Article
Chemistry, Analytical
Matthias Lorenz, Junting Zhang, Alexander G. Shard, Jean-Luc Vorng, Paulina D. Rakowska, Ian S. Gilmore
Summary: A technique for directed transfer of molecules onto a sample surface inside a ToF-SIMS instrument using GCIB sputtering is introduced, with an example application in ME SIMS. This method does not require solvents, can be interlaced with SIMS depth profiling and 3D imaging cycles, and allows fine tuning of molecular deposition. Further study and optimization are needed to enhance signal ratios for drug molecules.
ANALYTICAL CHEMISTRY
(2021)
Article
Biochemical Research Methods
Gordon Rinke, Ludger Harnau, Stephan Rauschenbach
Summary: The study demonstrates several methods for generating, characterizing, and depositing nanoparticle ion beams in vacuum, with a focus on cluster ion beams generated by ESI of organic salt solutions. The transition from clusters to nanoparticles, and their successful deposition, suggests that ES-IBD can handle heavy and highly charged nanoparticles in principle. However, the reproducibility of nanoparticle deposition from dispersions is low due to the lack of control by mass spectrometry.
JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
(2021)
Article
Chemistry, Multidisciplinary
Roland Sachser, Johanna Huetner, Christian H. Schwalb, Michael Huth
Summary: Scanning Hall probe microscopy is used for minimally invasive characterization of magnetic thin films and nanostructures by measuring the emanating magnetic stray field. Sensor probes typically use highly miniaturized spin-valve elements or semimetals. Nanogranular ferromagnetic Hall devices fabricated by direct-write method can be tailor-made for any probe geometry and the magnetic stray field sensitivity can be optimized in situ.
Article
Chemistry, Physical
Caleb Stetson, Yanli Yin, Andrew Norman, Steven P. Harvey, Manuel Schnabel, Chunmei Ban, Chun-Sheng Jiang, Steven C. DeCaluwe, Mowafak Al-Jassim
Summary: This study investigated the dynamic evolution of active silicon materials and solid electrolyte interface (SEI) using various analytical techniques, providing possible strategies for extending the lifetime of silicon anodes.
JOURNAL OF POWER SOURCES
(2021)
Article
Instruments & Instrumentation
N. Alex Zirakparvar, Tyler L. Spano, Andrew Miskowiec, Julie B. Smith, Cole R. Hexel, Michael Ambrogio, Roger Kapsimalis
Summary: The study on the sputtering and ionization process during SIMS analysis reveals that both the intrinsic properties of the compound and processes at the sputtering site influence the observed uranium elemental and molecular oxide secondary ion yields. The findings suggest that the material being sputtered and processes at the sputtering site play crucial roles in determining ion yields, emphasizing the need for additional models to consider the competing influences of a sample's chemical and/or structural form, reactions at the sputtering site, as well as ionization and ion extraction dynamics.
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
(2021)
Article
Materials Science, Multidisciplinary
Jean Almoric, Malik Durand, Anthony Seret, Alexis Nicolay, Arnaud Houel, Isabelle Berbezier, Nathalie Bozzolo
Summary: SIMS is a widely used chemical analysis technique in semiconductor science and metallurgy, providing semiquantitative information on the depth distribution of elements. The development of innovative analytical SIMS implemented in FIB/SEM allows high-resolution elemental chemical mapping, demonstrating excellent performance for nanoscale characterization of materials.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
(2022)
Article
Engineering, Biomedical
Yuji Nashimoto, Minori Abe, Ryota Fujii, Noriko Taira, Hiroki Ida, Yasufumi Takahashi, Kosuke Ino, Javier Ramon-Azcon, Hitoshi Shiku
Summary: This study evaluates the role of scanning probe microscopy (SPM) as an analytical tool for microphysiological systems (MPS), providing a new solution for real-time high spatial resolution imaging. A simple vascular model was used for permeability and topographical analysis, paving the way for the application of SPM technology in MPS.
ADVANCED HEALTHCARE MATERIALS
(2021)
Article
Chemistry, Physical
Sang Ju Lee, Aram Hong, Jinwan Cho, Chang Min Choi, Ji Young Baek, Jae Yeong Eo, Byeong Jun Cha, Woo Jun Byeon, Jin Young We, Sangwon Hyun, Minwoo Jeon, Choelho Jeon, Dong Jin Ku, Myoung Choul Choi
Summary: Studied the characteristics of gas cluster ion beam (GCIB) and found that the secondary ion efficiency is highest with a CO2/Ar mole fraction ratio of 96%, doubling the efficiency compared to pure Ar clusters.
APPLIED SURFACE SCIENCE
(2022)
Review
Physics, Multidisciplinary
Jean-Nicolas Audinot, Patrick Philipp, Olivier De Castro, Antje Biesemeier, Quang Hung Hoang, Tom Wirtz
Summary: This paper reviews the combination of Helium Ion Microscopy (HIM) and Secondary Ion Mass Spectrometry (SIMS), highlighting the advantages of the integrated HIM-SIMS instrument. The technique is capable of producing high-resolution elemental SIMS maps, while maintaining sub-nanometric resolution in the secondary electron microscopy mode. Applications in materials research, life sciences, and geology are also presented and summarized.
REPORTS ON PROGRESS IN PHYSICS
(2021)
Article
Chemistry, Analytical
David Klenerman, Yuri Korchev, Pavel Novak, Andrew Shevchuk
Summary: The reduction in ion current near a cell surface when a fine pipette approaches allows imaging of cell surface topography with nanoscale resolution without damaging the delicate surface. By combining various methods such as single-channel recording, force application, and fluorescence imaging, there is great potential to image and map live cell surfaces at the nanoscale with high resolution and speed.
ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, VOL 14, 2021
(2021)
Article
Multidisciplinary Sciences
Chao Li, Zhen Xu, Yajie Zhang, Jie Li, Na Xue, Ruoning Li, Mingjun Zhong, Tianhao Wu, Yifan Wang, Na Li, Ziyong Shen, Shimin Hou, Richard Berndt, Yongfeng Wang, Song Gao
Summary: Structure transformations from fractals to chains are achieved through the coassembly of carbon monoxide and the catassembly of carbon dioxide. Reversible transformations between fractals and periodic structures are important for understanding fractal formation, but controllably achieving such transformations remains a challenge. We investigate the effect of CO and CO2 molecules on Sierpinski triangles assembled from Fe atoms and C3PC molecules on Au surfaces, and discover that gas molecules induce a transition from STs into 1D chains. Based on density functional theory modeling, the atomistic mechanism involves the transformation of a stable 3-fold coordination Fe(C3PC)(3) motif to Fe(C3PC)(4) with an axially bonded CO molecule. CO2 causes the structural transformation through a molecular catassembly process.
NATIONAL SCIENCE REVIEW
(2023)
Article
Chemistry, Analytical
Florent Penen, Rene Raave, Annemarie Kip, Sandra Heskamp, Per Malmberg
Summary: ToF-SIMS imaging is a quick and sensitive technique that can visualize HER2 specific radiotracers in ovarian and breast cancer xenograft tumor sections to reflect the heterogeneous distribution of trastuzumab.
MICROCHEMICAL JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Xiangdong Xu, Daniel Martin-Yerga, Nicholas E. Grant, Geoff West, Sophie L. Pain, Minkyung Kang, Marc Walker, John D. Murphy, Patrick R. Unwin
Summary: Understanding the formation of SEI and (de)lithiation phenomena at silicon electrodes is crucial for improving the performance and longevity of Si-based lithium-ion batteries. However, these processes are still elusive, particularly the role of Si surface termination.
Article
Physics, Applied
Kouichi Hirata, Keisuke Yamada, Atsuya Chiba, Yoshimi Hirano, Yuichi Saitoh
Summary: Energetic C-60 ions with energies of the order of MeV are effective for highly sensitive secondary ion (SI) mass spectrometry, providing abundant SIs for the identification of target materials. This study investigated the impact angle dependence of SI mass spectra for MeV C-60 ions, revealing that shallower angle impacts can yield surface-sensitive information through intense emission of surface-derived SIs.
APPLIED PHYSICS EXPRESS
(2022)
Review
Chemistry, Physical
Chunlei Yang, Tianhui Su, Yanbo Hua, Liming Zhang
Summary: This review summarizes the latest results of electrochemical scanning probe microscopy techniques in studying the interfacial properties of electrocatalysts and photoelectrodes, and offers some perspectives on future research directions.
Retraction
Materials Science, Multidisciplinary
H. Wu, S. Sijbrandij, S. McVey, J. Notte
MICROSCOPY AND MICROANALYSIS
(2015)
Article
Microscopy
N. Klingner, R. Heller, G. Hlawacek, J. von Borany, J. Notte, J. Huang, S. Facsko
Article
Physics, Applied
T. Wirtz, N. Vanhove, L. Pillatsch, D. Dowsett, S. Sijbrandij, J. Notte
APPLIED PHYSICS LETTERS
(2012)
Article
Chemistry, Physical
L. Pillatsch, N. Vanhove, D. Dowsett, S. Sijbrandij, J. Notte, T. Wirtz
APPLIED SURFACE SCIENCE
(2013)
Article
Chemistry, Multidisciplinary
Donald Winston, Vitor R. Manfrinato, Samuel M. Nicaise, Lin Lee Cheong, Huigao Duan, David Ferranti, Jeff Marshman, Shawn McVey, Lewis Stern, John Notte, Karl K. Berggren
Article
Instruments & Instrumentation
Richard H. Livengood, Shida Tan, Roy Hallstein, John Notte, Shawn McVey, F. H. M. Faridur Rahman
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT
(2011)
Article
Instruments & Instrumentation
Nicholas P. Economou, John A. Notte, William B. Thompson
Article
Instruments & Instrumentation
F. H. M. Rahman, Shawn McVey, Louis Farkas, John A. Notte, Shida Tan, Richard H. Livengood
Article
Microscopy
F. H. M. F. Rahman, John A. Notte, Richard H. Livengood, Shida Tan
Article
Materials Science, Multidisciplinary
Frances Allen, Paul T. Blanchard, Russell Lake, David Pappas, Deying Xia, John A. Notte, Ruopeng Zhang, Andrew M. Minor, Norman A. Sanford
Summary: We introduce a new method for focused ion beam sample preparation in atom probe tomography, involving the use of a neon ion beam for final tip shaping. This approach combines the advantages of faster milling with gallium ions and higher precision milling with neon ions. Our experiments with titanium-aluminum alloy and layered aluminum/aluminum-oxide tunnel junction samples demonstrate that the combined gallium and neon ion approach eliminates the gallium contamination that often hinders composition analysis. We propose that using a noble gas ion beam, such as neon, can expand the range of materials suitable for atom probe tomography beyond current capabilities.
MICROSCOPY AND MICROANALYSIS
(2023)
Article
Engineering, Electrical & Electronic
Deying Xia, John Notte, Lewis Stern, Bernhard Goetze
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B
(2015)
Article
Engineering, Electrical & Electronic
David Dowsett, Tom Wirtz, Nico Vanhove, Lex Pillatsch, Sybren Sijbrandij, John Notte
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B
(2012)
Article
Engineering, Electrical & Electronic
Shida Tan, Richard Livengood, Paul Hack, Roy Hallstein, Darryl Shima, John Notte, Shawn McVey
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B
(2011)
Proceedings Paper
Microscopy
Mohan Ananth, Lewis Stern, David Ferranti, Chuong Huynh, John Notte, Larry Scipioni, Colin Sanford, Bill Thompson
SCANNING MICROSCOPIES 2011: ADVANCED MICROSCOPY TECHNOLOGIES FOR DEFENSE, HOMELAND SECURITY, FORENSIC, LIFE, ENVIRONMENTAL, AND INDUSTRIAL SCIENCES
(2011)