Construction of Chiral 2,3-Allenols through a Copper(I)-Catalyzed Asymmetric Direct Alkynylogous Aldol Reaction

Catalytic Regio- and Enantioselective Proton Migration from Skipped Enynes to Allenes

(2019) Xiao-Feng Wei et al.   Chem

Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct

(2019) Richard Y. Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper Hydride Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes

(2019) Liela Bayeh-Romero et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Asymmetric Induction Reactions using a E,E-Vinylketene Silyl N,O-Acetal and the Wide Range Stereocontrol Strategy for the Synthesis of Polypropionates

(2018) Seijiro Hosokawa   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalytic Formation of Chiral Trisubstituted Allenes and Chiral Furan Derivatives

(2018) Pernille H. Poulsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes

(2018) Erica Y. Tsai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Trisubstituted Allenyl–B(pin) Compounds by Phosphine–Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu–Allenyl Intermediates

(2018) Youming Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent development of vinylogous Mukaiyama aldol reactions

(2018) Seijiro Hosokawa   TETRAHEDRON LETTERS

Enantio- and Diastereoselective Synthesis of Chiral Allenes by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition Reactions

(2018) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of α,β-Unsaturated δ-Lactones through Copper(I)-Catalyzed Direct Vinylogous Aldol Reaction

(2018) Hai-Jun Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent progress on direct catalytic asymmetric vinylogous reactions

(2018) Hui Li et al.   TETRAHEDRON LETTERS

Copper(I)-Catalyzed Enantioselective Addition of Enynes to Ketones

(2017) Xiao-Feng Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Computational Investigation of the Ligand-Controlled Cu-Catalyzed Site-Selective Propargylation and Allenylation of Carbonyl Compounds

(2017) Yike Zou et al.   ORGANIC LETTERS

Recent advances in catalytic asymmetric synthesis of allenes

(2017) Wen-Dao Chu et al.   Catalysis Science & Technology

Highly Diastereo- and Enantioselective Cu-Catalyzed Borylative Coupling of 1,3-Dienes and Aldimines

(2016) Liyin Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Conjugate Additions of (pin)B-Substituted Allylcopper Compounds Generated in situ from Butadiene or Isoprene

(2016) Xiben Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic Kinetic Resolution and Asymmetric Propargyl Claisen Rearrangement for the Synthesis of Chiral Allenes

(2016) Yangbin Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Allenes via Alkynylogous Mukaiyama Aldol Reaction

(2016) Aurélien Tap et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes

(2016) Wen-Dao Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Proton Transfer Mechanism of Organocatalyzed Isomerization of Alkynoates into Allenoates: Enantioselectivity and Reversibility. A DFT Study

(2016) Hongyan Xiao et al.   ACS Catalysis

Diastereoselective and Enantioselective Alleno-aldol Reaction of Allenoates with Isatins to Synthesis of Carbinol Allenoates Catalyzed by Gold

(2016) Gang Wang et al.   ACS Catalysis

Chirality transfer in metal-catalysed intermolecular addition reactions involving allenes

(2016) José Miguel Alonso et al.   Organic Chemistry Frontiers

Direct Synthesis of Chiral Allenoates from the Asymmetric CH Insertion of α-Diazoesters into Terminal Alkynes

(2015) Yu Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cyclization Reactions of Allenes in the Presence of Unsaturated Carbon–Carbon Bonds

(2014) Juntao Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Alkoxyallenes as building blocks for organic synthesis

(2014) Reinhold Zimmer et al.   CHEMICAL SOCIETY REVIEWS

Phosphine catalysis of allenes with electrophiles

(2014) Zhiming Wang et al.   CHEMICAL SOCIETY REVIEWS

Diastereo- and Enantioselective Addition of Anilide-Functionalized Allenoates to N-Acylimines Catalyzed by a Pyridylalanine-Based Peptide

(2014) Curren T. Mbofana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The vinylogous Mukaiyama aldol reaction (VMAR) in natural product synthesis

(2014) Markus Kalesse et al.   NATURAL PRODUCT REPORTS

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In situ Catalytic Generation of Allylcopper Species for Asymmetric Allylation: Toward 1H-Isochromene Skeletons

(2013) Junya Kawai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allenamides: A Powerful and Versatile Building Block in Organic Synthesis

(2013) Ting Lu et al.   CHEMICAL REVIEWS

A Room-Temperature Catalytic Asymmetric Synthesis of Allenes with ECNU-Phos

(2013) Yuli Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Asymmetric β-Hydride Elimination en Route to Chiral Allenes

(2013) Ian T. Crouch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes

(2013) Hui Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

(2013) Takuya Hashimoto et al.   Nature Chemistry

Bimetallic Enantioselective Approach to Axially Chiral Allenes

(2013) Ruizhi Lü et al.   ORGANIC LETTERS

Copper-Catalyst-Controlled Site-Selective Allenylation of Ketones and Aldehydes with Propargyl Boronates

(2013) Keith R. Fandrick et al.   ORGANIC LETTERS

Catalytic enantioselective synthesis of 2-(2-hydroxyethyl)indole scaffolds via consecutive intramolecular amido-cupration of allenes and asymmetric addition of carbonyl compounds

(2013) Prasanna Kumara Chikkade et al.   Chemical Science

Palladium-Catalyzed Efficient Enantioselective Synthesis of Chiral Allenes: Steric and Electronic Effects of Ligands

(2013) Zi Wu et al.   ACS Catalysis

Recent Advances in the Catalytic Syntheses of Allenes: A Critical Assessment

(2013) Robynne K. Neff et al.   ACS Catalysis

Allenes in Molecular Materials

(2012) Pablo Rivera-Fuentes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Decarboxylative Amination: Synthesis of Axially Chiral Allenyl Amines

(2012) Baoqiang Wan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalyzed Isomerization of α-Substituted Alkynoates into Trisubstituted Allenoates by Dynamic Kinetic Resolution

(2012) Tsubasa Inokuma et al.   ChemCatChem

Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates

(2012) Mingyu Yang et al.   ORGANIC LETTERS

Copper-Catalyzed Enantioselective Synthesis of Axially Chiral Allenes

(2012) Hailing Li et al.   ORGANIC LETTERS

Organocatalytic Asymmetric Vinylogous Aldol Reactions

(2012) Vishnumaya Bisai   SYNTHESIS-STUTTGART

Enantioselective Enzymatic Desymmetrization of Prochiral Allenic Diols

(2011) Chicco Manzuna Sapu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Nucleophilic Cyclization of Functionalized Allenes: A Powerful Access to Carbo- and Heterocycles

(2011) Norbert Krause et al.   CHEMICAL REVIEWS

The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress†

(2011) Giovanni Casiraghi et al.   CHEMICAL REVIEWS

Bifunctional Hydrogen-Bond Donors That Bear a Quinazoline or Benzothiadiazine Skeleton for Asymmetric Organocatalysis

(2011) Tsubasa Inokuma et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Organocatalytic Vinylogous Aldol Reaction: Recent Advances

(2011) Sunil V. Pansare et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Allene-Containing Phosphines in Asymmetric Catalysis

(2011) Feng Cai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Computational investigation on the mechanism and stereochemistry of guanidine-catalyzed enantioselective isomerization of 3-alkynoates to allenoates

(2011) Dongfeng Huang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Gold-Catalyzed Intramolecular Oxidative Cross-Coupling of Nonactivated Arenes

(2010) Matthew N. Hopkinson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Identification of Modular Chiral Bisphosphines Effective for Cu(I)-Catalyzed Asymmetric Allylation and Propargylation of Ketones

(2010) Shi-Liang Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Vinylogation to Alkynylogation: Extending the Reactivity of Enolates

(2010) Bo Xu et al.   SYNLETT

Silver(i)-mediated highly enantioselective synthesis of axially chiral allenes under thermal and microwave-assisted conditions

(2009) Vanessa Kar-Yan Lo et al.   CHEMICAL COMMUNICATIONS

The economies of synthesis

(2009) Timothy Newhouse et al.   CHEMICAL SOCIETY REVIEWS

Intramolecular Alkynylogous Mukaiyama Aldol Reaction Starting from Bicyclic Alkanones Tethered to Alkynyl Esters: Formal Total Synthesis of (±)-Hamigeran B

(2009) Laurence Miesch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Chiral Allenoates by Guanidine-Catalyzed Isomerization of 3-Alkynoates

(2009) Hongjun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allenes in Asymmetric Catalysis: Asymmetric Ring Opening ofmeso-Epoxides Catalyzed by Allene-Containing Phosphine Oxides

(2009) Xiaotao Pu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct and Stereospecific Synthesis of Allenes via Reduction of Propargylic Alcohols with Cp2Zr(H)Cl

(2008) Xiaotao Pu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Highly Enantioselective Synthesis of Axially Chiral Allenes

(2008) Vanessa Kar-Yan Lo et al.   ORGANIC LETTERS

Thermodynamically Favored Aldol Reaction of Propargyl or Allenyl Esters: Regioselective Synthesis of Carbinol Allenoates

(2007) Bo Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION