An N-Heterocyclic Boryloxy Ligand Isoelectronic with N-Heterocyclic Imines: Access to an Acyclic Dioxysilylene and its Heavier Congeners

Precise Activation of Ammonia and Carbon Dioxide by an Iminodisilene

(2018) Daniel Wendel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low-Coordinate Barium Boryloxides: Synthesis and Dehydrocoupling Catalysis for the Production of Borasiloxanes

(2018) Erwann Le Coz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable lead(ii) boroxides

(2018) Adrian-Alexandru Someşan et al.   CHEMICAL COMMUNICATIONS

Diradical Anion of Potassium Aggregate: Reduction of Dimer Boroxide Complex

(2018) Yang Zheng et al.   INORGANIC CHEMISTRY

1,3,2-Diazaborolyl Anions - From Laboratory Curiosities to Versatile Reagents in Synthesis

(2017) Lothar Weber   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

From Si(II) to Si(IV) and Back: Reversible Intramolecular Carbon–Carbon Bond Activation by an Acyclic Iminosilylene

(2017) Daniel Wendel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silicon and Oxygen’s Bond of Affection: An Acyclic Three-Coordinate Silanone and Its Transformation to an Iminosiloxysilylene

(2017) Daniel Wendel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines

(2016) Tatsumi Ochiai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Tin Analogue of Carbenoid: Isolation and Reactivity of a Lithium Bis(imidazolin-2-imino)stannylenoid

(2016) Tatsumi Ochiai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stabilization of a two-coordinate, acyclic diaminosilylene (ADASi): completion of the series of isolable diaminotetrylenes, :E(NR2)2 (E = group 14 element)

(2016) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Applications of N-heterocyclic imines in main group chemistry

(2016) Tatsumi Ochiai et al.   CHEMICAL SOCIETY REVIEWS

Metal-Free Dehydrogenation of Amine-Boranes by Tunable N-Heterocyclic Iminoboranes

(2016) Melanie W. Lui et al.   CHEMISTRY-A EUROPEAN JOURNAL

Metal compounds of boron-substituted alkoxide (‘boroxide’) ligands

(2016) Martyn P. Coles   COORDINATION CHEMISTRY REVIEWS

Advances in the development of complexes that contain a group 13 element chalcogen multiple bond

(2016) Daniel Franz et al.   DALTON TRANSACTIONS

A stable heavier group 14 analogue of vinylidene

(2016) Arnab Rit et al.   Nature Chemistry

Formation of an Imino-Stabilized Cyclic Tin(II) Cation from an Amino(imino)stannylene

(2015) Tatsumi Ochiai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Isolation of a germanium(ii) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand

(2015) Tatsumi Ochiai et al.   DALTON TRANSACTIONS

Contrasting Reactivities of Silicon and Germanium Complexes Supported by an N-Heterocyclic Guanidine Ligand

(2015) Melanie W. Lui et al.   INORGANIC CHEMISTRY

A Dicationic Iminophosphane

(2015) Ying Kai Loh et al.   INORGANIC CHEMISTRY

A monotopic aluminum telluride with an Al=Te double bond stabilized by N-heterocyclic carbenes

(2015) Daniel Franz et al.   Nature Communications

Isolation of a Three-Coordinate Boron Cation with a Boron-Sulfur Double Bond

(2014) Daniel Franz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,2,4,3-Triazaborole-based neutral oxoborane stabilized by a Lewis acid

(2014) Ying Kai Loh et al.   CHEMICAL COMMUNICATIONS

Activation of Elemental Sulfur by Aluminum Dihydride: Isolation of Mono- and Bis(hydrogensulfide) Complexes of Aluminum

(2014) Daniel Franz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition metal complexes supported by highly basic imidazolin-2-iminato and imidazolin-2-imine N-donor ligands

(2013) Xian Wu et al.   COORDINATION CHEMISTRY REVIEWS

Stable Plumbylene Dichalcogenolate Monomers with Large Differences in Their Interligand Angles and the Synthesis and Characterization of a Monothiolato Pb(II) Bromide and Lithium Trithiolato Plumbate

(2013) Brian D. Rekken et al.   INORGANIC CHEMISTRY

Dispersion Forces and Counterintuitive Steric Effects in Main Group Molecules: Heavier Group 14 (Si–Pb) Dichalcogenolate Carbene Analogues with Sub-90° Interligand Bond Angles

(2013) Brian D. Rekken et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene

(2012) Andrey V. Protchenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modern 1,3,2-Diazaborole Chemistry - A Metamorphosis from Electrophilic to Nucleophilic Boron

(2012) Lothar Weber   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a Stable, Acyclic, Two-Coordinate Silylene

(2012) Brian D. Rekken et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Crystalline Singlet Phosphinonitrene: A Nitrogen Atom-Transfer Agent

(2012) F. Dielmann et al.   SCIENCE

Comparison of Anionic and Lewis Acid Stabilized N-Heterocyclic Oxoboranes: Their Facile Synthesis from a Borinic Acid

(2011) Yan Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Bulky guanidinates for the stabilization of low oxidation state metallacycles

(2009) Cameron Jones   COORDINATION CHEMISTRY REVIEWS

Chemistry of Boryllithium: Synthesis, Structure, and Reactivity

(2008) Yasutomo Segawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY