Thioether-directed acetoxylation of C(sp2)–H bonds of arenes by palladium catalysis

Palladium-Catalyzed Cs2CO3-Promoted Arylation of Unactivated C(sp3)–H Bonds by (Diacetoxyiodo)arenes: Shifting the Reactivity of (Diacetoxyiodo)arenes from Acetoxylation to Arylation

(2015) Quan Gou et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism of the Palladium-Catalyzed Arene C–H Acetoxylation: A Comparison of Catalysts and Ligand Effects

(2015) Amanda K. Cook et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Oxidative Alkenylation of 1,3-Dithiane-Protected Arenecarbaldehydes via Regioselective C–H Bond Cleavage

(2015) Yuto Unoh et al.   ORGANIC LETTERS

Synthesis of Axially Chiral Biaryls through Sulfoxide-Directed Asymmetric Mild CH Activation and Dynamic Kinetic Resolution

(2014) Chinmoy Kumar Hazra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C-H Acylation of Arenes Using Thioethers as Directing Groups

(2014) Bo Xu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed ortho-C–H Oxidation of Arylacetic Acid Derivatives: Synthesis of Benzofuranones

(2014) Raja K. Rit et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Ortho-Alkenylation through C–H Bond Cleavage Directed by Sulfoxide Groups

(2014) Kazunori Nobushige et al.   ORGANIC LETTERS

Controllable mono-/di-alkenylation of aryl alkyl thioethers tuned by oxidants via Pd-catalysis

(2014) Xi-Sha Zhang et al.   Organic Chemistry Frontiers

Atropodiastereoselective CH Olefination of Biphenylp-Tolyl Sulfoxides with Acrylates

(2013) Thomas Wesch et al.   ADVANCED SYNTHESIS & CATALYSIS

Controllable Mono-/Dialkenylation of Benzyl Thioethers through Rh-Catalyzed Aryl CH Activation

(2013) Xi-Sha Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

ortho-Acetoxylation of Phosphonic and Phosphoric Monoacids via Pd(II) Catalysis

(2013) Li Yan Chan et al.   JOURNAL OF ORGANIC CHEMISTRY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Palladium-Catalyzed Intramolecular Direct Arylation of 2-Bromo-diaryl Sulfoxides via C–H Bond Activation

(2013) Thomas Wesch et al.   ORGANIC LETTERS

Palladium-Catalyzed β-Acyloxylation of Simple Amide via sp3 C–H Activation

(2013) Lihong Zhou et al.   ORGANIC LETTERS

Palladium(II)-Catalyzed ortho-Olefination of Arenes Applying Sulfoxides as Remote Directing Groups

(2013) Binjie Wang et al.   ORGANIC LETTERS

1,2,3-Triazoles as versatile directing group for selective sp2 and sp3 C–H activation: cyclization vs substitution

(2013) Xiaohan Ye et al.   Chemical Science

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

Thioethers as Directing Group for the Palladium-Catalyzed Direct Arylation of Arenes

(2012) Jinzhong Yao et al.   ADVANCED SYNTHESIS & CATALYSIS

Pd-Catalyzed C-H Olefination of (Hetero)Arenes by Using Saturated Ketones as an Olefin Source

(2012) Yaping Shang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

Sulfoximines: A Reusable Directing Group for Chemo- and Regioselective ortho CH Oxidation of Arenes

(2012) M. Ramu Yadav et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Functionalization of Unactivated sp3 C–H Bonds via exo-Directing Groups: Synthesis of Chemically Differentiated 1,2-Diols

(2012) Zhi Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Primary-C(sp3)–H Acyloxylation at Room Temperature

(2012) Raja K. Rit et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Alkenylation of Arenes Using Thioethers as Directing Groups

(2012) Ming Yu et al.   ORGANIC LETTERS

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Pyridyldiisopropylsilyl Group: A Masked Functionality and Directing Group for Monoselective ortho-Acyloxylation and ortho-Halogenation Reactions of Arenes

(2011) Chunhui Huang et al.   ADVANCED SYNTHESIS & CATALYSIS

Modifiable Sulfur Tethers as Directing Groups for Aromatic CH Acetoxylation Reactions

(2011) Heinrich Richter et al.   ADVANCED SYNTHESIS & CATALYSIS

Synergistic Palladium-Catalyzed C(sp3)H Activation/C(sp3)O Bond Formation: A Direct, Step-Economical Route to Benzolactones

(2011) Petr Novák et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Efficient Photocatalytic System for Hydrogen Production by a Robust Hydrogenase Mimic in an Aqueous Solution

(2011) Feng Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Double CH Activation Directed by Sulfoxides in the Synthesis of Dibenzothiophenes

(2011) Rajarshi Samanta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

C–H Bond Activation at Palladium(IV) Centers

(2011) Joy M. Racowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

PyDipSi: A General and Easily Modifiable/Traceless Si-Tethered Directing Group for C−H Acyloxylation of Arenes

(2010) Natalia Chernyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzedo-C−H Acetoxylation of Phenylalanine and Ephedrine Derivatives with MeCOOOtBu/Ac2O

(2010) Chris J. Vickers et al.   ORGANIC LETTERS

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Ortho-Functionalization of 2-Phenoxypyrimidines via Palladium-Catalyzed C−H Bond Activation

(2009) Shaojin Gu et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanism of Benzoquinone-Promoted Palladium-Catalyzed Oxidative Cross-Coupling Reactions

(2009) Kami L. Hull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

(2009) Joy M. Racowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)−Pd(III) Intermediates

(2009) David C. Powers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

O-Acetyl Oximes as Transformable Directing Groups for Pd-Catalyzed C−H Bond Functionalization

(2009) Sharon R. Neufeldt et al.   ORGANIC LETTERS

Direct Ortho-Acetoxylation of Anilides via Palladium-Catalyzed sp2C−H Bond Oxidative Activation

(2008) Guan-Wu Wang et al.   JOURNAL OF ORGANIC CHEMISTRY