Bench-stable frustrated Lewis pair chemistry: fluoroborate salts as precatalysts for the C–H borylation of heteroarenes

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular B/N frustrated Lewis pairs and the hydrogenation of carbon dioxide

(2015) Marc-André Courtemanche et al.   CHEMICAL COMMUNICATIONS

Nickel-catalyzed borylation of arenes and indoles via C–H bond cleavage

(2015) Takayuki Furukawa et al.   CHEMICAL COMMUNICATIONS

Naphthylaminoborane: from structural switches to frustrated Lewis pair reactivity

(2015) Daniel Pla et al.   DALTON TRANSACTIONS

A General Method for Interconversion of Boronic Acid Protecting Groups: Trifluoroborates as Common Intermediates

(2015) Quentin I. Churches et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron-Catalyzed C–H Borylation of Arenes

(2015) Thomas Dombray et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dosage delivery of sensitive reagents enables glove-box-free synthesis

(2015) Aaron C. Sather et al.   NATURE

A leap ahead for activating C-H bonds

(2015) S. K. Bose et al.   SCIENCE

Metal-free catalytic C-H bond activation and borylation of heteroarenes

(2015) M.-A. Legare et al.   SCIENCE

Pinacolatoboron fluoride (pinBF) is an efficient fluoride transfer agent for diastereoselective synthesis of benzylic fluorides

(2015) Alexander J. Cresswell et al.   TETRAHEDRON LETTERS

Hydroboration of Carbon Dioxide Using Ambiphilic Phosphine–Borane Catalysts: On the Role of the Formaldehyde Adduct

(2015) Richard Declercq et al.   ACS Catalysis

Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones

(2015) Ádám Gyömöre et al.   ACS Catalysis

Facile Protocol for Water-Tolerant “Frustrated Lewis Pair”-Catalyzed Hydrogenation

(2015) Daniel J. Scott et al.   ACS Catalysis

Frustrated Lewis Pairs: From Concept to Catalysis

(2014) Douglas W. Stephan   ACCOUNTS OF CHEMICAL RESEARCH

Intramolecular Frustrated Lewis Pair with the Smallest Boryl Site: Reversible H2Addition and Kinetic Analysis

(2014) Konstantin Chernichenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine catalyzed reduction of CO2 with boranes

(2014) Tongen Wang et al.   CHEMICAL COMMUNICATIONS

Metal-Free Reduction of CO2with Hydroboranes: Two Efficient Pathways at Play for the Reduction of CO2to Methanol

(2014) Christophe Das Neves Gomes et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene-9-BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO2Reduction

(2014) Tongen Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reducing CO2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism of Phosphine–Borane-Mediated Hydroboration of CO2

(2014) Marc-André Courtemanche et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed C–H Borylation

(2014) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

(2014) Adrian Y. Houghton et al.   Nature Chemistry

Selection of boron reagents for Suzuki–Miyaura coupling

(2013) Alastair J. J. Lennox et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Active Phosphine–Borane Organocatalyst for the Reduction of CO2 to Methanol Using Hydroboranes

(2013) Marc-André Courtemanche et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base Metal Catalysts for Photochemical C–H Borylation That Utilize Metal–Metal Cooperativity

(2013) Thomas J. Mazzacano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes

(2013) Konstantin Chernichenko et al.   Nature Chemistry

A Tris(triphenylphosphine)aluminum Ambiphilic Precatalyst for the Reduction of Carbon Dioxide with Catecholborane

(2013) Marc-André Courtemanche et al.   ORGANOMETALLICS

Mechanistic Studies into Amine-Mediated Electrophilic Arene Borylation and Its Application in MIDA Boronate Synthesis

(2012) Viktor Bagutski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pair” hydrogenations

(2012) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Iridium-catalyzed C–H borylation of quinolines and unsymmetrical 1,2-disubstituted benzenes: insights into steric and electronic effects on selectivity

(2012) Hazmi Tajuddin et al.   Chemical Science

A Boronium Ion with Exceptional Electrophilicity

(2011) Aleksandrs Prokofjevs et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pinacol Boronates by Direct Arene Borylation with Borenium Cations

(2011) Alessandro Del Grosso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aryl Trifluoroborates in Suzuki-Miyaura Coupling: The Roles of Endogenous Aryl Boronic Acid and Fluoride

(2010) Mike Butters et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

(2010) Britt A. Vanchura et al.   CHEMICAL COMMUNICATIONS

CH Bond Activation/Borylation of Furans and Thiophenes Catalyzed by a Half-Sandwich Iron N-Heterocyclic Carbene Complex

(2010) Tsubasa Hatanaka et al.   Chemistry-An Asian Journal

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Chelate Restrained Boron Cations for Intermolecular Electrophilic Arene Borylation

(2009) Alessandro Del Grosso et al.   ORGANOMETALLICS

Improved method for the conversion of pinacolboronic esters into trifluoroborate salts: facile synthesis of chiral secondary and tertiary trifluoroborates

(2009) Viktor Bagutski et al.   TETRAHEDRON

Metal-Free Catalytic Hydrogenation of Enamines, Imines, and Conjugated Phosphinoalkenylboranes

(2008) Patrick Spies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS