Making the Silylation of Alcohols Chiral: Asymmetric Protection of Hydroxy Groups

Kinetic Resolution of α-Hydroxy-Substituted Oxime Ethers by Enantioselective Cu−H-Catalyzed Si−O Coupling

(2018) Xichang Dong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Kinetic Resolution of Tertiary Propargylic Alcohols by Enantioselective Cu−H-Catalyzed Si−O Coupling

(2018) Jan Seliger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylative Kinetic Resolution of Racemic 1-Indanol Derivatives Catalyzed by Chiral Guanidine

(2017) Shuhei Yoshimatsu et al.   JOURNAL OF ORGANIC CHEMISTRY

Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes

(2017) Xichang Dong et al.   Nature Communications

Sodium Hydroxide Catalyzed Dehydrocoupling of Alcohols with Hydrosilanes

(2016) Anton A. Toutov et al.   ORGANIC LETTERS

Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life

(2016) S. B. Jennifer Kan et al.   SCIENCE

Catalytic Silylations of Alcohols: Turning Simple Protecting-Group Strategies into Powerful Enantioselective Synthetic Methods

(2015) Li-Wen Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polystyrene-Supported Triphenylsilyl Chloride for the Silylation-Based Kinetic Resolution of Secondary Alcohols

(2015) Ravish K. Akhani et al.   ChemCatChem

Diastereoselective and Enantioselective Silylation of 2-Arylcyclohexanols

(2015) Li Wang et al.   ORGANIC LETTERS

Brønsted Acid Catalyzed Asymmetric Silylation of Alcohols

(2015) Benjamin List et al.   SYNLETT

Parts-per-million level loading organocatalysed enantioselective silylation of alcohols

(2015) Sang Yeon Park et al.   Nature Communications

Linear Free-Energy Relationship and Rate Study on a Silylation-Based Kinetic Resolution: Mechanistic Insights

(2014) Ravish K. Akhani et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-catalysed selective hydroamination reactions of alkynes

(2014) Shi-Liang Shi et al.   Nature Chemistry

N-Heterocyclic Carbene Organocatalysts for Dehydrogenative Coupling of Silanes and Hydroxyl Compounds

(2013) Dongjing Gao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Resolution of Terminal 1,2-Diols via Silyl Transfer

(2013) Xixi Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective silyl protection of alcohols promoted by a combination of chiral and achiral Lewis basic catalysts

(2013) Nathan Manville et al.   Nature Chemistry

Silylation-Based Kinetic Resolution of α-Hydroxy Lactones and Lactams

(2013) Robert W. Clark et al.   ORGANIC LETTERS

Monophasic Catalytic System for the Selective Semireduction of Alkynes

(2013) Aaron M Whittaker et al.   ORGANIC LETTERS

Copper-Catalyzed Highly Selective Semihydrogenation of Non-Polar Carbon-Carbon Multiple Bonds using a Silane and an Alcohol

(2012) Kazuhiko Semba et al.   ADVANCED SYNTHESIS & CATALYSIS

The efficient desymmetrization of glycerol using scaffolding catalysis

(2012) Zachary X. Giustra et al.   CHEMICAL COMMUNICATIONS

Site-Selective Catalysis: Toward a Regiodivergent Resolution of 1,2-Diols

(2012) Amanda D. Worthy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scaffolding Catalysts: Highly Enantioselective Desymmetrization Reactions

(2011) Xixi Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylation-Based Kinetic Resolution of Monofunctional Secondary Alcohols

(2011) Cody I. Sheppard et al.   ORGANIC LETTERS

Regiodivergent Reactions through Catalytic Enantioselective Silylation of Chiral Diols. Synthesis of Sapinofuranone A

(2011) Jason M. Rodrigo et al.   ORGANIC LETTERS

A Highly Selective Ferrocene-Based Planar Chiral PIP (Fc-PIP) Acyl Transfer Catalyst for the Kinetic Resolution of Alcohols

(2010) Bin Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Si–O coupling of alcohols

(2010) Andreas Weickgenannt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols

(2009) Andreas Weickgenannt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Potassiumtert-Butoxide-Catalyzed Dehydrogenative SiO Coupling: Reactivity Pattern and Mechanism of an Underappreciated Alcohol Protection

(2009) Andreas Weickgenannt et al.   Chemistry-An Asian Journal

Facile preparation of CF3-substituted carbinols with an azine donor and subsequent kinetic resolution through stereoselective Si–O coupling

(2009) Anne Steves et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Enantioselective Silylation of Acyclic and Cyclic Triols: Application to Total Syntheses of Cleroindicins D, F, and C

(2008) Zhen You et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Alcohol Silylation by Dehydrogenative Si-O Coupling: Scope, Limitations, and Mechanism of the Cu-H-Catalyzed Non-Enzymatic Kinetic Resolution with Silicon-Stereogenic Silanes

(2008) Sebastian Rendler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetic resolution of donor-functionalised tertiary alcohols by Cu–H-catalysed stereoselective silylation using a strained silicon-stereogenic silane

(2008) Betül Karatas et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Kinetic Resolution and Desymmetrization by Stereoselective Silylation of Alcohols

(2007) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION