Activation of “Inert” Alkenyl/Aryl CO Bond and Its Application in Cross-Coupling Reactions

Selective cine Substitution of 1-Arylethenyl Acetates with Arylboron Reagents and a Diene/Rhodium Catalyst

(2010) Jung-Yi Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cobalt-Catalyzed Sulfonate/Copper Exchange for the Preparation of Highly Functionalized Electron-Deficient Aryl Copper Reagents

(2010) Christoph J. Rohbogner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc Chloride Enhanced Arylations of Secondary Benzyl Trifluoroacetates in the Presence of β-Hydrogen Atoms

(2010) Hui Duan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Synthetic Double Punch: Suzuki-Miyaura Cross-Coupling Mates with CH Functionalization

(2010) Christiane E. I. Knappke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Application of Phenolic Salts to Nickel-Catalyzed Cross-Coupling Reactions with Aryl Grignard Reagents

(2010) Da-Gang Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A P,N-Ligand for Palladium-Catalyzed Ammonia Arylation: Coupling of Deactivated Aryl Chlorides, Chemoselective Arylations, and Room Temperature Reactions

(2010) Rylan J. Lundgren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Amination of Aryl Pivalates by the Cleavage of Aryl CO Bonds

(2010) Toshiaki Shimasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct dehydrative cross-coupling of tautomerizable heterocycles with alkynes via Pd/Cu-catalyzed phosphonium coupling

(2010) Fu-An Kang et al.   CHEMICAL COMMUNICATIONS

A pyridine-bridged bis-benzimidazolylidene pincer nickel(ii) complex: synthesis and practical catalytic application towards Suzuki–Miyaura coupling with less-activated electrophiles

(2010) Tao Tu et al.   CHEMICAL COMMUNICATIONS

A General Palladium-Catalyzed Sonogashira Coupling of Aryl and Heteroaryl Tosylates

(2010) Omar R'kyek et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Sonogashira Coupling of Aryl Mesylates and Tosylates

(2010) Pui Ying Choy et al.   CHEMISTRY-A EUROPEAN JOURNAL

Construction of Polysubstituted Olefins through Ni-Catalyzed Direct Activation of Alkenyl CO of Substituted Alkenyl Acetates

(2010) Chang-Liang Sun et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd-Catalyzed CN Bond Formation with Heteroaromatic Tosylates

(2010) Mette L. H. Mantel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aryl Phosphoramides: Useful Electrophiles for Suzuki-Miyaura Coupling Catalyzed by a NiCl2/dppp System (dppp=1,3-Bis(diphenylphosphino)propane)

(2010) Yu-Long Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Retraction: Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates in Water

(2010) Jan Pschierer et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Retraction: Suzuki-Miyaura Coupling of Aryl Tosylates and Mesylates in Water

(2010) Jan Pschierer et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Stille Cross-Coupling Reactions of Aryl Mesylates and Tosylates Using a Biarylphosphine Based Catalyst System

(2010) Stephen L. Buchwald et al.   HETEROCYCLES

Carbonylative Palladium-Catalyzed Reactions of Lactam-, Lactone-, and Thiolactone-Derived Vinyl Triflates and Phosphates for the Synthesis of N-, O-, and S-Heterocycles

(2010) Ernesto G. Occhiato et al.   HETEROCYCLES

A General Palladium Catalyst System for Suzuki−Miyaura Coupling of Potassium Aryltrifluoroborates and Aryl Mesylates

(2010) Wing Kin Chow et al.   JOURNAL OF ORGANIC CHEMISTRY

Neopentylglycolborylation of Aryl Mesylates and Tosylates Catalyzed by Ni-Based Mixed-Ligand Systems Activated with Zn

(2010) Daniela A. Wilson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed C−O Activation of Phenol Derivatives with Potassium Heteroaryltrifluoroborates

(2010) Gary A. Molander et al.   ORGANIC LETTERS

Nickel-Catalyzed Efficient and Practical Suzuki−Miyaura Coupling of Alkenyl and Aryl Carbamates with Aryl Boroxines

(2010) Li Xu et al.   ORGANIC LETTERS

Efficient Pd-Catalyzed Coupling of Tautomerizable Heterocycles with Terminal Alkynes via C−OH Bond Activation Using PyBrOP

(2010) Ce Shi et al.   ORGANIC LETTERS

Pd-Catalyzed Cross-Coupling Reactions of Amides and Aryl Mesylates

(2010) Karin Dooleweerdt et al.   ORGANIC LETTERS

Palladium-Catalyzed Direct Arylations, Alkenylations, and Benzylations through C−H Bond Cleavages with Sulfamates or Phosphates as Electrophiles

(2010) Lutz Ackermann et al.   ORGANIC LETTERS

Copper-free palladium-catalyzed Sonogashira and Hiyama cross-couplings using aryl imidazol-1-ylsulfonates

(2010) Steven J. Shirbin et al.   TETRAHEDRON LETTERS

Rhodium-Catalyzed Cross-Coupling of Organoboron Compounds with Vinyl Acetate

(2009) Jung-Yi Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C(aryl)O Activation of Aryl Carboxylates in Nickel-Catalyzed Biaryl Syntheses

(2009) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Direct Arylation of (Hetero)Arenes by CH Bond Cleavage

(2009) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbonylation Reactions of Aryl Halides and Related Compounds

(2009) Anne Brennführer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Decarboxylative Cross-Coupling of Aryl Tosylates with Aromatic Carboxylate Salts

(2009) Lukas J. Gooßen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni0-catalyzed Direct Amination of Anisoles Involving the Cleavage of Carbon–Oxygen Bonds

(2009) Mamoru Tobisu et al.   CHEMISTRY LETTERS

Heteroaromatic Tosylates as Electrophiles in Regioselective Mizoroki-Heck-Coupling Reactions with Electron-Rich Olefins

(2009) Thomas M. Gøgsig et al.   CHEMISTRY-A EUROPEAN JOURNAL

N-Heterocyclic Carbene Derived Nickel-Pincer Complexes: Efficient and Applicable Catalysts for Suzuki-Miyaura Coupling Reactions of Aryl/Alkenyl Tosylates and Mesylates

(2009) Jun-ichi Kuroda et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of Isoindolobenzazepine Alkaloids, Lennoxamine and Chilenine, Based on Palladium-Catalyzed Reduction of Alkenyl Phosphates

(2009) Haruhiko Fuwa et al.   HETEROCYCLES

A Ligand Free and Room Temperature Protocol for Pd-Catalyzed Kumada−Corriu Couplings of Unactivated Alkenyl Phosphates

(2009) Delphine Gauthier et al.   JOURNAL OF ORGANIC CHEMISTRY

Suzuki−Miyaura Coupling of Aryl Carbamates, Carbonates, and Sulfamates

(2009) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyphosphine Ligand for Nickel-Catalyzed Cross-Coupling through Nickel/Magnesium Bimetallic Cooperation

(2009) Naohiko Yoshikai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N,N-DiethylO-Carbamate: Directed Metalation Group and Orthogonal Suzuki−Miyaura Cross-Coupling Partner

(2009) Aurora Antoft-Finch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Ni-Catalyzed Selective C−O Bond Activation in Cross-Coupling of Aryl Esters

(2009) Zhe Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Coupling of Ammonia with Aryl Chlorides, Bromides, Iodides, and Sulfonates: A General Method for the Preparation of Primary Arylamines

(2009) Giang D. Vo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling of Alkenyl/Aryl Carboxylates with Grignard Reagent via Fe-Catalyzed C−O Bond Activation

(2009) Bi-Jie Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heteroaromatic Sulfonates and Phosphates as Electrophiles in Iron-Catalyzed Cross-Couplings

(2009) Thomas M. Gøgsig et al.   ORGANIC LETTERS

Imidazolylsulfonates: Electrophilic Partners in Cross-Coupling Reactions

(2009) Jennifer Albaneze-Walker et al.   ORGANIC LETTERS

General, Robust, and Stereocomplementary Preparation of α,β-Disubstituted α,β-Unsaturated Esters

(2009) Hidefumi Nakatsuji et al.   ORGANIC LETTERS

Neopentylglycolborylation of Aryl Chlorides Catalyzed by the Mixed Ligand System NiCl2(dppp)/dppf

(2009) Costel Moldoveanu et al.   ORGANIC LETTERS

A Versatile Catalyst System for Suzuki−Miyaura Cross-Coupling Reactions of C(sp2)-Tosylates and Mesylates

(2009) Brijesh Bhayana et al.   ORGANIC LETTERS

Biaryl Construction through Kumada Coupling with Diaryl Sulfates as One-by-One Electrophiles under Mild Conditions

(2009) Bing-Tao Guan et al.   ORGANIC LETTERS

Synthesis of Arylphosphonates via Palladium-Catalyzed Coupling Reactions of Aryl Imidazolylsulfonates with H-Phosphonate Diesters

(2009) Yong Luo et al.   ORGANOMETALLICS

Enol Phosphinates and Phosphonates: Practical Electrophiles for Cross-Coupling Strategies

(2009) Patrick Steel et al.   SYNTHESIS-STUTTGART

Aminocarbonylations of alkenyl phosphates, chlorides, bromides, and triflates with Mo(CO)6 as a solid CO source

(2009) Olof Lagerlund et al.   TETRAHEDRON

Copper-free Sonogashira reactions of 4-hydroxycoumarins with alkynes

(2009) Yong Luo et al.   TETRAHEDRON

Acyclic ketene aminal phosphates derived from N,N-diprotected acetamides: stability and cross-couplings

(2009) Alessandro B.C. Simas et al.   TETRAHEDRON LETTERS

Palladium-catalyzed direct arylation of 4-hydroxycoumarins with arylboronic acids via C–OH bond activation

(2009) Yong Luo et al.   TETRAHEDRON LETTERS

An efficient route to 4-substituted coumarins, 2(5H)-furanones, and pyrones via palladium-catalyzed couplings of alkenyl tosylates with organoindium reagents

(2009) Wei Gao et al.   TETRAHEDRON LETTERS

Cross-Coupling Reaction of Alkyl Halides with Grignard Reagents Catalyzed by Ni, Pd, or Cu Complexes with π-Carbon Ligand(s)

(2008) Jun Terao et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Promise and Challenge of Iron-Catalyzed Cross Coupling

(2008) Benjamin D. Sherry et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium/N-Heterocyclic Carbene-Catalyzed Cross-Couplings of Aryl Arenesulfonates with Arylboronic Acids

(2008) Liang Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Cross-Coupling of Aryl/Alkenyl Pivalates with Organozinc Reagents through Nickel-Catalyzed CO Bond Activation under Mild Reaction Conditions

(2008) Bi-Jie Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Mesylates

(2008) Chau Ming So et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Amination of Aryl Mesylates

(2008) Chau Ming So et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Cross-Coupling of Aryl Methyl Ethers with Aryl Boronic Esters

(2008) Mamoru Tobisu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biaryl Formation Involving Carbon-Based Leaving Groups: Why Not?

(2008) Sergio M. Bonesi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Arylations of Heteroarenes with Tosylates and Mesylates

(2008) Lutz Ackermann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biaryl Phosphane Ligands in Palladium-Catalyzed Amination

(2008) David S. Surry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Methylation of arenes via Ni-catalyzed aryl C–O/F activation

(2008) Bing-Tao Guan et al.   CHEMICAL COMMUNICATIONS

Phosphate esters as “tunable” reagents in organic synthesis

(2008) Stefano Protti et al.   CHEMICAL COMMUNICATIONS

Direct Vinylation and Difluorovinylation of Arylboronic Acids Using Vinyl- and 2,2-Difluorovinyl Tosylates via the Suzuki−Miyaura Cross Coupling

(2008) Thomas M. Gøgsig et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Amination of Aryl Tosylates

(2008) Cai-Yan Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Suzuki−Miyaura Coupling of Aryl Tosylates Catalyzed by an Array of Indolyl Phosphine−Palladium Catalysts

(2008) Chau Ming So et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 2-Substituted Indoles and Indolines via Suzuki−Miyaura Coupling/5-endo-trigCyclization Strategies

(2008) Haruhiko Fuwa et al.   JOURNAL OF ORGANIC CHEMISTRY

Studies on the 1,2-Migrations in Pd-Catalyzed Negishi Couplings with JosiPhos Ligands

(2008) Anders T. Lindhardt et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Amination of Aryl and Heteroaryl Tosylates at Room Temperature

(2008) Tokutaro Ogata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Hiyama Cross-Couplings of Aryl Arenesulfonates with Arylsilanes

(2008) Liang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Direct Arylation of Tautomerizable Heterocycles with Aryl Boronic Acids via C−OH Bond Activation Using Phosphonium Salts

(2008) Fu-An Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Active Catalyst for Pd-Catalyzed Amination Reactions: Cross-Coupling Reactions Using Aryl Mesylates and the Highly Selective Monoarylation of Primary Amines Using Aryl Chlorides

(2008) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Carbonylation of Aryl Tosylates and Mesylates

(2008) Rachel H. Munday et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling Reactions of Aryl Pivalates with Boronic Acids

(2008) Kyle W. Quasdorf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Biaryl Construction via Ni-Catalyzed C−O Activation of Phenolic Carboxylates

(2008) Bing-Tao Guan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Hiyama Cross-Coupling Reactions of Aryl Mesylates

(2008) Liang Zhang et al.   ORGANIC LETTERS

Efficient Preparation of Terminal Conjugated Dienes by Coupling of Dienol Phosphates with Grignard Reagents under Iron Catalysis

(2008) Gérard Cahiez et al.   ORGANIC LETTERS

C−C Bond Formation Catalyzed Heterogeneously by Nickel-on-Graphite (Ni/Cg)

(2008) Bruce H. Lipshutz et al.   ORGANIC LETTERS

Suzuki-Miyaura Coupling of Diarylmethyl Carbonates with Arylboronic Acids:  A New Access to Triarylmethanes

(2008) Jung-Yi Yu et al.   ORGANIC LETTERS

Two-Step, One-Pot Ni-Catalyzed Neopentylglycolborylation and Complementary Pd/Ni-Catalyzed Cross-Coupling with Aryl Halides, Mesylates, and Tosylates

(2008) Daniela A. Wilson et al.   ORGANIC LETTERS

Palladium−Indolylphosphine-Catalyzed Hiyama Cross-Coupling of Aryl Mesylates

(2008) Chau Ming So et al.   ORGANIC LETTERS

Iron-Catalyzed Alkenylation of Grignard Reagents by Enol Phosphates

(2008) Gérard Cahiez et al.   SYNTHESIS-STUTTGART

Suzuki–Miyaura cross-coupling of α-phosphoryloxy enol ethers with arylboronic acids

(2008) Lee Pedzisa et al.   TETRAHEDRON LETTERS