4.5 Article

PVA nano composite membrane for DMFC application

Journal

SOLID STATE IONICS
Volume 201, Issue 1, Pages 21-26

Publisher

ELSEVIER
DOI: 10.1016/j.ssi.2011.07.013

Keywords

Polyvinyl alcohol (PVA); Sulfonated MWCNT; Fluorinated MMT; Polymer nano composite membrane; DMFC

Funding

  1. National Research Foundation of Korea
  2. Ministry of Education, Science and Technology [2011-0001676]

Ask authors/readers for more resources

A new PEM composite membrane comprising of polyvinyl alcohol (PVA), sulfonic acid functionalized CNT and fluorinated MMT has been fabricated. Composite polymer membrane has been prepared by simple solution casting method. Composite properties have been evaluated by using thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), and FTIR techniques. The proton conductivity, methanol crossover and water uptake properties of newly fabricated membrane have been studied. The polymer membrane shows good thermal properties. The water content is in the range of 35-45%. Especially, it has been found that the fluorinated MMT used in this study plays a decisive role in water uptake and acts as a hydrophobic surface for controlling the swelling. The proton conductivities and the methanol permeabilities of all the membranes are in the range of 10(-3) to 10(-2) S/cm and 2.08 x 10(-6) cm(2)/s at room temperature, respectively. (C) 2011 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.5
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Physical

An approach of balancing the ionic conductivity and mechanical properties of PVA based nanocomposite membrane for DMFC by various crosslinking agents with ionic liquid

Nitul Kakati, Jatindranath Maiti, Gautam Das, Seok Hee Lee, Young Soo Yoon

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2015)

Article Chemistry, Physical

Imidazolium functionalized poly(vinyl chloride-co-vinyl acetate)-based anion exchange membrane

Jatindranath Maiti, Nitul Kakati, Padrnini Basumatary, Sung Pil Woo, Young Soo Yoon

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2016)

Article Physics, Multidisciplinary

A new approach: Li2S-P2S5 thin-films prepared by thermal evaporation as solid electrolytes

Sung Pil Woo, Nitul Kakati, In Yea Kim, Seok Hee Lee, Young Soo Yoon

JOURNAL OF THE KOREAN PHYSICAL SOCIETY (2016)

Letter Physics, Multidisciplinary

Ionic-liquid-assisted Synthesis of Core-shell RuNi@Pt Nanoparticles on Multiwall Carbon Nanotubes for Methanol Oxidation

Nitul Kakati, Young Soo Yoon

JOURNAL OF THE KOREAN PHYSICAL SOCIETY (2016)

Article Materials Science, Coatings & Films

Corrosion and electrical properties of carbon/ceramic multilayer coated on stainless steel bipolar plates

SeokHee Lee, SungPil Woo, Nitul Kakati, Youna Lee, YoungSoo Yoon

SURFACE & COATINGS TECHNOLOGY (2016)

Article Chemistry, Physical

Synthesis of ZnNiSnO4 nanorods by a simple hydrothermal method as a new anode material for Li ion battery

Nitul Kakati, Kangsoo Lee, Young Soo Yoon

JOURNAL OF ALLOYS AND COMPOUNDS (2017)

Article Materials Science, Composites

Nafion® based hybrid composite membrane containing GO and dihydrogen phosphate functionalized ionic liquid for high temperature polymer electrolyte membrane fuel cell

Jatindranath Maiti, Nitul Kakati, Sung Pil Woo, Young Soo Yoon

COMPOSITES SCIENCE AND TECHNOLOGY (2018)

Review Chemistry, Multidisciplinary

Anode Catalysts for Direct Methanol Fuel Cells in Acidic Media: Do We Have Any Alternative for Pt or Pt-Ru?

Nitul Kakati, Jatindranath Maiti, Seok Hee Lee, Seung Hyun Jee, Balasubramanian Viswanathan, Young Soo Yoon

CHEMICAL REVIEWS (2014)

Article Chemistry, Multidisciplinary

Water Soluble Sodium Sulfate Nanorods as a Versatile Template for the Designing of Copper Sulfide Nanotubes

Gautam Das, Nitul Kakati, Seok Hee Lee, Niranjan Karak, Young Soo Yoon

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY (2014)

Review Energy & Fuels

A Comprehensive Review of Nanomaterials Developed Using Electrophoresis Process for High-Efficiency Energy Conversion and Storage Systems

Seok Hee Lee, Sung Pil Woo, Nitul Kakati, Dong-Joo Kim, Young Soo Yoon

ENERGIES (2018)

Article Materials Science, Multidisciplinary

One-pot hydrothermal synthesis of heteroatom co-doped with fluorine on reduced graphene oxide for enhanced ORR activity and stability in alkaline media

Yvonne Ligaya F. Musico, Nitul Kakati, Marc Francis M. Labata, Joey D. Ocon, Po-Ya Abel Chuang

MATERIALS CHEMISTRY AND PHYSICS (2019)

Article Chemistry, Physical

Insights into the Ni/C-Based Thin-Film Catalyst Layer Design for Urea Oxidation Reaction in a Three-Electrode System

Nitul Kakati, Guangfu Li, Po-Ya Abel Chuang

Summary: This study systematically investigated the influence of Nafion ionomer in Ni/C catalyst ink, catalyst loading on the glassy carbon electrode surface, and KOH and urea concentrations on UOR activity. A standard preparation method and benchmark protocol were proposed to obtain reliable UOR catalyst performance. The findings provide insights into designing and evaluating UOR catalysts for advancing urea electrolysis technology.

ACS APPLIED ENERGY MATERIALS (2021)

Article Electrochemistry

Hollow Sodium Nickel Fluoride Nanocubes Deposited MWCNT as An Efficient Electrocatalyst for Urea Oxidation

Nitul Kakati, Jatindranath Maiti, Kang Soo Lee, Balasubramanian Viswanathan, Young Soo Yoon

ELECTROCHIMICA ACTA (2017)

No Data Available