4.2 Article

TOTAL SYNTHESIS OF ISOINDOLOBENZAZEPINE ALKALOIDS, LENNOXAMINE AND CHILENINE, BASED ON PALLADIUM-CATALYZED REDUCTION OF ALKENYL PHOSPHATES

期刊

HETEROCYCLES
卷 76, 期 1, 页码 521-539

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.3987/COM-08-S(N)40

关键词

Lennoxamine; Chilenine; Isoindolobenzazepine Alkaloid; Alkenyl Phosphate; Palladium-Catalyzed Reaction

资金

  1. Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan

向作者/读者索取更多资源

An efficient method for the synthesis of enol ethers and enecarbamates has been developed based on palladium(0)-catalyzed chemoselective reduction of alkenyl phosphates. This method has been applied successfully to the total synthesis of two isoindolobenzazepine alkaloids, lennoxamine and chilenine.

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