期刊
ORGANIC LETTERS
卷 17, 期 15, 页码 3758-3761出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01741
关键词
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资金
- National Basic Research Program of China [2015CB856600]
- NSFC [21422206, 21272206]
- Fundamental Research Funds for the Central Universities
A catalyst-controlled vicinal amino- versus oxy-acetoxylation of alkenes with PhI(OAc)(2) as the oxidant is described. The divergent synthesis of cyclic ureas and isoureas was achieved in good yields under mild conditions employing ambident urea nucleophiles. Both terminal and internal alkenes are compatible with this reaction protocol.
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