Journal
ORGANOMETALLICS
Volume 30, Issue 6, Pages 1291-1294Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200028m
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Funding
- Physical Sciences Research Council [MA, EP/E03117X/1]
- Engineering and Physical Sciences Research Council [EP/E03117X/1] Funding Source: researchfish
- EPSRC [EP/E03117X/1] Funding Source: UKRI
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Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)(2)}(2)(THF)(2)] (Ac = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkeries.
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