期刊
SYNTHESIS-STUTTGART
卷 -, 期 16, 页码 2636-2644出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2008-1067194
关键词
cross-coupling; Grignard reactions; iron; alkenes; stereoselectivity
资金
- CNRS
- Ecole Superieure de Chimie Organique et Minerale (ESCOM)
- Fondation de France
Stereoselective preparation of trisubstituted olefins can be easily performed from an Z/E-mixture of enol phosphates by reacting only the E-isomer with a Grignard reagent in the presence of Fe(acac)(3). This procedure combines a kinetic differentiation and a stereoselective reaction. The coupling is very chemoselective in the presence of an alkyl chloride, an ester, a ketone or a nitrile.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据