Highly Enantioselective Rhodium(I)-Catalyzed Carbonyl Carboacylations Initiated by CC Bond Activation

Highly Enantioselective Rhodium(I)-Catalyzed Activation of Enantiotopic Cyclobutanone CC Bonds

(2014) Laetitia Souillart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Divergent Syntheses of Fused β-Naphthol and Indene Scaffolds by Rhodium-Catalyzed Direct and Decarbonylative Alkyne-Benzocyclobutenone Couplings

(2014) Peng-hao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cleavage of C–C and C–Si σ-Bonds and Their Intramolecular Exchange

(2014) Naoki Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Insertion of a Carbenoid Carbon into a C–C Bond To Expand Cyclobutanols to Cyclopentanols

(2014) Akira Yada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Rhodium(I)-Catalyzed C–C Activations with Zwitterionic Bis-phospholane Ligands

(2014) Evelyne Parker et al.   ORGANOMETALLICS

Exploitation of Rh(i)–Rh(iii) cycles in enantioselective C–C bond cleavages: access to β-tetralones and benzobicyclo[2.2.2]octanones

(2013) Laetitia Souillart et al.   Chemical Science

Rhodium-Catalyzed Regioselective Carboacylation of Olefins: A CC Bond Activation Approach for Accessing Fused-Ring Systems

(2012) Tao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom- and Step-Economical Pathway to Chiral Benzobicyclo[2.2.2]octenones through Carbon-Carbon Bond Cleavage

(2012) Lantao Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed C-C Bond Cleavage Reactions - An Update

(2012) Ales Korotvicka et al.   CURRENT ORGANIC CHEMISTRY

Highly Enantioselective Rh-Catalyzed Carboacylation of Olefins: Efficient Syntheses of Chiral Poly-Fused Rings

(2012) Tao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular σ-Bond Metathesis Between Carbon–Carbon and Silicon–Silicon Bonds

(2012) Naoki Ishida et al.   ORGANIC LETTERS

The Evans-Tishchenko Reaction: Scope and Applications

(2012) Alison Hulme et al.   SYNTHESIS-STUTTGART

Synthesis of 3,3-disubstituted α-tetralones by rhodium-catalysed reaction of 1-(2-haloaryl)cyclobutanols

(2011) Naoki Ishida et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Acylation with Quinolinyl Ketones: Carbon−Carbon Single Bond Activation as the Turnover-Limiting Step of Catalysis

(2011) Colin M. Rathbun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

β-Carbon Elimination from Cyclobutanols: A Clean Access to Alkylrhodium Intermediates Bearing a Quaternary Stereogenic Center

(2011) Nicolai Cramer et al.   SYNLETT

Transition-Metal-Catalyzed Rearrangements of Small Cycloalkanes: Regioselectivity Trends in β-Carbon Elimination Reactions

(2011) Christophe Aïssa   SYNTHESIS-STUTTGART

Rhodium(I)-Catalyzed 1,4-Silicon Shift of Unactivated Silanes from Aryl to Alkyl: Enantioselective Synthesis of Indanol Derivatives

(2010) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Arylative Ring-Opening Reactions of Norbornenols: Entry to Highly Substituted Cyclohexenes, Quinolines, and Tetrahydroquinolines

(2010) Michael Waibel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desymmetrizations of meso-tert-norbornenols by rhodium(i)-catalyzed enantioselective retro-allylations

(2010) Michael Waibel et al.   CHEMICAL COMMUNICATIONS

Metal-catalysed cleavage of carbon–carbon bonds

(2010) Masahiro Murakami et al.   CHEMICAL COMMUNICATIONS

Rhodium(I)-Catalyzed Enantioselective Activation of Cyclobutanols: Formation of Cyclohexane Derivatives with Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed C−C Bond Cleavage: Construction of Acyclic Methyl Substituted Quaternary Stereogenic Centers

(2010) Tobias Seiser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nitrogen-directed ketone hydroacylation: Enantioselective synthesis of benzoxazecinones

(2010) Hasan A. Khan et al.   Chemical Science

Enantioselective Synthesis of Indanols from tert-Cyclobutanols Using a Rhodium-Catalyzed CC/CH Activation Sequence

(2009) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselectivity in Catalytic CC and CH Bond Activation: Controlling Intermolecular Carboacylation and Hydroarylation of Alkenes

(2009) Michael T. Wentzel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereoselective Restructuring of 3-Arylcyclobutanols into 1-Indanols by Sequential Breaking and Formation of Carbon–Carbon Bonds

(2009) Masanori Shigeno et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Insights into the Rhodium-Catalyzed Intramolecular Ketone Hydroacylation

(2009) Zengming Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phthalides by Rhodium-Catalyzed Ketone Hydroacylation

(2009) Diem H. T. Phan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective metal-catalyzed activation of strained rings

(2009) Tobias Seiser et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective CC Bond Activation of Allenyl Cyclobutanes: Access to Cyclohexenones with Quaternary Stereogenic Centers

(2008) Tobias Seiser et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed [4+2+2]-Type Annulation Reaction of Cyclobutanones with Diynes and Enynes

(2008) Shinji Ashida et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Rh-Catalyzed Carbonyl Hydroacylation:  An Enantioselective Approach to Lactones

(2008) Zengming Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Sequential Carbon−Carbon Bond Cleavage/Formation Producing Arylated Benzolactones

(2008) Takanori Matsuda et al.   ORGANIC LETTERS

Rhodium-Catalyzed Kinetic Resolution of Tertiary Homoallyl Alcohols via Stereoselective Carbon−Carbon Bond Cleavage

(2008) Ryo Shintani et al.   ORGANIC LETTERS

A Pre-RNA Candidate Revisited:  Both Enantiomers of Flexible Nucleoside Triphosphates are DNA Polymerase Substrates

(2007) Benjamin D. Heuberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY