A Desulfurative Strategy for the Generation of Alkyl Radicals Enabled by Visible-Light Photoredox Catalysis

Heck Reaction of Electronically Diverse Tertiary Alkyl Halides

(2018) Daria Kurandina et al.   ORGANIC LETTERS

Photoredox-Catalyzed Decarboxylative Alkylation of Silyl Enol Ethers To Synthesize Functionalized Aryl Alkyl Ketones

(2018) Weiguang Kong et al.   ORGANIC LETTERS

Decarboxylative Giese-Type Reaction of Carboxylic Acids Promoted by Visible Light: A Sustainable and Photoredox-Neutral Protocol

(2017) Nieves P. Ramirez et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Decarboxylative–Decarbonylative Alkylation of α-Oxo Acids with Electrophilic Olefins via Visible-Light Photoredox Catalysis

(2017) Jian-Qiang Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Versatile Construction of 6-Substituted cis-2,8-Dioxabicyclo[3.3.0]octan-3-ones: Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C

(2017) Yuriy Slutskyy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer

(2017) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalyst-Free and Redox-Neutral Innate Trifluoromethylation and Alkylation of Aromatics Enabled by Light

(2017) Peng Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative [1,2]-Brook Rearrangements Exploiting Single-Electron Transfer: Photoredox-Catalyzed Alkylations and Arylations

(2017) Yifan Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis

(2017) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials

(2017) Steven Bloom et al.   Nature Chemistry

Ru/Ni Dual Catalytic Desulfinative Photoredox Csp2–Csp3 Cross-Coupling of Alkyl Sulfinate Salts and Aryl Halides

(2017) Thomas Knauber et al.   ORGANIC LETTERS

Radicals in Action: A Festival of Radical Transformations

(2017)   ORGANIC LETTERS

Direct Conversion of Carboxylic Acids to Alkyl Ketones

(2017) Javad Amani et al.   ORGANIC LETTERS

Visible-Light Photocatalytic Decarboxylative Alkyl Radical Addition Cascade for Synthesis of Benzazepine Derivatives

(2017) Yu Zhao et al.   ORGANIC LETTERS

Decarboxylative Borylation of Aliphatic Esters under Visible-Light Photoredox Conditions

(2017) Dawei Hu et al.   ORGANIC LETTERS

Photoinduced decarboxylative borylation of carboxylic acids

(2017) Alexander Fawcett et al.   SCIENCE

Metal-free C–H alkylation of heteroarenes with alkyltrifluoroborates: a general protocol for 1°, 2° and 3° alkylation

(2017) Jennifer K. Matsui et al.   Chemical Science

Haloselective Cross-Coupling via Ni/Photoredox Dual Catalysis

(2017) Kingson Lin et al.   ACS Catalysis

Aminomethylation of Aryl Halides Using α-Silylamines Enabled by Ni/Photoredox Dual Catalysis

(2017) Camille Remeur et al.   ACS Catalysis

Mild, Redox-Neutral Alkylation of Imines Enabled by an Organic Photocatalyst

(2017) Niki R. Patel et al.   ACS Catalysis

Nickel/Photoredox-Catalyzed Amidation via Alkylsilicates and Isocyanates

(2017) Shuai Zheng et al.   ACS Catalysis

Visible Light-Mediated Direct Decarboxylative C–H Functionalization of Heteroarenes

(2017) R. Aleyda Garza-Sanchez et al.   ACS Catalysis

A Radical Cascade Enabling Collective Syntheses of Natural Products

(2017) Xiaobei Wang et al.   Chem

Visible Light Activation of Boronic Esters Enables Efficient Photoredox C(sp2)-C(sp3) Cross-Couplings in Flow

(2016) Fabio Lima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis

(2016) Jian Rong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative Peptide Macrocyclization through Photoredox Catalysis

(2016) Stefan J. McCarver et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible Light-Promoted Decarboxylative Di- and Trifluoromethylthiolation of Alkyl Carboxylic Acids

(2016) Lisa Candish et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Access to Alkyl Bromides, Chlorides and Iodides via Visible Light-Promoted Decarboxylative Halogenation

(2016) Lisa Candish et al.   CHEMISTRY-A EUROPEAN JOURNAL

Visible-Light-Mediated Alkenylation, Allylation, and Cyanation of Potassium Alkyltrifluoroborates with Organic Photoredox Catalysts

(2016) Drew R. Heitz et al.   JOURNAL OF ORGANIC CHEMISTRY

Photoredox Catalysis in Organic Chemistry

(2016) Megan H. Shaw et al.   JOURNAL OF ORGANIC CHEMISTRY

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling

(2016) Patricia Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis

(2016) Zhiwei Zuo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic, Enantioselective Addition of Alkyl Radicals to Alkenes via Visible-Light-Activated Photoredox Catalysis with a Chiral Rhodium Complex

(2016) Haohua Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3–sp2 Cross-Coupling of Oxalates with Aryl Halides

(2016) Xiaheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radicals: Reactive Intermediates with Translational Potential

(2016) Ming Yan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metallaphotoredox-catalysed sp3–sp3 cross-coupling of carboxylic acids with alkyl halides

(2016) Craig P. Johnston et al.   NATURE

Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis

(2016) Rahman Karimi-Nami et al.   ORGANIC LETTERS

Engaging Alkenyl Halides with Alkylsilicates via Photoredox Dual Catalysis

(2016) Niki R. Patel et al.   ORGANIC LETTERS

Direct alkylation of heteroarenes with unactivated bromoalkanes using photoredox gold catalysis

(2016) T. McCallum et al.   Chemical Science

Photoredox-mediated Minisci C–H alkylation of N-heteroarenes using boronic acids and hypervalent iodine

(2016) Guo-Xing Li et al.   Chemical Science

Photoredox/Brønsted Acid Co-Catalysis Enabling Decarboxylative Coupling of Amino Acid and Peptide Redox-Active Esters with N-Heteroarenes

(2016) Wan-Min Cheng et al.   ACS Catalysis

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis

(2015) Mirna El Khatib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silicates as Latent Alkyl Radical Precursors: Visible-Light Photocatalytic Oxidation of Hypervalent Bis-Catecholato Silicon Compounds

(2015) Vincent Corcé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis of Radical Reactions: A Radical Chemistry Perspective

(2015) Armido Studer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Cu-catalyzed Atom Transfer Radical Addition Reactions of Fluoroalkylsulfonyl Chlorides with Electron-deficient Alkenes Induced by Visible Light

(2015) Xiao-Jun Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylchlorosulfonylation of Alkenes: Evidence for an Inner-Sphere Mechanism by a Copper Phenanthroline Photoredox Catalyst

(2015) Dattatraya B. Bagal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis

(2015) Gregory L. Lackner et al.   JOURNAL OF ORGANIC CHEMISTRY

Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis

(2015) Gerald Pratsch et al.   JOURNAL OF ORGANIC CHEMISTRY

Constructing Quaternary Stereogenic Centers Using Tertiary Organocuprates and Tertiary Radicals. Total Synthesis of trans-Clerodane Natural Products

(2015) Daniel S. Müller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides

(2015) Adam Noble et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrodecarboxylation of Carboxylic and Malonic Acid Derivatives via Organic Photoredox Catalysis: Substrate Scope and Mechanistic Insight

(2015) Jeremy D. Griffin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis

(2015) Sandrine Ventre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling

(2015) Christopher C. Nawrat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling

(2015) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Free Photoredox/Nickel Dual-Catalytic Cross-Coupling of Ammonium Alkylsilicates

(2015) Matthieu Jouffroy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis

(2015) Yanjie Li et al.   Organic Chemistry Frontiers

Thiyl Radicals in Organic Synthesis

(2014) Fabrice Dénès et al.   CHEMICAL REVIEWS

Vicinal Difunctionalization of Alkenes: Chlorotrifluoromethylation with CF3SO2Cl by Photoredox Catalysis

(2014) Se Hwan Oh et al.   ORGANIC LETTERS

Radical Migration–Addition of N-tert-Butanesulfinyl Imines with Organozinc Reagents

(2013) Wei Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Hydrotrifluoromethylation of Unactivated Alkenes

(2013) Satoshi Mizuta et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis

(2013) Yusuke Yasu et al.   ORGANIC LETTERS

Catalytic hydrotrifluoromethylation of styrenes and unactivated aliphatic alkenes via an organic photoredox system

(2013) Dale J. Wilger et al.   Chemical Science

Visible-Light Photoredox Catalysis

(2012) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of CC Bonds Mediated by Photoredox Catalysts

(2012) Yusuke Yasu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylation of arenes and heteroarenes by means of photoredox catalysis

(2011) David A. Nagib et al.   NATURE

Thiol-Ene Click Chemistry

(2010) Charles E. Hoyle et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light photoredox catalysis: applications in organic synthesis

(2010) Jagan M. R. Narayanam et al.   CHEMICAL SOCIETY REVIEWS