Highly Site Selective Formal [5+2] and [4+2] Annulations of Isoxazoles with Heterosubstituted Alkynes by Platinum Catalysis: Rapid Access to Functionalized 1,3-Oxazepines and 2,5-Dihydropyridines

Recent Advances in Gold-Catalyzed N- and O-Functionalizations of Alkynes with Nitrones, Nitroso, Nitro and Nitroxy Species

(2016) Deepak B. Huple et al.   ADVANCED SYNTHESIS & CATALYSIS

Gold-Catalyzed Synthesis of Quinolines from Propargyl Silyl Ethers and Anthranils through the Umpolung of a Gold Carbene Carbon

(2016) Hongming Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Au-Catalysed oxidative cyclisation

(2016) Zhitong Zheng et al.   CHEMICAL SOCIETY REVIEWS

Recent advances in enantioselective gold catalysis

(2016) Weiwei Zi et al.   CHEMICAL SOCIETY REVIEWS

Gold carbenes, gold-stabilized carbocations, and cationic intermediates relevant to gold-catalysed enyne cycloaddition

(2016) R. J. Harris et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Ynamide Oxidation Strategy for the Preparation of α-Functionalized Amides

(2016) Fei Pan et al.   ACS Catalysis

[3,3]-Sigmatropic Rearrangement/Allylboration/Cyclization Sequence: Enantioenriched Seven-Membered-Ring Carbamates and Ring Contraction to Pyrrolidines

(2015) Aurélie Macé et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-Catalyzed Alkyne Oxidation/CH Functionalization: Highly Site-Selective Synthesis of Versatile Isoquinolones and β-Carbolines

(2015) Long Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed CH Annulation of Anthranils with Alkynes: A Facile, Flexible, and Atom-Economical Synthesis of Unprotected 7-Acylindoles

(2015) Hongming Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Jadomycins, put a bigger ring in it: isolation of seven- to ten-membered ring analogues

(2015) Camilo F. Martinez-Farina et al.   CHEMICAL COMMUNICATIONS

Gold(I)-Catalyzed Activation of Alkynes for the Construction of Molecular Complexity

(2015) Ruth Dorel et al.   CHEMICAL REVIEWS

Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox

(2015) Deyun Qian et al.   CHEMICAL SOCIETY REVIEWS

Gold Carbene or Carbenoid: Is There a Difference?

(2015) Yahui Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Atom-Economic Synthesis of Fully Substituted 2-Aminopyrroles via Gold-Catalyzed Formal [3+2] Cycloaddition between Ynamides and Isoxazoles

(2015) Xin-Yu Xiao et al.   Chemistry-An Asian Journal

Generation of α-Imino Gold Carbenes through Gold-Catalyzed Intermolecular Reaction of Azides with Ynamides

(2015) Chao Shu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Mediated Vinylogous Additions of Enol Nucleophiles into an α,β-Unsaturated Platinum Carbene

(2015) Paul A. Allegretti et al.   ORGANIC LETTERS

Rhodium(II)-Catalyzed Formal [3 + 2] Cycloaddition of N-Sulfonyl-1,2,3-triazoles with Isoxazoles: Entry to Polysubstituted 3-Aminopyrroles

(2015) Xiaoqiang Lei et al.   ORGANIC LETTERS

Atom-economic generation of gold carbenes: gold-catalyzed formal [3+2] cycloaddition between ynamides and isoxazoles

(2015) Ai-Hua Zhou et al.   Chemical Science

Nucleophilic Nitrenoids Through π-Acid Catalysis: Providing a Common Basis for Rapid Access into Diverse Nitrogen Heterocycles

(2015) Paul W. Davies et al.   Asian Journal of Organic Chemistry

Catalytic Access to α-Oxo Gold Carbenes by N–O Bond Oxidants

(2014) Hyun-Suk Yeom et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Non-Diazo Approach to α-Oxo Gold Carbenes via Gold-Catalyzed Alkyne Oxidation

(2014) Liming Zhang   ACCOUNTS OF CHEMICAL RESEARCH

Dual Gold Catalysis

(2014) A. Stephen K. Hashmi   ACCOUNTS OF CHEMICAL RESEARCH

Molecular Complexity from Polyunsaturated Substrates: The Gold Catalysis Approach

(2014) Louis Fensterbank et al.   ACCOUNTS OF CHEMICAL RESEARCH

Intramolecular Metal-Free Oxidative Aryl-Aryl Coupling: An Unusual Hypervalent-Iodine-Mediated Rearrangement of 2-SubstitutedN-Phenylbenzamides

(2014) Siyun Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Platinum-Catalyzed Synthesis of Substituted Phenanthrenes from Biphenyl Propargyl Alcohols via a Carbene Intermediate

(2014) Yongseok Kwon et al.   ORGANIC LETTERS

Generation of gold carbenes in water: efficient intermolecular trapping of the α-oxo gold carbenoids by indoles and anilines

(2014) Long Li et al.   Chemical Science

Synthesis of novel [3,1]-benzothiazepine and [3,1]-benzoxazepine derivatives with antitumoral activity

(2014) Walter R. Martínez et al.   RSC Advances

Ynamides in Ring Forming Transformations

(2013) Xiao-Na Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Gold-Catalyzed Rearrangements and Beyond

(2013) Carla Obradors et al.   ACCOUNTS OF CHEMICAL RESEARCH

From Understanding to Prediction: Gold- and Platinum-Based π-Acid Catalysis for Target Oriented Synthesis

(2013) Alois Fürstner   ACCOUNTS OF CHEMICAL RESEARCH

Development of Catalysts and Ligands for Enantioselective Gold Catalysis

(2013) Yi-Ming Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nitrones as Trapping Reagents of α,β-Unsaturated Carbene Intermediates - [1,2]Oxazino[5,4-b]indoles by a Platinum- Catalyzed Intermolecular [3+3] Cycloaddition

(2013) Weibo Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium- and Platinum-Catalyzed [4+3] Cycloaddition with Concomitant Indole Annulation: Synthesis of Cyclohepta[b]indoles

(2013) Dongxu Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–C bond migration in the cycloisomerization of oxygen-tethered 1,6-enynes

(2013) Susan M. Stevenson et al.   CHEMICAL COMMUNICATIONS

Intriguing mechanistic labyrinths in gold(i) catalysis

(2013) Carla Obradors et al.   CHEMICAL COMMUNICATIONS

Vicinal Bisheterocyclizations of Alkynes via Nucleophilic Interception of a Catalytic Platinum Carbene

(2013) Paul A. Allegretti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiocontrolled 1,2-migration in cyclization of 1-(indol-2-yl)-3-alkyn-1-ols: (Ph3P)Au+vs. PtCl4

(2013) Youai Qiu et al.   Organic Chemistry Frontiers

Gold(i) and platinum(ii) switch: a post-Ugi intramolecular hydroarylation to pyrrolopyridinones and pyrroloazepinones

(2012) Sachin G. Modha et al.   CHEMICAL COMMUNICATIONS

Platinum-catalyzed cyclizations viacarbene intermediates: syntheses of complementary positional isomers of isoxazoles

(2012) Paul A. Allegretti et al.   Chemical Science

Gold α-Oxo Carbenoids in Catalysis: Catalytic Oxygen-Atom Transfer to Alkynes

(2011) Jian Xiao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unexpected C–C bond cleavage of epoxide motif: Rhodium(i)-catalyzed tandem heterocyclization/[4+1] cycloaddition of 1-(1-alkynyl)oxiranyl ketones

(2011) Tao Wang et al.   CHEMICAL COMMUNICATIONS

Ni(ClO4)2-catalysed regio- and diastereoselective [3+2] cycloaddition of indoles and aryl oxiranyl-dicarboxylates/diketones: a facile access to furo[3,4-b]indoles

(2011) Jieming Zhang et al.   CHEMICAL COMMUNICATIONS

Identification of Novel Malarial Cysteine Protease Inhibitors Using Structure-Based Virtual Screening of a Focused Cysteine Protease Inhibitor Library

(2011) Falgun Shah et al.   Journal of Chemical Information and Modeling

Lewis Acid Catalyzed Carbon−Carbon Bond Cleavage of Aryl Oxiranyl Diketones: Synthesis ofcis-2,5-Disubstituted 1,3-Dioxolanes

(2011) Zuliang Chen et al.   ORGANIC LETTERS

Generation of α,β-Unsaturated Platinum Carbenes from Homopropargylic Alcohols: Rearrangements to Polysubstituted Furans

(2011) Paul A. Allegretti et al.   ORGANIC LETTERS

Identification of Metabotropic Glutamate Receptor Subtype 5 Potentiators Using Virtual High-Throughput Screening

(2010) Ralf Mueller et al.   ACS Chemical Neuroscience

Ynamides: Versatile Tools in Organic Synthesis

(2010) Gwilherm Evano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ynamides: A Modern Functional Group for the New Millennium

(2010) Kyle A. DeKorver et al.   CHEMICAL REVIEWS

Chemoselective CC Bond Cleavage of Epoxide Motifs: Gold(I)-Catalyzed Diastereoselective [4+3] Cycloadditions of 1-(1-Alkynyl)oxiranyl Ketones and Nitrones

(2010) Tao Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Platinum(II)-Catalyzed Generation and [3+2] Cycloaddition Reaction of α,β-Unsaturated Carbene Complex Intermediates for the Preparation of Polycyclic Compounds

(2010) Kodai Saito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbocyclisation of alkynes with external nucleophiles catalysed by gold, platinum and other electrophilic metals

(2009) Shariar Md. Abu Sohel et al.   CHEMICAL SOCIETY REVIEWS

Gold and platinum catalysis—a convenient tool for generating molecular complexity

(2009) Alois Fürstner   CHEMICAL SOCIETY REVIEWS

Efficient Generation of Highly Functionalized Fused Oxazepine Frameworks Based on a CAN-Catalyzed Four-Component Tetrahydropyridine Synthesis/Ring-Closing Metathesis Sequence

(2009) Vellaisamy Sridharan et al.   JOURNAL OF ORGANIC CHEMISTRY

Platinum-Catalyzed Dehydroalkoxylation−Cyclization Cascade via N−O Bond Cleavage

(2009) Itaru Nakamura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cycloisomerization of 1,n-Enynes: Challenging Metal-Catalyzed Rearrangements and Mechanistic Insights

(2008) Véronique Michelet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

5-(4-Chlorophenyl)-5,6-dihydro-1,3-oxazepin-7(4H)-one derivatives as lipophilic cyclic analogues of baclofen: Design, synthesis, and neuropharmacological evaluation

(2008) Atef A. Abdel-Hafez et al.   BIOORGANIC & MEDICINAL CHEMISTRY

Platinum- and Gold-Catalyzed Hydrative Carbocyclization of Oxo Diynes for One-Pot Synthesis of Benzopyrones and Bicyclic Spiro Ketones

(2008) Arindam Das et al.   ORGANIC LETTERS