Recent advances in the sulfonylation of alkenes with the insertion of sulfur dioxide via radical reactions

Generation of sulfonated 1-isoindolinones through a multicomponent reaction with the insertion of sulfur dioxide

(2018) Jun Zhang et al.   CHEMICAL COMMUNICATIONS

Stereoselective synthesis of sulfonated 1-indenones via radical-triggered multi-component cyclization of β-alkynyl propenones

(2018) Zheng-Jia Shen et al.   CHEMICAL COMMUNICATIONS

Radicals and Sulfur Dioxide: A Versatile Combination for the Construction of Sulfonyl-Containing Molecules

(2018) Kamil Hofman et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photocatalytic Reaction of Potassium Alkyltrifluoroborates and Sulfur Dioxide with Alkenes

(2018) Tong Liu et al.   ORGANIC LETTERS

Insertion of sulfur dioxide via a radical process: an efficient route to sulfonyl compounds

(2018) Guanyinsheng Qiu et al.   Organic Chemistry Frontiers

Generation of sulfonated isobenzofuran-1(3H)-ones under photocatalysis through the insertion of sulfur dioxide

(2018) Jun Zhang et al.   Organic Chemistry Frontiers

Intramolecular oxysulfonylation of alkenes with the insertion of sulfur dioxide under photocatalysis

(2018) Fu-Sheng He et al.   Organic Chemistry Frontiers

Visible-Light Photocatalysis as an Enabling Tool for the Functionalization of Unactivated C(sp3 )-Substrates

(2017) Sara Roslin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis

(2017) Javad Amani et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Synthesis of Secondary Benzylic Alcohols Enabled by Photoredox/Ni Dual-Catalyzed Cross-Coupling

(2017) Rauful Alam et al.   JOURNAL OF ORGANIC CHEMISTRY

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer

(2017) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides

(2017) Javad Amani et al.   ORGANIC LETTERS

Direct α-Arylation/Heteroarylation of 2-Trifluoroboratochromanones via Photoredox/Nickel Dual Catalysis

(2017) Jennifer K. Matsui et al.   ORGANIC LETTERS

Direct Conversion of Carboxylic Acids to Alkyl Ketones

(2017) Javad Amani et al.   ORGANIC LETTERS

Construction of Functionalized Annulated Sulfone via SO2/I Exchange of Cyclic Diaryliodonium Salts

(2017) Ming Wang et al.   ORGANIC LETTERS

Pd-Catalyzed Intramolecular Aminoalkylation of Unactivated Alkenes: Access to Diverse N-Heterocycles

(2017) Liu Ye et al.   ORGANIC LETTERS

Pd-Catalyzed Selective Synthesis of Cyclic Sulfonamides and Sulfinamides Using K2S2O5 as a Sulfur Dioxide Surrogate

(2017) Hideyuki Konishi et al.   ORGANIC LETTERS

Radical Alkynyltrifluoromethylation of Alkenes Initiated by an Electron Donor–Acceptor Complex

(2017) Heng Jiang et al.   ORGANIC LETTERS

Copper-Catalyzed Arylsulfonylation and Cyclizative Carbonation of N-(Arylsulfonyl)acrylamides Involving Desulfonative Arrangement toward Sulfonated Oxindoles

(2017) Hepan Wang et al.   ORGANIC LETTERS

Organocatalyzed, Photoredox Heteroarylation of 2-Trifluoroboratochromanones via C–H Functionalization

(2017) Jennifer K. Matsui et al.   ORGANIC LETTERS

Dual gold and photoredox catalysis: visible light-mediated intermolecular atom transfer thiosulfonylation of alkenes

(2017) Haoyu Li et al.   Chemical Science

O-Benzyl Xanthate Esters under Ni/Photoredox Dual Catalysis: Selective Radical Generation and Csp3–Csp2 Cross-Coupling

(2017) Brandon A. Vara et al.   ACS Catalysis

Synthesis of 3-(((2,3-dihydrobenzofuran-3-yl)methyl)sulfonyl) coumarins through the reaction of 2-(allyloxy)anilines, sulfur dioxide, and aryl propiolates

(2017) Xuefeng Wang et al.   Organic Chemistry Frontiers

Radical cyclization of benzene-tethered 1,7-enynes with aryldiazonium tetrafluoroborates: a facile route to benzo[j]phenanthridines

(2017) Yuanyuan An et al.   Organic Chemistry Frontiers

Synthesis of 3-((arylsulfonyl)methyl)indolin-2-ones via insertion of sulfur dioxide using anilines as the aryl source

(2017) Tong Liu et al.   Organic Chemistry Frontiers

Reductive insertion of sulfur dioxide for the synthesis of trifluoromethyl thiolsulphonates through a one-pot reaction of aniline and trifluoromethanesulfanylamide

(2017) Jie Sheng et al.   Organic Chemistry Frontiers

Transition-metal-free oxidative reaction of hydrazines and potassium metabisulfite for preparation of sulfonohydrazides

(2017) Yang Wang et al.   Organic Chemistry Frontiers

Synthesis of Chiral Sulfonyl Lactones via Copper-Catalyzed Asymmetric Radical Reaction of DABCO⋅(SO2 )

(2017) Yang Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Generation of Sulfonyl Radicals from Aryldiazonium Tetrafluoroborates and Sulfur Dioxide: The Synthesis of 3-Sulfonated Coumarins

(2016) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-catalyzed synthesis of arylsulfinates through radical coupling reaction

(2016) Weixi Zhang et al.   CHEMICAL COMMUNICATIONS

New amination strategies based on nitrogen-centered radical chemistry

(2016) Tao Xiong et al.   CHEMICAL SOCIETY REVIEWS

Visible light photoredox-controlled reactions of N-radicals and radical ions

(2016) Jia-Rong Chen et al.   CHEMICAL SOCIETY REVIEWS

Photochemically Assisted Introduction of a Benzyl Unit into Isoquinolines Using Benzyltrifluoroborates

(2016) Yutaka Nishigaichi et al.   CHEMISTRY LETTERS

Visible-Light-Mediated Alkenylation, Allylation, and Cyanation of Potassium Alkyltrifluoroborates with Organic Photoredox Catalysts

(2016) Drew R. Heitz et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Progress in Visible-Light Photoredox-Catalyzed Intermolecular 1,2-Difunctionalization of Double Bonds via an ATRA-Type Mechanism

(2016) Thibaut Courant et al.   JOURNAL OF ORGANIC CHEMISTRY

DDQ-Mediated Three-Component Dioxygenation of Alkenes

(2016) Tian-Shu Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Mediated Synthesis of Amidyl Radicals: Transition-Metal-Free Hydroamination and N-Arylation Reactions

(2016) Jacob Davies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Directed, Regiocontrolled Hydroamination of Unactivated Alkenes via Protodepalladation

(2016) John A. Gurak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron(iii)-catalyzed aerobic dioxygenation of styrenes using N-hydroxyphthalimide and N-hydroxybenzotriazole

(2016) Raghunath Bag et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Visible Light Photoredox Cross-Coupling of Acyl Chlorides with Potassium Alkoxymethyltrifluoroborates: Synthesis of α-Alkoxyketones

(2016) Javad Amani et al.   ORGANIC LETTERS

Single-Electron Transmetalation: Protecting-Group-Independent Synthesis of Secondary Benzylic Alcohol Derivatives via Photoredox/Nickel Dual Catalysis

(2016) Rahman Karimi-Nami et al.   ORGANIC LETTERS

Regioselective Intermolecular Diamination and Aminooxygenation of Alkenes with Saccharin

(2016) Claudio Martínez et al.   ORGANIC LETTERS

Catalytic N-radical cascade reaction of hydrazones by oxidative deprotonation electron transfer and TEMPO mediation

(2016) Xiao-Qiang Hu et al.   Nature Communications

Visible-Light-Promoted Carboimination of Unactivated Alkenes for the Synthesis of Densely Functionalized Pyrroline Derivatives

(2016) Sai-Hu Cai et al.   ACS Catalysis

Recent developments for the photoinduced Ar–X bond dissociation reaction

(2016) Guanyinsheng Qiu et al.   Organic Chemistry Frontiers

A versatile strategy for difunctionalization of carbon–carbon multiple bonds by photoredox catalysis

(2016) Takashi Koike et al.   Organic Chemistry Frontiers

Manganese-catalysed hydroperoxidation of carbon–carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions

(2016) Daisuke Yamamoto et al.   Organic Chemistry Frontiers

Generation of (2-oxoindolin-3-yl)methanesulfonohydrazides via a photo-induced reaction of N-(2-iodoaryl)acrylamide, DABSO, and hydrazine

(2016) Kaida Zhou et al.   Organic Chemistry Frontiers

A copper(ii)-catalyzed three-component reaction of aryldiazonium tetrafluoroborates, sulfur dioxide, with alkenes

(2016) Runyu Mao et al.   Organic Chemistry Frontiers

The Cleavage of a CC Bond in Cyclobutylanilines by Visible-Light Photoredox Catalysis: Development of a [4+2] Annulation Method

(2015) Jiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis

(2015) Mirna El Khatib et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Carboetherification of Unactivated Alkenes by Alkyl Nitriles and Alcohols

(2015) Claire Chatalova-Sazepin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Mediated Generation of Nitrogen-Centered Radicals: Metal-Free Hydroimination and Iminohydroxylation Cyclization Reactions

(2015) Jacob Davies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Promoted Iminyl-Radical Formation from Acyl Oximes: A Unified Approach to Pyridines, Quinolines, and Phenanthridines

(2015) Heng Jiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Single-Electron Transmetalation: Synthesis of 1,1-Diaryl-2,2,2-trifluoroethanes by Photoredox/Nickel Dual Catalytic Cross-Coupling

(2015) DaWeon Ryu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organotrifluoroborates: Another Branch of the Mighty Oak

(2015) Gary A. Molander   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Olefin Hydroamidation Enabled by Proton-Coupled Electron Transfer

(2015) David C. Miller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-Electron Transmetalation: An Enabling Technology for Secondary Alkylboron Cross-Coupling

(2015) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Alkene Carboaminations Enabled by Oxidative Proton-Coupled Electron Transfer

(2015) Gilbert J. Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes

(2015) Rong Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Pd-Catalyzed Intermolecular Fluorosulfonylation of Styrenes

(2015) Zheliang Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mn-Catalyzed Highly Efficient Aerobic Oxidative Hydroxyazidation of Olefins: A Direct Approach to β-Azido Alcohols

(2015) Xiang Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

(2015) Osvaldo Gutierrez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fixation of sulfur dioxide into small molecules

(2015) Gang Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Tetrabutylammonium iodide-catalyzed oxidative coupling of enamides with sulfonylhydrazides: synthesis of β-keto-sulfones

(2015) Yucai Tang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Photoredox Cross-Coupling: Ir/Ni Dual Catalysis for the Synthesis of Benzylic Ethers

(2015) Idris Karakaya et al.   ORGANIC LETTERS

Catalytic Arylsulfonyl Radical Triggered 1,7-Enyne Bicyclizations

(2015) Yi-Long Zhu et al.   ORGANIC LETTERS

2,2,2-Trifluoroethylation of Styrenes with Concomitant Introduction of a Hydroxyl Group from Molecular Oxygen by Photoredox Catalysis Activated by Visible Light

(2015) Lun Li et al.   ORGANIC LETTERS

Catalyst-Controlled Amino- versus Oxy-Acetoxylation of Urea-Tethered Alkenes: Efficient Synthesis of Cyclic Ureas and Isoureas

(2015) Wei-Hao Rao et al.   ORGANIC LETTERS

Palladium-Catalyzed Aerobic Aminooxygenation of Alkenes for Preparation of Isoindolinones

(2015) Xuezhen Kou et al.   ORGANIC LETTERS

Protecting group-free, selective cross-coupling of alkyltrifluoroborates with borylated aryl bromides via photoredox/nickel dual catalysis

(2015) Yohei Yamashita et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

An efficient one-pot, three-component synthesis of vinyl sulfones via iodide-catalyzed radical alkenylation

(2015) Weizheng Fan et al.   TETRAHEDRON

Direct difunctionalization of alkenes with sulfinic acids and NBS leading to β-bromo sulfones

(2015) Wei Wei et al.   TETRAHEDRON LETTERS

Boron chemistry in a new light

(2015) Guillaume Duret et al.   Chemical Science

The Development and Application of Sulfur Dioxide Surrogates in Synthetic Organic Chemistry

(2015) Edward J. Emmett et al.   Asian Journal of Organic Chemistry

Alkyl- and aryl-thioalkylation of olefins with organotrifluoroborates by photoredox catalysis

(2015) Yanjie Li et al.   Organic Chemistry Frontiers

Visible Light-Induced γ-Alkoxynitrile SynthesisviaThree- Component Alkoxycyanomethylation of Alkenes

(2014) Hong Yi et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydroaminomethylation of Olefins with Aminomethyltrifluoroborate by Photoredox Catalysis

(2014) Kazuki Miyazawa et al.   ADVANCED SYNTHESIS & CATALYSIS

Photocatalytic Generation of N-Centered Hydrazonyl Radicals:  A Strategy for Hydroamination of β,γ-Unsaturated Hydrazones

(2014) Xiao-Qiang Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Aminosulfonylation of Aryldiazonium Tetrafluoroborates with DABCO⋅(SO2)2and Hydrazines

(2014) Danqing Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives

(2014) Miles W. Johnson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nitrogen-centered radical-mediated C–H imidation of arenes and heteroarenes via visible light induced photocatalysis

(2014) Hyejin Kim et al.   CHEMICAL COMMUNICATIONS

Synthesis of 1-(2,3-dihydrobenzofuran-3-yl)-methanesulfonohydrazides through insertion of sulfur dioxide

(2014) Yuanyuan An et al.   CHEMICAL COMMUNICATIONS

Visible-Light Promoted Catalyst-Free Imidation of Arenes and Heteroarenes

(2014) Lu Song et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Mediated/Catalyzed Oxyalkylation of Alkenes with Alkylnitriles

(2014) Ala Bunescu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Radical Carbooxygenation: Alkylation and Alkoxylation of Styrenes

(2014) Zhixiong Liao et al.   Chemistry-An Asian Journal

Vicinal Difunctionalization of Alkenes with Iodine(III) Reagents and Catalysts

(2014) R. Martín Romero et al.   Chemistry-An Asian Journal

N-Acyloxyphthalimides as Nitrogen Radical Precursors in the Visible Light Photocatalyzed Room Temperature C–H Amination of Arenes and Heteroarenes

(2014) Laura J. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Olefin Hydroamination with Aminium Radical Cations: A Photoredox Method for Direct C–N Bond Formation

(2014) Andrew J. Musacchio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aerobic oxysulfonylation of alkenes using thiophenols: an efficient one-pot route to β-ketosulfones

(2014) Atul K. Singh et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Visible-Light-Promoted Redox Neutral C–H Amidation of Heteroarenes with Hydroxylamine Derivatives

(2014) Qixue Qin et al.   ORGANIC LETTERS

N-Aminopyridinium Salts as Precursors for N-Centered Radicals – Direct Amidation of Arenes and Heteroarenes

(2014) Tobias W. Greulich et al.   ORGANIC LETTERS

A Copper-Catalyzed Three-Component Reaction of Triethoxysilanes, Sulfur Dioxide, and Hydrazines

(2014) Xianbo Wang et al.   ORGANIC LETTERS

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Recent progress in copper-catalyzed difunctionalization of unactivated carboncarbon multiple bonds

(2014) Yohei Shimizu et al.   TETRAHEDRON LETTERS

Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β-Hydroxysulfones

(2013) Qingquan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed direct oxysulfonylation of alkenes with dioxygen and sulfonylhydrazides leading to β-ketosulfones

(2013) Wei Wei et al.   CHEMICAL COMMUNICATIONS

Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

(2013) Kazuki Miyazawa et al.   CHEMICAL COMMUNICATIONS

Desulfonylation of Tosyl Amides through Catalytic Photoredox Cleavage of NS Bond Under Visible-Light Irradiation

(2013) Jun Xuan et al.   Chemistry-An Asian Journal

Alkene Oxyalkylation Enabled by Merging Rhenium Catalysis with Hypervalent Iodine(III) Reagents via Decarboxylation

(2013) Yin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Taming sulfur dioxide: a breakthrough for its wide utilization in chemistry and biology

(2013) Philippe Bisseret et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Radical carbooxygenations of alkenes using hydroxamic acids

(2013) Ryan K. Quinn et al.   Chemical Science

Visible Light-Induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis

(2012) Yusuke Yasu et al.   ADVANCED SYNTHESIS & CATALYSIS

A Visible-Light-Mediated Oxidative CN Bond Formation/Aromatization Cascade: Photocatalytic Preparation of N-Arylindoles

(2012) Soumitra Maity et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A palladium-catalyzed reaction of aryl halides, potassium metabisulfite, and hydrazines

(2012) Shengqing Ye et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Free Oxyarylation of Alkenes with Aryl Diazonium Salts and TEMPONa

(2012) Marcel Hartmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Oxidation of Alkyl Trifluoroborates: An Opportunity for Tin-Free Radical Chemistry

(2010) Geoffroy Sorin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Aminosulfonylation of Aryl Halides

(2010) Bao Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent progress in the generation and use of nitrogen-centred radicals

(2008) Samir Z. Zard   CHEMICAL SOCIETY REVIEWS

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

(2008) Katrina H. Jensen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY