1,1,1,4,4,4‐Hexafluorobut‐2‐yne (HFB) as a Versatile Dipolarophile for [3+2] Cycloaddition with 1,3‐Dipoles toward Azoles with Adjacent CF 3 Groups

Ambident polyfluoroalkyl-substituted pyrazoles in the methylation reactions

(2017) Anna E. Ivanova et al.   JOURNAL OF FLUORINE CHEMISTRY

Unified Approach to Pyrazole-Fused Heterocyclic and Carbocyclic Motifs through One-Pot Condensation and Intramolecular Dipolar Cycloaddition Reaction

(2016) Thachapully Suja et al.   SYNTHESIS-STUTTGART

Three-component synthesis of C2F5-substituted pyrazoles from C2F5CH2NH2·HCl, NaNO2and electron-deficient alkynes

(2015) Pavel K Mykhailiuk   Beilstein Journal of Organic Chemistry

Multigram Synthesis of Fluoroalkyl-Substituted Pyrazole-4-carboxylic Acids

(2014) Rustam T. Iminov et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of CF3-Substituted Pyrazolines/Pyrazoles from Electron-Deficient Alkenes/Alkynes and CF3CHN2Generated in situ: Optimized Synthesis of Tris(trifluoromethyl)pyrazole

(2014) Evgeniy Y. Slobodyanyuk et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

1,3-Dipolar Cycloadditions of Ethyl 2-Diazo-3,3,3-trifluoropropanoate to Alkynes and [1,5] Sigmatropic Rearrangements of the Resulting 3H-Pyrazoles: Synthesis of Mono-, Bis- and Tris(trifluoromethyl)-Substituted Pyrazoles

(2014) Daniel Gladow et al.   HELVETICA CHIMICA ACTA

Regioselective One-Step Synthesis of Pyrazoles from Alkynes and N-Tosylhydrazones: [3+2] Dipolar Cycloaddition/[1,5] Sigmatropic Rearrangement Cascade

(2013) M. Carmen Pérez-Aguilar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 4-Fluoromethylsydnones and their Participation in Alkyne Cycloaddition Reactions

(2013) Robert S. Foster et al.   JOURNAL OF ORGANIC CHEMISTRY

Practical and innate carbon–hydrogen functionalization of heterocycles

(2012) Yuta Fujiwara et al.   NATURE

Taming of Fluoroform: Direct Nucleophilic Trifluoromethylation of Si, B, S, and C Centers

(2012) G. K. S. Prakash et al.   SCIENCE

Tosylhydrazones: New Uses for Classic Reagents in Palladium-Catalyzed Cross-Coupling and Metal-Free Reactions

(2011) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of pyrazoles through catalyst-free cycloaddition of diazo compounds to alkynes

(2008) Daniela Vuluga et al.   GREEN CHEMISTRY