Direct Synthesis of Chiral Allenoates from the Asymmetric CH Insertion of α-Diazoesters into Terminal Alkynes

Recent applications of chiral allenes in axial-to-central chirality transfer reactions

(2015) Robynne K. Neff et al.   TETRAHEDRON

Asymmetric NH Insertion of Secondary and Primary Anilines under the Catalysis of Palladium and Chiral Guanidine Derivatives

(2014) Yin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu(II)–Cu(I) Synergistic Cooperation to Lead the Alkyne C–H Activation

(2014) Ruopeng Bai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Observation of Reduction of Cu(II) to Cu(I) by Terminal Alkynes

(2014) Guanghui Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Advancements in the mechanistic understanding of the copper-catalyzed azide–alkyne cycloaddition

(2013) Regina Berg et al.   Beilstein Journal of Organic Chemistry

Three Carbons for Complexity! Recent Developments of Palladium-Catalyzed Reactions of Allenes

(2013) Tilman Lechel et al.   ChemCatChem

Allenamides: A Powerful and Versatile Building Block in Organic Synthesis

(2013) Ting Lu et al.   CHEMICAL REVIEWS

Axial-to-central chirality transfer in cyclization processes

(2013) Damien Campolo et al.   CHEMICAL SOCIETY REVIEWS

A Room-Temperature Catalytic Asymmetric Synthesis of Allenes with ECNU-Phos

(2013) Yuli Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Asymmetric β-Hydride Elimination en Route to Chiral Allenes

(2013) Ian T. Crouch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Oxyamination of Azlactones: Kinetic Resolution of Oxaziridines and Asymmetric Synthesis of Oxazolin-4-ones

(2013) Shunxi Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes

(2013) Hui Qian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

(2013) Takuya Hashimoto et al.   Nature Chemistry

Recent Advances in the Catalytic Syntheses of Allenes: A Critical Assessment

(2013) Robynne K. Neff et al.   ACS Catalysis

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalyzed Isomerization of α-Substituted Alkynoates into Trisubstituted Allenoates by Dynamic Kinetic Resolution

(2012) Tsubasa Inokuma et al.   ChemCatChem

Platinum complexes of cationic ligands for the aerobic oxidation of “inert” perfluoro-substituted alcohols

(2012) Haviv Ben-David et al.   CHEMICAL COMMUNICATIONS

Highly Enantioselective Cyclopropenation Reaction of 1-Alkynes with α-Alkyl-α-Diazoesters Catalyzed by Dirhodium(II) Carboxylates

(2011) Takayuki Goto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

How easy are the syntheses of allenes?

(2011) Shichao Yu et al.   CHEMICAL COMMUNICATIONS

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

Bifunctional Hydrogen-Bond Donors That Bear a Quinazoline or Benzothiadiazine Skeleton for Asymmetric Organocatalysis

(2011) Tsubasa Inokuma et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Cyclopropenation of Alkynes with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis

(2011) Xin Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Allene-Containing Phosphines in Asymmetric Catalysis

(2011) Feng Cai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Synthesis of 2,4-Disubstituted Allenoates from α-Diazoesters

(2011) Matthew Hassink et al.   ORGANIC LETTERS

Click-alkynylation of N- and P-nucleophiles by oxidative cross-coupling with alkynylcopper reagents: a general synthesis of ynamides and alkynylphosphonates

(2011) Kévin Jouvin et al.   Chemical Science

Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation

(2010) Marion H. Emmert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coupling of N-Tosylhydrazones with Terminal Alkynes Catalyzed by Copper(I): Synthesis of Trisubstituted Allenes

(2010) Qing Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Bisguanidine-Catalyzed Inverse-Electron-Demand Hetero-Diels−Alder Reaction of Chalcones with Azlactones

(2010) Shunxi Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Rh2(S-DOSP)4-Catalyzed Cyclopropenation of Alkynes with Styryldiazoacetates

(2010) John F. Briones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioenriched Synthesis of Cyclopropenes with a Quaternary Stereocenter, Versatile Building Blocks

(2010) Misaki Uehara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Resolution of Racemic 2,3-Allenoates by Organocatalytic Asymmetric 1,3-Dipolar Cycloaddition

(2010) Jie Yu et al.   ORGANIC LETTERS

Bifunctional Guanidine via an Amino Amide Skeleton for Asymmetric Michael Reactions of β-Ketoesters with Nitroolefins: A Concise Synthesis of Bicyclic β-Amino Acids

(2009) Zhipeng Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Chiral Allenoates by Guanidine-Catalyzed Isomerization of 3-Alkynoates

(2009) Hongjun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allenes in Asymmetric Catalysis: Asymmetric Ring Opening ofmeso-Epoxides Catalyzed by Allene-Containing Phosphine Oxides

(2009) Xiaotao Pu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective synthesis of axially chiral allenes

(2009) Masamichi Ogasawara   TETRAHEDRON-ASYMMETRY

Cu-Catalyzed Azide−Alkyne Cycloaddition

(2008) Morten Meldal et al.   CHEMICAL REVIEWS

Synthesis and Complexation Properties of Allenic Bipyridines, a New Class of Axially Chiral Ligands for Transition Metal Catalysis

(2007) Sandra Löhr et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY