Thioethers

(2013) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Electrophilic Carbofunctionalization of Alkynes to Highly Functionalized Tetrasubstituted Alkenes

(2013) Marcos G. Suero et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters

(2013) Yu-Dong Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Trifluoromethylthiolation of Allylsilanes with Trifluoromethanesulfanamide

(2013) Jianbo Liu et al.   ORGANIC LETTERS

Electrophilic Trifluoromethanesulfanylation of Organometallic Species with Trifluoromethanesulfanamides

(2012) François Baert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Oxidative Trifluoromethylthiolation of Aryl Boronic Acids with TMSCF3 and Elemental Sulfur

(2012) Chao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sequential Electrophilic Trifluoromethanesulfanylation–Cyclization of Tryptamine Derivatives: Synthesis of C(3)-Trifluoromethanesulfanylated Hexahydropyrrolo[2,3-b]indoles

(2012) Yi Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur

(2012) Chao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Synthesis of ArSCF3 Compounds under Mild Conditions

(2011) Georgiy Teverovskiy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Synthesis of Aryl Trifluoromethyl Sulfides at Room Temperature

(2011) Cheng-Pan Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethanesulfanylamides as Easy-to-Handle Equivalents of the Trifluoromethanesulfanyl Cation (CF3S+): Reaction with Alkenes and Alkynes

(2009) Aurélien Ferry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Microwave-assisted aliphatic fluorine–chlorine exchange using triethylamine trihydrofluoride (TREAT-HF)

(2009) Jennifer M. Kremsner et al.   TETRAHEDRON LETTERS

Recent Advances in Efficient and Selective Synthesis of Di-, Tri-, and Tetrasubstituted Alkenes via Pd-Catalyzed Alkenylation−Carbonyl Olefination Synergy

(2008) Ei-ichi Negishi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS