Amine-Borane Dehydropolymerization: Challenges and Opportunities

Generation of High-Molecular-Weight Polymers with Diverse Substituents: An Unusual Metal-Free Synthesis of Poly(aminoborane)s

(2018) Anne Staubitz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Solventless and Metal-Free Synthesis of High-Molecular-Mass Polyaminoboranes from Diisopropylaminoborane and Primary Amines

(2018) Carlos Antonio De Albuquerque Pinheiro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General, Rhodium-Catalyzed, Synthesis of Deuterated Boranes and N -Methyl Polyaminoboranes

(2018) Annie L. Colebatch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts

(2018) Gemma M. Adams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Step-growth titanium-catalysed dehydropolymerisation of amine–boranes

(2018) Titel Jurca et al.   Chemical Science

Catalytic Dehydrogenation of (Di)Amine-Boranes with a Geometrically Constrained Phosphine-Borane Lewis Pair

(2018) Maxime Boudjelel et al.   ACS Catalysis

Dehydropolymerisation of methylamine borane using a dinuclear 1,3-allenediyl bridged zirconocene complex

(2018) M. Trose et al.   DALTON TRANSACTIONS

Recent advances in transition metal catalysed dehydropolymerisation of amine boranes and phosphine boranes

(2018) Delong Han et al.   COORDINATION CHEMISTRY REVIEWS

Fluoroarene Complexes with Small Bite Angle Bisphosphines: Routes to Amine-Borane and Aminoborylene Complexes

(2017) Annie L. Colebatch et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ammonia Borane Dehydrogenation Catalyzed by (κ4-EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids

(2017) Stefano Todisco et al.   INORGANIC CHEMISTRY

Synthesis, Characterization, and Properties of Poly(aryl)phosphinoboranes Formed via Iron-Catalyzed Dehydropolymerization

(2017) Joshua R. Turner et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Polyolefins, a Success Story

(2017) et al.   Polymers

The Simplest Amino-borane H2 B=NH2 Trapped on a Rhodium Dimer: Pre-Catalysts for Amine-Borane Dehydropolymerization

(2016) Amit Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ammonia–Borane and Amine–Borane Dehydrogenation Mediated by Complex Metal Hydrides

(2016) Andrea Rossin et al.   CHEMICAL REVIEWS

Iridium(iii) hydrido complexes for the catalytic dehydrogenation of hydrazine borane

(2016) D. Han et al.   DALTON TRANSACTIONS

Aluminum borate nanowires from the pyrolysis of polyaminoborane precursors

(2016) Van An Du et al.   DALTON TRANSACTIONS

Ammonia Borane Dehydrogenation Promoted by a Pincer-Square-Planar Rhodium(I) Monohydride: A Stepwise Hydrogen Transfer from the Substrate to the Catalyst

(2016) Miguel A. Esteruelas et al.   INORGANIC CHEMISTRY

Catalytic B–N Dehydrogenation Using Frustrated Lewis Pairs: Evidence for a Chain-Growth Coupling Mechanism

(2016) Zhenbo Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrocoupling of phosphine–boranes using the [RhCp*Me(PMe3)(CH2Cl2)][BArF4] precatalyst: stoichiometric and catalytic studies

(2016) Thomas N. Hooper et al.   Chemical Science

Combining Protons and Hydrides by Homogeneous Catalysis for Controlling the Release of Hydrogen from Ammonia–Borane: Present Status and Challenges

(2016) Sourav Bhunya et al.   ACS Catalysis

Toward Benchmarking in Catalysis Science: Best Practices, Challenges, and Opportunities

(2016) Thomas Bligaard et al.   ACS Catalysis

Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH2: A Route to Poly(alkylphosphinoboranes)

(2015) Christian Marquardt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Dehydropolymerization: A Convenient Route to Poly(phosphinoboranes) with Molecular-Weight Control

(2015) André Schäfer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Theoretical Investigation on the Chemistry of Entrapment of the Elusive Aminoborane (H2NBH2) Molecule

(2015) Tanmay Malakar et al.   CHEMISTRY-A EUROPEAN JOURNAL

B-Methylated Amine-Boranes: Substituent Redistribution, Catalytic Dehydrogenation, and Facile Metal-Free Hydrogen Transfer Reactions

(2015) Naomi E. Stubbs et al.   INORGANIC CHEMISTRY

Highly Active Iron Catalyst for Ammonia Borane Dehydrocoupling at Room Temperature

(2015) Arne Glüer et al.   ACS Catalysis

Low-Valent Iron Mono-Diazadiene Compounds: Electronic Structure and Catalytic Application

(2015) Crispin Lichtenberg et al.   ACS Catalysis

Unraveling the Crucial Role of Metal-Free Catalysis in Borazine and Polyborazylene Formation in Transition-Metal-Catalyzed Ammonia–Borane Dehydrogenation

(2015) Sourav Bhunya et al.   ACS Catalysis

Generation of aminoborane monomers RR′NBH2from amine–boronium cations [RR′NH–BH2L]+: metal catalyst-free formation of polyaminoboranes at ambient temperature

(2014) Owen J. Metters et al.   CHEMICAL COMMUNICATIONS

Unfolding the crucial role of a nucleophile in Ziegler–Natta type Ir catalyzed polyaminoborane formation

(2014) Sourav Bhunya et al.   CHEMICAL COMMUNICATIONS

Mechanistic Studies of the Dehydrocoupling and Dehydropolymerization of Amine–Boranes Using a [Rh(Xantphos)]+ Catalyst

(2014) Heather C. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multiple metal-bound oligomers from Ir-catalysed dehydropolymerisation of H3B·NH3 as probed by experiment and computation

(2014) Amit Kumar et al.   Chemical Science

Ammonia-Borane Dehydrogenation Promoted by an Osmium Dihydride Complex: Kinetics and Mechanism

(2014) Miguel A. Esteruelas et al.   ACS Catalysis

Polymer-Derived Boron Nitride: A Review on the Chemistry, Shaping and Ceramic Conversion of Borazine Derivatives

(2014) Samuel Bernard et al.   Materials

The Roles of Dihydrogen Bonds in Amine Borane Chemistry

(2013) Xuenian Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Reaction of a P/Al-Based Frustrated Lewis Pair with Ammonia, Borane, and Amine-Boranes: Adduct Formation and Catalytic Dehydrogenation

(2013) Christian Appelt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polyaminoborane main chain scission using N-heterocyclic carbenes; formation of donor-stabilised monomeric aminoboranes

(2013) Naomi E. Stubbs et al.   CHEMICAL COMMUNICATIONS

Mechanisms of the Thermal and Catalytic Redistributions, Oligomerizations, and Polymerizations of Linear Diborazanes

(2013) Alasdair P. M. Robertson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrocoupling Reactions of Dimethylamine-Borane by Pt(II) Complexes: A New Mechanism Involving Deprotonation of Boronium Cations

(2013) Marta Roselló-Merino et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Mechanism of Borane–Amine Dehydrocoupling with Bifunctional Ruthenium Catalysts

(2013) Alexander N. Marziale et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials

(2013) Erin M. Leitao et al.   Nature Chemistry

Aminoborane σ Complexes: Significance of Hydride Co-ligands in Dynamic Processes and Dehydrogenative Borylene Formation

(2013) David A. Addy et al.   ORGANOMETALLICS

“Spontaneous” Ambient Temperature Dehydrocoupling of Aromatic Amine-Boranes

(2012) Holger Helten et al.   CHEMISTRY-A EUROPEAN JOURNAL

A tert-butyl-substituted amino-borane bound to an iridium fragment: A latent source of free H2BNtBuH

(2012) Heather C. Johnson et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Iron Complex-Catalyzed Ammonia–Borane Dehydrogenation. A Potential Route toward B–N-Containing Polymer Motifs Using Earth-Abundant Metal Catalysts

(2012) R. Tom Baker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Metal-Free Hydrogen Transfer between Amine–Boranes and Aminoboranes

(2012) Erin M. Leitao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic versus stoichiometric dehydrocoupling using main group metals

(2012) Robert J. Less et al.   RSC Advances

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

(2011) Romaeo Dallanegra et al.   CHEMICAL COMMUNICATIONS

Transition metal catalysed ammonia-borane dehydrogenation in ionic liquids

(2011) William R. H. Wright et al.   CHEMICAL COMMUNICATIONS

Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes

(2011) Jongwook Choi et al.   CHEMICAL REVIEWS

Dehydrocoupling Reactions of Secondary and Primary Amine–Borane Adducts Catalyzed by Half-sandwich Carbonyl Complexes, [CpMn(CO)3], [(η6-C6H6)Cr(CO)3], and [CpV(CO)4]

(2011) Taeko Kakizawa et al.   CHEMISTRY LETTERS

[Ir(PCy3)2(H)2(H2BNMe2)]+ as a Latent Source of Aminoborane: Probing the Role of Metal in the Dehydrocoupling of H3B⋅NMe2H and Retrodimerisation of [H2BNMe2]2

(2011) Charlotte J. Stevens et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photoactivated, Iron-Catalyzed Dehydrocoupling of Amine-Borane Adducts: Formation of Boron-Nitrogen Oligomers and Polymers

(2011) James R. Vance et al.   CHEMISTRY-A EUROPEAN JOURNAL

Syntheses and Structural Characterizations of Anionic Borane-Capped Ammonia Borane Oligomers: Evidence for Ammonia Borane H2Release via a Base-Promoted Anionic Dehydropolymerization Mechanism

(2011) William C. Ewing et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catching the First Oligomerization Event in the Catalytic Formation of Polyaminoboranes: H3B·NMeHBH2·NMeH2Bound to Iridium

(2011) Heather C. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Redistribution and Polymerization of Diborazanes: Unexpected Observation of Metal-Free Hydrogen Transfer between Aminoboranes and Amine-Boranes

(2011) Alasdair P. M. Robertson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrogenation of amine–boranes with a frustrated Lewis pair

(2010) Alexander J. M. Miller et al.   CHEMICAL COMMUNICATIONS

Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Thermal Decomposition of Mono- and Bimetallic Magnesium Amidoborane Complexes

(2010) Jan Spielmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Theoretical Investigations on the Formation and Dehydrogenation Reaction Pathways of H(NH2BH2)nH (n= 1−4) Oligomers: Importance of Dihydrogen Interactions

(2010) Jun Li et al.   INORGANIC CHEMISTRY

Catalytic Dehydrocoupling/Dehydrogenation of N-Methylamine-Borane and Ammonia-Borane: Synthesis and Characterization of High Molecular Weight Polyaminoboranes

(2010) Anne Staubitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Bis(σ-BH) Aminoborane Complexes from Dehydrogenation of Amine-Boranes: Trapping of H2BNH2

(2009) Gilles Alcaraz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane

(2009) Martina Käß et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coordination Polymerization of Polar Vinyl Monomers by Single-Site Metal Catalysts

(2009) Eugene Y.-X. Chen   CHEMICAL REVIEWS

Thermochemistry for the Dehydrogenation of Methyl-Substituted Ammonia Borane Compounds

(2009) Daniel J. Grant et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Structures and Aggregation of the Methylamine−Borane Molecules, MenH3−nN·BH3(n= 1−3), Studied by X-ray Diffraction, Gas-Phase Electron Diffraction, and Quantum Chemical Calculations

(2009) Simon Aldridge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrocoupling Reactions of Borane−Secondary and −Primary Amine Adducts Catalyzed by Group-6 Carbonyl Complexes: Formation of Aminoboranes and Borazines

(2009) Yasuro Kawano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Dehydrocoupling of Primary Amine-Borane Adducts: A Route to High Molecular Weight Polyaminoboranes, Boron-Nitrogen Analogues of Polyolefins

(2008) Anne Staubitz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Soluble Boron-Nitrogen High Polymers from Metal-Complex-Catalyzed Amine Borane Dehydrogenation

(2008) Vincent Pons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coordination of aminoborane, NH2BH2, dictates selectivity and extent of H2 release in metal-catalysed ammonia borane dehydrogenation

(2008) Vincent Pons et al.   CHEMICAL COMMUNICATIONS

Iridium-Catalyzed Dehydrogenation of Substituted Amine Boranes: Kinetics, Thermodynamics, and Implications for Hydrogen Storage

(2008) Brandon L. Dietrich et al.   INORGANIC CHEMISTRY