Rhodium-Catalyzed Geminal Oxyfluorination and Oxytrifluoro-Methylation of Diazocarbonyl Compounds

Cyclic Hypervalent Iodine Reagents for Atom-Transfer Reactions: Beyond Trifluoromethylation

(2016) Yifan Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrophilic trifluoromethylation of carbonyl compounds and their nitrogen derivatives under copper catalysis

(2016) Alexis Prieto et al.   CHEMICAL COMMUNICATIONS

Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas

(2016) Yu Zhou et al.   CHEMICAL REVIEWS

18F-Labeling of Arenes and Heteroarenes for Applications in Positron Emission Tomography

(2016) Sean Preshlock et al.   CHEMICAL REVIEWS

Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds with Hypervalent Iodine Reagents

(2016) Durga Prasad Hari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis

(2016) Christophe Werlé et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aminofluorination: transition-metal-free N–F bond insertion into diazocarbonyl compounds

(2016) Gui Chen et al.   Chemical Science

Rh-Catalyzed Intermolecular Reactions of α-Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β-Hydride Migration

(2015) Andrew DeAngelis et al.   ACCOUNTS OF CHEMICAL RESEARCH

Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes

(2015) Wei Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Trifluoromethylazidation of Alkynes: Efficient Access to CF3-Substituted Azirines and Aziridines

(2015) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent

(2015) Weiming Yuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intramolecular Fluorocyclizations of Unsaturated Carboxylic Acids with a Stable Hypervalent Fluoroiodane Reagent

(2015) Gemma C. Geary et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Strategies for Rapid 18F-Radiolabeling of Biomolecules for Radionuclide-Based In Vivo Imaging

(2015) Jun-Liang Zeng et al.   BIOCONJUGATE CHEMISTRY

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Carbon Trifluoromethylation Reactions of Hydrocarbon Derivatives and Heteroarenes

(2015) Concepción Alonso et al.   CHEMICAL REVIEWS

A Fluorination/Aryl Migration/Cyclization Cascade for the Metal-Free Synthesis of Fluoro-Benzoxazepines

(2015) Anna Ulmer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hypervalent Iodine-Mediated Fluorination of Styrene Derivatives: Stoichiometric and Catalytic Transformation to 2,2-Difluoroethylarenes

(2015) Tsugio Kitamura et al.   JOURNAL OF ORGANIC CHEMISTRY

Aminotrifluoromethylation of Olefins via Cyclic Amine Formation: Mechanistic Study and Application to Synthesis of Trifluoromethylated Pyrrolidines

(2015) Shintaro Kawamura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes

(2015) Zheliang Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Stereoselective Carboperfluoroalkylation of Alkynes

(2015) Zhaodong Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors

(2015) Mingyou Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preparation of o-Fluorophenols from Nonaromatic Precursors: Mechanistic Considerations for Adaptation to Fluorine-18 Radiolabeling

(2015) Norio Yasui et al.   ORGANIC LETTERS

Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation

(2015) Zhengbiao He et al.   ORGANIC LETTERS

Effects of B2pin2 and PCy3 on copper-catalyzed trifluoromethylation of substituted alkenes and alkynes with the Togni reagent

(2015) Pär G. Janson et al.   TETRAHEDRON

Palladium-Catalyzed Iodofluorination of Alkenes Using Fluoro-Iodoxole Reagent

(2015) Nadia O. Ilchenko et al.   ACS Catalysis

Asymmetric Fluorocyclizations of Alkenes

(2014) Jamie R. Wolstenhulme et al.   ACCOUNTS OF CHEMICAL RESEARCH

Oxidative Trifluoromethylation and Trifluoromethylthiolation Reactions Using (Trifluoromethyl)trimethylsilane as a Nucleophilic CF3 Source

(2014) Lingling Chu et al.   ACCOUNTS OF CHEMICAL RESEARCH

A General Copper-Mediated Nucleophilic18F Fluorination of Arenes

(2014) Matthew Tredwell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3-Containing Alkyl Azides

(2014) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild Silver-Mediated Geminal Difluorination of Styrenes Using an Air- and Moisture-Stable Fluoroiodane Reagent

(2014) Nadia O. Ilchenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and metal-free oxy- and amino-fluorination for the synthesis of fluorinated heterocycles

(2014) Dixit Parmar et al.   CHEMICAL COMMUNICATIONS

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Intermolecular Radical Carbofluorination of Non-activated Alkenes

(2014) Stephanie Kindt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Divergent Reaction Mechanisms in the Aminofluorination of Alkenes

(2014) Wangqing Kong et al.   CHIMIA

Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent

(2014) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene Catalyzed Highly Chemoselective Intermolecular Crossed Acyloin Condensation of Aromatic Aldehydes with Trifluoroacetaldehyde Ethyl Hemiacetal

(2014) Bandaru T. Ramanjaneyulu et al.   ORGANIC LETTERS

Diversity-Oriented Approach to CF3CHF-, CF3CFBr-, CF3CF2-, (CF3)2CH-, and CF3(SCF3)CH-Substituted Arenes from 1-(Diazo-2,2,2-trifluoroethyl)arenes

(2014) Enrico Emer et al.   ORGANIC LETTERS

Novel Multicomponent Reactions via Trapping of Protic Onium Ylides with Electrophiles

(2013) Xin Guo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Electrophilic Fluorocyclization with Carbon Nucleophiles

(2013) Jamie R. Wolstenhulme et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Three-Component Oxytrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate and Hydroxamic Acid

(2013) Xin-Yi Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Fluoroamination: 1,4-Addition to Conjugated Dienes Using Anionic Phase-Transfer Catalysis

(2013) Hunter P. Shunatona et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Enantioselective Aminofluorination of Alkenes

(2013) Wangqing Kong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes

(2013) Rong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Introduction of Fluorine and Fluorine-Containing Functional Groups

(2013) Theresa Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-mediated C–H trifluoromethylation of quinones

(2013) Nadia O. Ilchenko et al.   CHEMICAL COMMUNICATIONS

Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride

(2013) Gemma C. Geary et al.   CHEMICAL COMMUNICATIONS

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Copper-Mediated Cyanotrifluoromethylation of Styrenes Using the Togni Reagent

(2013) Nadia O. Ilchenko et al.   JOURNAL OF ORGANIC CHEMISTRY

Regio- and Stereoselective Allylic Trifluoromethylation and Fluorination using CuCF3 and CuF Reagents

(2013) Johanna M. Larsson et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation

(2013) Václav Matoušek et al.   JOURNAL OF ORGANIC CHEMISTRY

Dihaloiodoarenes: α,α-Dihalogenation of Phenylacetate Derivatives

(2013) Jason Tao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular generation and rearrangement of oxonium ylides: methodology studies and their application in synthesis

(2013) Graham K. Murphy et al.   TETRAHEDRON

Carbofluorination via a palladium-catalyzed cascade reaction

(2013) Marie-Gabrielle Braun et al.   Chemical Science

Catalytic Cascade Reactions Involving Metal Carbene Migratory Insertion

(2013) Ying Xia et al.   ACS Catalysis

Catalytic Aminohalogenation of Alkenes and Alkynes

(2013) Sherry R. Chemler et al.   ACS Catalysis

Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

(2012) Qing Xiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

1-Fluoro-3,3-dimethyl-1,3-dihydro-1λ3-benzo[d][1,2]iodoxole

(2012) Claude Y. Legault et al.   ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Transition-Metal-Free Trifluoromethylaminoxylation of Alkenes

(2012) Yi Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter

(2012) Mingyou Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trifluoromethylation of Propargylic Halides and Trifluoroacetates Using (Ph3P)3Cu(CF3) Reagent

(2012) Tony S. N. Zhao et al.   ORGANIC LETTERS

Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes

(2012) Pär G. Janson et al.   ORGANIC LETTERS

Oxytrifluoromethylation of multiple bonds using copper catalyst under mild conditions

(2012) Hiromichi Egami et al.   TETRAHEDRON LETTERS

The Long-Arm Effect: Influence of Axially Chiral Phosphoramidite Ligands on the Diastereo- and Enantioselectivity of the Tandem 1,4-Addition/Fluorination

(2011) Lian Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalyzed Enantioselective Fluorocyclizations

(2011) Oscar Lozano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Fluoride-Derived Electrophilic Late-Stage Fluorination Reagent for PET Imaging

(2011) E. Lee et al.   SCIENCE

Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst

(2011) V. Rauniyar et al.   SCIENCE

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Application of donor/acceptor-carbenoids to the synthesis of natural products

(2009) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes

(2009) Tao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS