Convergent, asymmetric synthesis of vicinal amino alcohols via Rh-catalyzed addition of α-amido trifluoroborates to carbonyls

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Trifluoromethyl Ketones

(2013) Renshi Luo et al.   ADVANCED SYNTHESIS & CATALYSIS

Trifluoromethyl ketones: properties, preparation, and application

(2013) Christopher B. Kelly et al.   CHEMICAL COMMUNICATIONS

Development of a Large Scale Asymmetric Synthesis of the Glucocorticoid Agonist BI 653048 BS H3PO4

(2013) Jonathan T. Reeves et al.   JOURNAL OF ORGANIC CHEMISTRY

Improving Carbene–Copper-Catalyzed Asymmetric Synthesis of α-Aminoboronic Esters Using Benzimidazole-Based Precursors

(2013) Kun Wen et al.   JOURNAL OF ORGANIC CHEMISTRY

Boronic Esters in Asymmetric Synthesis

(2013) Donald S. Matteson   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective One-pot Aminoborylation of Aldehydes: A Strategy for Construction of Nonracemic α-Amino Boronates

(2013) Kai Hong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enantioenriched Tertiary Boronic Esters by the Lithiation/Borylation of Secondary Alkyl Benzoates

(2013) Alexander P. Pulis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereo- and Enantioselective Allylboration of Aldehydes using α-Substituted Allyl/Crotyl Pinacol Boronic Esters via in Situ Generated Borinic Esters

(2013) Jack L.-Y. Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal free catalytic hydroboration of multiple bonds in methanol using N-heterocyclic carbenes under open atmosphere

(2013) Kun Wen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh-catalyzed Addition of β-Carbonyl Pinacol Alkylboronates to Aldehydes: Asymmetric Synthesis of γ-Butyrolactones

(2013) Changwan Zhang et al.   ORGANIC LETTERS

Pd-Catalyzed Suzuki–Miyaura Cross-Coupling Reactions between Sulfamates and Potassium Boc-Protected Aminomethyltrifluoroborates

(2013) Gary A. Molander et al.   ORGANIC LETTERS

Chiral NHC/Cu(I)-Catalyzed Asymmetric Hydroboration of Aldimines: Enantioselective Synthesis of α-Amido Boronic Esters

(2013) Ping Tian et al.   SYNLETT

Asymmetric addition of chiral boron-ate complexes to cyclic iminium ions

(2013) Maziar Mohiti et al.   Chemical Science

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

(2012) Benjamin M. Partridge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium and copper-catalyzed asymmetric conjugate addition of alkenyl nucleophiles

(2012) Daniel Müller et al.   CHEMICAL COMMUNICATIONS

Asymmetric synthesis of α-amino boronate esters via organocatalytic pinacolboryl addition to tosylaldimines

(2012) Cristina Solé et al.   CHEMICAL COMMUNICATIONS

Boron Containing Compounds as Protease Inhibitors

(2012) Reem Smoum et al.   CHEMICAL REVIEWS

Convergent, Fit-For-Purpose, Kilogram-Scale Synthesis of a 5-Lipoxygenase Inhibitor

(2012) Stéphane G. Ouellet et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Discovery of HSD-621 as a Potential Agent for the Treatment of Type 2 Diabetes

(2012) Zhao-Kui Wan et al.   ACS Medicinal Chemistry Letters

Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary Stereocentres

(2011) Helen K. Scott et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reinvestigation of Aminomethyltrifluoroborates and Their Application in Suzuki−Miyaura Cross-Coupling Reactions

(2011) Jessica Raushel et al.   JOURNAL OF ORGANIC CHEMISTRY

Inversion or Retention? Effects of Acidic Additives on the Stereochemical Course in Enantiospecific Suzuki–Miyaura Coupling of α-(Acetylamino)benzylboronic Esters

(2011) Tomotsugu Awano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Cross-Coupling of Sulfonamidomethyltrifluoroborates

(2011) Gary A. Molander et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Arylation

(2011) Ping Tian et al.   ACS Catalysis

Synthesis and Applications oftert-Butanesulfinamide

(2010) MaryAnn T. Robak et al.   CHEMICAL REVIEWS

Synthetic applications of rhodium catalysed conjugate addition

(2010) Hannah J. Edwards et al.   CHEMICAL SOCIETY REVIEWS

Conjugate Boration of β,β-Disubstituted Unsaturated Esters: Asymmetric Synthesis of Functionalized Chiral Tertiary Organoboronic Esters

(2010) Xinhui Feng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments in Methodology for the Direct Oxyamination of Olefins

(2010) Timothy J. Donohoe et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of β-amino-α-trifluoromethyl alcohols and their applications in organic synthesis

(2010) Grzegorz Mlostoń et al.   JOURNAL OF FLUORINE CHEMISTRY

Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Amidomethyltrifluoroborates and Their Use in Cross-Coupling Reactions

(2010) Gary A. Molander et al.   ORGANIC LETTERS

A chiral Rh–phosphite complex displaying high activity in the enantioselective Rh-catalyzed addition of arylboronic acids to carbonyl compounds: when and why atropos is better than tropos

(2010) Varsha R. Jumde et al.   TETRAHEDRON-ASYMMETRY

Complete Stereoretention in the Rhodium-Catalyzed 1,2-Addition of Chiral Secondary and Tertiary Alkyl Potassium Trifluoroborate Salts to Aldehydes

(2009) Abel Ros et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organotrifluoroborates and Monocoordinated Palladium Complexes as Catalysts—A Perfect Combination for Suzuki–Miyaura Coupling

(2009) Gary A. Molander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α-Amidobenzylation of Aryl and Alkenyl Halides via Palladium-catalyzed Suzuki–Miyaura Coupling with α-(Acylamino)benzylboronic Esters

(2009) Toshimichi Ohmura et al.   CHEMISTRY LETTERS

Rhodium-Catalyzed Tandem Transformations with Organoboron Reagents: Sequential Multiple C-C Bond Formations

(2009) So Won Youn   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Reductive cross-coupling reactions (RCCR) between CN and CO for β-amino alcohol synthesis

(2009) Olga N. Burchak et al.   TETRAHEDRON

The rhodium-catalysed 1,2-addition of arylboronic acids to aldehydes and ketones with sulfonated S-Phos

(2009) James R. White et al.   TETRAHEDRON LETTERS

Metal-Catalyzed Reactions of Organoboronic Acids and Esters

(2008) Norio Miyaura   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

The Many Roles for Fluorine in Medicinal Chemistry

(2008) William K. Hagmann   JOURNAL OF MEDICINAL CHEMISTRY

Asymmetric Copper-Catalyzed Synthesis of α-Amino Boronate Esters fromN-tert-Butanesulfinyl Aldimines

(2008) Melissa A. Beenen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS