☆ 4.8 Article

Cationic Palladium(II)-Catalyzed Highly Enantioselective Tandem Reactions of ortho-Boronate-Substituted Cinnamic Ketones and Internal Alkynes: A Convenient Synthesis of Optically Active Indenes

ORGANIC LETTERS (2009)

Journal

ORGANIC LETTERS

Volume 11, Issue 6, Pages 1405-1408

Publisher

AMER CHEMICAL SOC

DOI: 10.1021/ol9001015

Keywords

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Categories

Chemistry, Organic

Funding

Major State Basic Research Program [2006CB806105]
National Natural Science Foundation of China [20732005]
Chinese Academy of Sciences

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Abstract

Cationic palladium(II)-catalyzed tandem reactions of ortho-boronate-substituted cinnamic ketones and internal alkynes to yield optically active indenes were developed in high yields and good enantioselectivities.

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