Journal
SYNLETT
Volume -, Issue 10, Pages 1442-1454Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0029-1219840
Keywords
vinylogation; alkynylogation; enolates; aldol reactions; halogenations
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Funding
- National Science Foundation [CHE-0809683]
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Extending reactivity through conjugated multiple carbon-carbon bonds can be a rapid way to expand the scope of synthetic chemistry. In this account, we describe our research on the alkynylogation of enolates. We conducted a systematic investigation on reactions of alkynyl- and allenyl-substituted enolates with various electrophiles. Those reactions led to the convenient synthesis of highly functionalized allenes, alkynes, and 1,3-dienes. Some relevant literature reports are also described.
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