Visible‐Light‐Mediated Charge Transfer Enables C−C Bond Formation with Traceless Acceptor Groups

Harnessing Alkylpyridinium Salts as Electrophiles in Deaminative Alkyl–Alkyl Cross-Couplings

(2019) Shane Plunkett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Desulfurative Strategy for the Generation of Alkyl Radicals Enabled by Visible-Light Photoredox Catalysis

(2018) Fei Xue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Promoted Dearomative Fluoroalkylation of β-Naphthols through Intermolecular Charge Transfer

(2018) Quanping Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Functionalization of Aminoheterocycles by a Pyrylium Salt

(2018) Daniel Moser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoredox Catalysis for Building C–C Bonds from C(sp2)–H Bonds

(2018) Chang-Sheng Wang et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Decarboxylative Heck-Type Coupling of Activated Aliphatic Carboxylic Acids Enabled by Visible Light

(2018) Maximilian Koy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transforming Benzylic Amines into Diarylmethanes: Cross-Couplings of Benzylic Pyridinium Salts via C–N Bond Activation

(2018) Jennie Liao et al.   ORGANIC LETTERS

Visible-Light-Promoted Cascade Alkene Trifluoromethylation and Dearomatization of Indole Derivatives via Intermolecular Charge Transfer

(2018) Min Zhu et al.   ORGANIC LETTERS

Modular radical cross-coupling with sulfones enables access to sp3-rich (fluoro)alkylated scaffolds

(2018) Rohan R. Merchant et al.   SCIENCE

Catalytic enantioselective Minisci-type addition to heteroarenes

(2018) Rupert S. J. Proctor et al.   SCIENCE

Vinylation of Benzylic Amines via C–N Bond Functionalization of Benzylic Pyridinium Salts

(2018) Mary Watson et al.   SYNTHESIS-STUTTGART

Lewis Base Promoted Selective C-N Borylation of Alkyl Amines

(2018) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoinduced Deaminative Borylation of Alkylamines

(2018) Jingjing Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective radical conjugate additions driven by a photoactive intramolecular iminium-ion-based EDA complex

(2018) Zhong-Yan Cao et al.   Nature Communications

Bioinspired Radical Stetter Reaction: Radical Umpolung Enabled by Ion-Pair Photocatalysis

(2018) Tobias Morack et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deaminative Borylation of Aliphatic Amines Enabled by Visible Light Excitation of an Electron Donor-Acceptor Complex

(2018) Frederik Sandfort et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkyl Sulfinates: Radical Precursors Enabling Drug Discovery

(2018) Joel M. Smith et al.   JOURNAL OF MEDICINAL CHEMISTRY

Redox-Activated Amines in C(sp3)–C(sp) and C(sp3)–C(sp2) Bond Formation Enabled by Metal-Free Photoredox Catalysis

(2018) Michał Ociepa et al.   ACS Catalysis

Visible-Light-Mediated Deaminative Three-Component Dicarbofunctionalization of Styrenes with Benzylic Radicals

(2018) Felix J. R. Klauck et al.   ACS Catalysis

Intermolecular Radical Addition to Carbonyls Enabled by Visible Light Photoredox Initiated Hole Catalysis

(2017) Lena Pitzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C–N Bond Activation

(2017) Corey H. Basch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative alkenylation

(2017) Jacob T. Edwards et al.   NATURE

Synthetic Applications of Proton-Coupled Electron Transfer

(2016) Emily C. Gentry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Carbon–Carbon Bond Forming Reactions via Photogenerated Intermediates

(2016) Davide Ravelli et al.   CHEMICAL REVIEWS

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism of the Stereoselective α-Alkylation of Aldehydes Driven by the Photochemical Activity of Enamines

(2016) Ana Bahamonde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides

(2016) Kierra M. M. Huihui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Building Congested Ketone: Substituted Hantzsch Ester and Nitrile as Alkylation Reagents in Photoredox Catalysis

(2016) Wenxin Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes Enabled by an Electron-Donor–Acceptor Complex of Togni’s Reagent with a Tertiary Amine

(2016) Yuanzheng Cheng et al.   ORGANIC LETTERS

A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents

(2016) T. Qin et al.   SCIENCE

Organic Synthesis Enabled by Light-Irradiation of EDA Complexes: Theoretical Background and Synthetic Applications

(2016) Carolina G. S. Lima et al.   ACS Catalysis

1,4-Dihydropyridines as Alkyl Radical Precursors: Introducing the Aldehyde Feedstock to Nickel/Photoredox Dual Catalysis

(2016) Álvaro Gutiérrez-Bonet et al.   ACS Catalysis

Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives

(2015) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Aromatic CH Trifluoromethylation via an Electron-Donor-Acceptor Complex

(2015) Yuanzheng Cheng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photo-organocatalytic Enantioselective Perfluoroalkylation of β-Ketoesters

(2015) Łukasz Woźniak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohols as alkylating agents in heteroarene C–H functionalization

(2015) Jian Jin et al.   NATURE

X-Ray Characterization of an Electron Donor-Acceptor Complex that Drives the Photochemical Alkylation of Indoles

(2014) Sandeep R. Kandukuri et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Photochemical Aromatic Perfluoroalkylation of α-Cyano Arylacetates

(2014) Manuel Nappi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Free Coupling Reactions

(2014) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore

(2014) Zhiwei Zuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines

(2014) Adam Noble et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The electron is a catalyst

(2014) Armido Studer et al.   Nature Chemistry

Photochemical activity of a key donor–acceptor complex can drive stereoselective catalytic α-alkylation of aldehydes

(2013) Elena Arceo et al.   Nature Chemistry

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Cross-Coupling: A Historical Contextual Perspective to the 2010 Nobel Prize

(2012) Carin C. C. Johansson Seechurn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Proton-Coupled Electron Transfer

(2012) David R. Weinberg et al.   CHEMICAL REVIEWS

Practical and innate carbon–hydrogen functionalization of heterocycles

(2012) Yuta Fujiwara et al.   NATURE

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

(2011) Javier Magano et al.   CHEMICAL REVIEWS

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS