Rh-catalyzed desymmetrization of α-quaternary centers by isomerization-hydroacylation

Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

(2015) Yiyang Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Isomerization of Olefins Triggered by Rhodium-Catalyzed CH Bond Activation: Control of Endocyclic β-Hydrogen Elimination

(2015) Stephanie Y. Y. Yip et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intramolecular Hydroacylation of Unactivated Alkenes: An NHC-Catalyzed Robust and Versatile Formation of Cyclic Chiral Ketones

(2015) Daniel Janssen-Müller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Substrate-Directed Hydroacylation: Rhodium-Catalyzed Coupling of Vinylphenols and Nonchelating Aldehydes

(2014) Stephen K. Murphy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Rhodium(I)-Catalyzed Carbonyl Carboacylations Initiated by CC Bond Activation

(2014) Laetitia Souillart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective Carbocyclization of 1,6-Heptadienes Triggered by Rhodium-Catalyzed Activation of an Olefinic CH Bond

(2014) Christophe Aïssa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Rhodium(I)-Catalyzed Activation of Enantiotopic Cyclobutanone CC Bonds

(2014) Laetitia Souillart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Formation of Cyano-Bearing All-Carbon Quaternary Stereocenters: Desymmetrization by Copper-Catalyzed N-Arylation

(2014) Fengtao Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective hydroacylation of N-vinylindole-2-carboxaldehydes

(2014) Avipsa Ghosh et al.   CHEMICAL COMMUNICATIONS

Rh(I)-Catalyzed Intermolecular Hydroacylation: Enantioselective Cross-Coupling of Aldehydes and Ketoamides

(2014) Kevin G. M. Kou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Enantioselective C(sp3)–H Activation Using a Chiral Hydroxamic Acid Ligand

(2014) Kai-Jiong Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective synthesis of quaternary carbon stereocentres

(2014) Kyle W. Quasdorf et al.   NATURE

Enantioselective construction of remote quaternary stereocentres

(2014) Tian-Sheng Mei et al.   NATURE

Synthetic ion transporters can induce apoptosis by facilitating chloride anion transport into cells

(2014) Sung-Kyun Ko et al.   Nature Chemistry

Enantioselective Synthesis of Polycyclic Nitrogen Heterocycles by Rh-Catalyzed Alkene Hydroacylation: Constructing Six-Membered Rings in the Absence of Chelation Assistance

(2014) Xiang-Wei Du et al.   ORGANIC LETTERS

Stereocontrol of All-Carbon Quaternary Centers through Enantioselective Desymmetrization ofMesoPrimary Diols by Organocatalyzed Acyl Transfer

(2013) Christèle Roux et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic asymmetric desymmetrization: efficient construction of spirocyclic oxindoles bearing a unique all-carbon quaternary stereogenic center via sulfa-Michael addition

(2013) Lu Yao et al.   CHEMICAL COMMUNICATIONS

Enantioselective Gold(I)-Catalyzed Vinylogous [3 + 2] Cycloaddition between Vinyldiazoacetates and Enol Ethers

(2013) John F. Briones et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Pyrroloindolines via a Rhodium(II)-Catalyzed Annulation of Indoles

(2013) Jillian E. Spangler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

(2013) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Olefin Isomerization/Allyl Claisen Rearrangement/Intramolecular Hydroacylation Cascade

(2013) Ryuichi Okamoto et al.   ORGANIC LETTERS

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Rh-Catalyzed Carboacylation of Olefins: Efficient Syntheses of Chiral Poly-Fused Rings

(2012) Tao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Allylic Carbon–Carbon Double Bond Directed Pd-Catalyzed Oxidative ortho-Olefination of Arenes

(2012) Parthasarathy Gandeepan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium/Brønsted Acid-Catalyzed α-Allylation of Aldehydes with Allylic Alcohols

(2011) Gaoxi Jiang et al.   ADVANCED SYNTHESIS & CATALYSIS

Chlorostyrenes in Iron-Catalyzed Biaryl Coupling Reactions

(2011) Samet Gülak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Intramolecular Hydroacylation with Rhodium/Phosphoramidite-Alkene Ligand Complexes

(2011) Thomas J. Hoffman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of All-Carbon Quaternary Stereocenters via Desymmetrization of 2,2-Disubstituted 1,3-Propanediols

(2011) Ji Young Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Enantioselective Intermolecular Hydroacylation: Substrate-Directed Addition of Salicylaldehydes to Homoallylic Sulfides

(2010) Matthew M. Coulter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation

(2010) Diem H. T. Phan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen-directed ketone hydroacylation: Enantioselective synthesis of benzoxazecinones

(2010) Hasan A. Khan et al.   Chemical Science

Transition Metal Catalyzed Alkene and Alkyne Hydroacylation

(2009) Michael C. Willis   CHEMICAL REVIEWS

Rh-Catalyzed Intramolecular Olefin Hydroacylation: Enantioselective Synthesis of Seven- and Eight-Membered Heterocycles

(2009) Matthew M. Coulter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes

(2009) Yu Shibata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Enantioselective C−H Olefination of Diphenylacetic Acids

(2009) Bing-Feng Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed anomalous dimerization of styrenes involving the cleavage of the ortho C–H bond

(2008) Mamoru Tobisu et al.   CHEMICAL COMMUNICATIONS

Catalytic Enantioselective Intermolecular Hydroacylation: Rhodium-Catalyzed Combination of β-S-Aldehydes and 1,3-Disubstituted Allenes

(2008) James D. Osborne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Carbon−Carbon σ Bond Activation: An Intramolecular Carbo-Acylation Reaction with Acylquinolines

(2008) Ashley M. Dreis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Rhodium-Catalyzed Intramolecular Hydroacylation: A Computational Study

(2007) I. F. Dempsey Hyatt et al.   ORGANOMETALLICS