Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life

Copper-Catalyzed Insertion into Heteroatom-Hydrogen Bonds with Trifluorodiazoalkanes

(2016) Stephen Hyde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C−H Bonds

(2016) Taegyo Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Identification of Mechanism-Based Inactivation in P450-Catalyzed Cyclopropanation Facilitates Engineering of Improved Enzymes

(2016) Hans Renata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes

(2016) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Industrial research: Drug companies must adopt green chemistry

(2016) John L. Tucker et al.   NATURE

Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

(2015) Andrew DeAngelis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Biological Significance and Applications of Heme c Proteins and Peptides

(2015) Jesse G. Kleingardner et al.   ACCOUNTS OF CHEMICAL RESEARCH

Bimetallic Nanoshells as Platforms for Metallo- and Biometallo-Catalytic Applications

(2015) Camila M. Kisukuri et al.   ChemCatChem

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst

(2015) Anton A. Toutov et al.   NATURE

Intermolecular carbene S–H insertion catalysed by engineered myoglobin-based catalysts

(2015) Vikas Tyagi et al.   Chemical Science

Improved Cyclopropanation Activity of Histidine-Ligated Cytochrome P450 Enables the Enantioselective Formal Synthesis of Levomilnacipran

(2014) Z. Jane Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereoselective and Enantioselective Olefin Cyclopropanation Using Engineered Myoglobin-Based Catalysts

(2014) Melanie Bordeaux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methionine Ligand Lability of Homologous Monoheme Cytochromes c

(2014) Benjamin D. Levin et al.   INORGANIC CHEMISTRY

Enzyme-Controlled Nitrogen-Atom Transfer Enables Regiodivergent C–H Amination

(2014) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes

(2013) Antoine Simonneau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The role of key residues in structure, function, and stability of cytochrome-c

(2013) Sobia Zaidi et al.   CELLULAR AND MOLECULAR LIFE SCIENCES

Synthesis and Characterization of Novel Liquid Crystalline Polystyrene

(2013) Bai Wang et al.   CHEMISTRY LETTERS

Photoinduced Electron Transfer as a Probe for the Folding Behavior of Dimethylsilylene-Spaced Alternating Donor–Acceptor Oligomers and Polymers

(2013) Wei-Chih Liao et al.   MACROMOLECULES

A serine-substituted P450 catalyzes highly efficient carbene transfer to olefins in vivo

(2013) Pedro S Coelho et al.   Nature Chemical Biology

Synthesis, Structural Analysis, and Catalytic Properties of Tetrakis(binaphthyl or octahydrobinaphthyl phosphate) Dirhodium(II,II) Complexes

(2013) Radim Hrdina et al.   ORGANOMETALLICS

Cytochrome P450-catalyzed insertion of carbenoids into N–H bonds

(2013) Z. Jane Wang et al.   Chemical Science

Highly enantioselective intermolecular carbene insertion to C–H and Si–H bonds catalyzed by a chiral iridium(iii) complex of a D4-symmetric Halterman porphyrin ligand

(2012) Jing-Cui Wang et al.   CHEMICAL COMMUNICATIONS

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Synthesis of Phenols via Fluoride-free Oxidation of Arylsilanes and Arylmethoxysilanes

(2012) Elizabeth J. Rayment et al.   JOURNAL OF ORGANIC CHEMISTRY

Engineering the third wave of biocatalysis

(2012) U. T. Bornscheuer et al.   NATURE

Olefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 Enzymes

(2012) P. S. Coelho et al.   SCIENCE

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Reducing Codon Redundancy and Screening Effort of Combinatorial Protein Libraries Created by Saturation Mutagenesis

(2012) Sabrina Kille et al.   ACS Synthetic Biology

Total Synthesis of (−)-Virginiamycin M2: Application of Crotylsilanes Accessed by Enantioselective Rh(II) or Cu(I) Promoted Carbenoid Si–H Insertion

(2011) Jie Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Synthesis of Trisubstituted Aziridines

(2011) Li Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enzyme Promiscuity: A Mechanistic and Evolutionary Perspective

(2010) Olga Khersonsky and Dan S. Tawfik   Annual Review of Biochemistry

Metallopeptides for Asymmetric Dirhodium Catalysis

(2010) Ramya Sambasivan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center

(2010) Yoichi Yasutomi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling Reactions of Aromatic and Heteroaromatic Silanolates with Aromatic and Heteroaromatic Halides

(2009) Scott E. Denmark et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enzymatic assembly of DNA molecules up to several hundred kilobases

(2009) Daniel G Gibson et al.   NATURE METHODS

Organosilicon Biotechnology

(2009) Mark B. Frampton et al.   Silicon

Copper-Catalyzed Highly Enantioselective Carbenoid Insertion into SiH Bonds

(2008) Yong-Zhen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Novel Type of Monoheme Cytochromec: Biochemical and Structural Characterization at 1.23 Å Resolution ofRhodothermus marinusCytochromec†‡

(2008) Meike Stelter et al.   BIOCHEMISTRY

Palladium-Catalyzed Cross-Coupling of α-Diazocarbonyl Compounds with Arylboronic Acids

(2008) Cheng Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY