N-Heterocyclic carbene phosphaketene adducts as precursors to carbene–phosphinidene adducts and a rearranged π-system

N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism

(2016) Zhongshu Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene

(2016) Shenglai Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Singlet (Phosphino)phosphinidenes are Electrophilic

(2016) Max M. Hansmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a Heavier Cyclobutadiene Analogue: 2,4-Digerma-1,3-diphosphacyclobutadiene

(2016) Yile Wu et al.   ORGANOMETALLICS

A Singlet Phosphinidene Stable at Room Temperature

(2016) Liu Liu et al.   Chem

E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound

(2015) Thomas P. Robinson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes

(2015) Kuntal Pal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Probing the Diastereoselectivity of Staudinger Reactions Catalyzed by N-Heterocyclic Carbenes

(2015) Morgan Hans et al.   CHEMISTRY-A EUROPEAN JOURNAL

A stable phosphanyl phosphaketene and its reactivity

(2015) Zhongshu Li et al.   DALTON TRANSACTIONS

Frustrated N-heterocyclic carbene–silylium ion Lewis pairs

(2015) Miguel F. Silva Valverde et al.   DALTON TRANSACTIONS

Ambient-Temperature Synthesis of 2-Phosphathioethynolate, PCS-, and the Ligand Properties of ECX-(E = N, P; X = O, S)

(2015) Andrew R. Jupp et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cyclo-oligomerization of isocyanates with Na(PH2) or Na(OCP) as “P−” anion sources

(2015) Dominikus Heift et al.   Chemical Science

Sodium Phosphaethynolate as a Building Block for Heterocycles

(2014) Xiaodan Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene-Phosphinidyne Transition Metal Complexes

(2014) Adinarayana Doddi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Triggered Reversible Interconversion of a Monocyclic and a Bicyclic Phosphorus Heterocycle

(2014) Dominikus Heift et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphaketenes as Building Blocks for the Synthesis of Triphospha Heterocycles

(2014) Dominikus Heift et al.   CHEMISTRY-A EUROPEAN JOURNAL

Is the phosphaethynolate anion, (OCP)−, an ambident nucleophile? A spectroscopic and computational study

(2014) Dominikus Heift et al.   DALTON TRANSACTIONS

N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field

(2014) Yuzhong Wang et al.   INORGANIC CHEMISTRY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Structures and Ambident Reactivities of Azolium Enolates

(2013) Biplab Maji et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Evidence for the Attack of a Free N-Heterocyclic Carbene at a Carbonyl Ligand: A Zwitterionic Osmium Carbonyl Cluster

(2013) Yu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The 2-Phosphaethynolate Anion: A Convenient Synthesis and [2+2] Cycloaddition Chemistry

(2013) Andrew R. Jupp et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

31P NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the π-Accepting Properties of Carbenes

(2013) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coulomb repulsion versus cycloaddition: formation of anionic four-membered rings from sodium phosphaethynolate, Na(OCP)

(2013) Dominikus Heift et al.   DALTON TRANSACTIONS

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Sodium phosphaethynolate, Na(OCP), as a “P” transfer reagent for the synthesis of N-heterocyclic carbene supported P3 and PAsP radicals

(2013) Aaron M. Tondreau et al.   Chemical Science

Synthesis and Characterization of Terminal [Re(XCO)(CO)2(triphos)] (X=N, P): Isocyanate versus Phosphaethynolate Complexes

(2012) Simone Alidori et al.   CHEMISTRY-A EUROPEAN JOURNAL

Covalent Capture of Nitrous Oxide by N-Heterocyclic Carbenes

(2011) Alexander G. Tskhovrebov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amine-Linked N-Heterocyclic Carbenes: The Importance of an Pendant Free-Amine Auxiliary in Assisting the Catalytic Reaction

(2011) Chia-Yi Li et al.   Chemistry-An Asian Journal

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

A Systematic Investigation of Factors Influencing the Decarboxylation of Imidazolium Carboxylates

(2009) Bret R. Van Ausdall et al.   JOURNAL OF ORGANIC CHEMISTRY